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Precipitaion of Acid Mine Drainage Using Coagulants and Flocculants

유기 및 무기응집제를 이용한 산성광산배수 침전 연구

  • Oh, Taek-Geun (Department of Energy and Mineral Resources Engineering, Dong-A University) ;
  • Hwang, Won-Jeong (Department of Energy and Mineral Resources Engineering, Dong-A University) ;
  • Lee, Jong-Un (Department of Energy and Mineral Resources Engineering, Chonnam National University) ;
  • Cha, Jongmun (Department of Energy and Mineral Resources Engineering, Chonnam National University)
  • 오택근 (동아대학교 에너지.자원공학과) ;
  • 황원정 (동아대학교 에너지.자원공학과) ;
  • 이종운 (전남대학교 에너지자원공학과) ;
  • 차종문 (전남대학교 에너지자원공학과)
  • Received : 2016.02.04
  • Accepted : 2016.04.15
  • Published : 2016.06.30

Abstract

The passive treatment was required a large area for the treatment of acid mine drainage (AMD), and pollutants were discharged with mine drainage by the increased flow rate in summer. This study was performed to improve the turbidity and to precipitate the pollutants quickly using coagulants and flocculants in AMD of abandoned mine sites that were difficult to build the passive treatment system. The coagulant PAC (Poly aluminium chloride) and flocculant PAM (Polyacrylamide) were selected to improve turbidity in W mine waters. We also tested the particle size analysis, ICP-OES and/or SEM-EDS for water and sludge samples.

산성광산배수(Acid mine drainage; AMD)를 처리하기 위한 자연정화시설의 반응조는 긴 체류시간을 위해 넓은 면적이 요구되며, 집중호우로 인해 유량이 급격히 늘어나는 여름에는 체류시간 부족으로 반응이 충분히 일어나지 못하고 많은 오염물질이 유출수로 빠져나가는 현상이 발생한다. 본 연구에서는 국내 부지 및 환경 특성으로 인해 넓은 면적이 요구되는 자연정화시설을 설치하기에 어려움이 있는 폐광산의 AMD에 응집제를 사용하여 빠른 시간 내에 오염물질을 침전시키고 탁도를 개선하는 연구를 진행하였다. W광산에서 배출되는 AMD에 무기응집제 PAC (Poly Aluminium Chloride)와 유기응집제인 PAM (Polyacrylamide) 성분이 포함된 고분자응집제를 사용하여 AMD의 상등수 및 여액의 중금속 농도와 침전된 슬러지의 형태를 파악하기 위해 입도분석, ICP-OES, SEM-EDS 분석을 실시하였다.

Keywords

References

  1. Hyun-Ho Kwon and Gwang-Su Nam, 2013: Mine Reclamation Prevention Engineering, 2nd Ed., Dong Hwa, Kyung Gi, Korea, pp. 255-263.
  2. Sang-Woo Ji, Young-Wook Cheong, Gil-Jae Yim, Kyeong-Jo Kim and Hyun-Sung Park, 2012: "The Treatment Efficiency of the Oxidation/Settling Ponds in the Passive Mine Water Treatment Systems in South Korea", The Korean Society for Geosystem Engineering, Vol. 49, No. 6, pp.788-798.
  3. Cheon-Young Park, Oh-Hyung Han, Dae-Yewn Shin and Young-Ui Hong, 2009: Seasonal Characteristics Variation of the Geochemical Components of Acid Mine Drainage and Yellow-colored Iron Hydroxide in the Abandoned GwangYang Gold Mine, South Korea, The Korean Society for Geosystem Engineering, Vol. 46, No. 2, pp. 190-206.
  4. Young-Do Jo, Hyung-Seok Kim, Ji-Whan Ahn, 2007: "Precipitation Characteristics of Heavy Metal Ions in Coal Mine Drainage", J. Miner. Soc., Vol. 20, No. 2, pp. 125-134.
  5. Gi-Ok Hong, Myung-Seok Seo, Deok-Kyun Na, Jong-Heom Kwak, 2006: "The Proportion and Fluctuations Trend of Rainy Season and Localized Heavy Rain in Korea Precipitation", 2006 Proceedings of the Spring Meeting of KMS, Korean Meteorological Society, Ilsan KINTEX, October 11-13, pp. 46-47.
  6. Yong-Su Park, A Study on the Pre-treatment Installation of Sewer Plant of Inclined Settler and Coagulation Agitato, MS Thesis, Suwon University.
  7. Seong-Won Lee, 2006: A Study on Conditioning using Polymers and Improvement of Dewaterability of Alum Sludge, Kwangwoon University, Korea.
  8. Kyu-Bong Sim, 2007: A Study of Al(III) Coagulation Characterization under Various Coagulation Condition, MS Thesis, Bukyong National University, Korea.
  9. Sun-Jon Lee, 2002: Effects of Single and Blended Coagulants on Organic Matters Removal in Coagulation Process, MS Thesis, Konkuk University, Korea.
  10. Young-Jun Song, Gye-Seong Lee, Kang-Ho Shin, Youn-Che Kim, Bong-Won Seo, Si-Nae Yoon, 2012: "Adsorption of Heavy Metals on Sludge from the Treatment Process of Acid Mine Drainage", J. of Korean Inst. of Resources Recycling, Vol. 21, No. 4, pp.35-43 https://doi.org/10.7844/kirr.2012.21.4.035
  11. Gye-Seong Lee, Young-Jun Song, 2010: "Characterization of Leaching of Heavy Metal and Formation of Acid Mine Drainage from Coal Mine Tailings", J. of Korean Inst. of Resources Recycling, Vol. 19, No. 2, pp.54-62
  12. Jung-Seock Kang, Gil-Jae Yim, Eui-Young Seo, Young-Wook Cheong, Sang-Soo Kang, Gyoung-Man Kim, Chamteut Oh and Sang-Woo Ji, 2014: "The Improvement of Turbidity and the AMD Neutralization Applicability Assessment of the Dolomite Mine Dust Screen Water", J. Korean Soc. Miner. Energy Resour. Eng., Vol. 51, No. 3, pp.366-376. https://doi.org/10.12972/ksmer.2014.51.3.366
  13. Jung-Seock Kang, So-Keul Chung, Young-Wook Cheong, Eui-Young Seo, Gil-Jae Yim and Sang-Woo Ji, 2013: "Coagulation of Suspended Solids and Neutralization Capacity of Sludge in a Settling Pond of O Limestone Mine, J. Korean Soc. Miner. Energy Resour. Eng., Vol. 50, No. 2 (2013) pp. 204-211. https://doi.org/10.12972/ksmer.2013.50.2.204