• Title/Summary/Keyword: Energy gap

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Correlation Between Energy Gap and Defect Formation of Al Doped Zinc Oxide on Carbon Doped Silicon Oxide

  • Oh, Teresa;Kim, Chy Hyung
    • Transactions on Electrical and Electronic Materials
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    • v.15 no.4
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    • pp.207-212
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    • 2014
  • Aluminum-doped zinc oxide (AZO) films were deposited on SiOC/Si wafer by an RF-magnetron sputtering system, by varying the deposition parameters of radio frequency power from 50 to 200 W. To assess the correlation of the optical properties between the substrate and AZO thin film, photoluminescence was measured, and the origin of deep level emission of AZO thin films grown on SiOC/Si wafer was studied. AZO formed on SiOC/Si substrates exhibited ultraviolet emission due to exciton recombination, and the visible emission was associated with intrinsic and extrinsic defects. For the AZO thin film deposited on SiOC at low RF-power, the deep level emission near the UV region is attributed to an increase of the variations of defects related to the AZO and SiOC layers. The applied RF-power influenced an energy gap of localized trap state produced from the defects, and the gap increased at low RF power due to the formation of new defects across the AZO layer caused by lattice mismatch of the AZO and SiOC films. The optical properties of AZO films on amorphous SiOC compared with those of AZO film on Si were considerably improved by reducing the roughness of the surface with low surface ionization energy, and by solving the problem of structural mismatch with the AZO film and Si wafer.

The analysis of Ag doping mechanism by photo-exposure (광노출에 따른 Ag도핑 메카니즘 해석)

  • 이현용;김민수;정홍배
    • Electrical & Electronic Materials
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    • v.8 no.4
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    • pp.472-477
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    • 1995
  • The degree of the photodoping process in Ag(100[.angs.])/a-Se$_{75}$Ge$_{25}$(1500[.angs.]) films has measured as a function of the photon energy between 1.5[eV] and 2.9[eV] with the exposing time. The "window" characteristics of Ag occur at 3400[.angs.] (3.65[eV]) and Ag is almost transparent in this region. It is shown that transmittance is almost constant (40-50%) for the wavelength ranges of our experiment. It is found that the energy gap of a unexposed a-Se$_{75}$Ge$_{25}$ film is 1.81[eV]. Ag photodoping process results in the photodarkening effect which the absorption edge shifts to the long wavelength. Especially, very large band shift (-0.3[eV]) is obtained by exposing He-Ne laser(6328[.angs.]).. We have obtained "the U-type property" for Ar He-Ne and semiconductor laser. It is associated with the variation of energy gap(E$_{g}$) with photo-dose and substantially is explained by DWP model.l.gap(E$_{g}$) with photo-dose and substantially is explained by DWP model.

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Preparation and Properties of $Zn_{1-x}Mg_xO$ Thin Films Prepared by Pulsed Laser Deposition Method (펄스 레이저 증착법을 이용한 $Zn_{1-x}Mg_xO$ 박막의 제작과 특성연구)

  • Suh, Kwang-Jong
    • Journal of the Microelectronics and Packaging Society
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    • v.12 no.1 s.34
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    • pp.73-76
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    • 2005
  • To widen the band gap of ZnO, we have investigated $Zn_{1-x}Mg_xO(ZMO)$ thin films prepared by pulsed laser deposition on c-plane sapphire substrates at $500^{\circ}C$. From X-ray diffraction patterns, ZMO films show only the (0002) and (0004) diffraction peaks. It means that the flints have the wurtzite structure. Segregation of ZnO and MgO phases is found in the films with x=0.59. All the samples are highly transparent in the visible region and have a sharp absorption edge in the UV region. The shift of absorption edge to higher energy is observed in the films with higher Mg composition. The excitonic nature of the films is clearly appeared in the spectra for all alloy compositions. The optical band-gap ($E_g$) of ZMO films is obtained from the ${\alpha}^2$ vs Photon energy plot assuming ${\alpha}^2\;\propto$ (hv - $E_g$), where u is the absorption coefficient and hv is the photon energy. The value of $E_g$ increases up to 3.72 eV for the films with x=0.35. It is important to adjust Mg composition control for controlling the band-gap of ZMO films.

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Effect on Electrical Characteristics of OLEDs According to Energy Gap for HIL of Amorphous Fluoropolymer Materials by Simulation (모의시험에서 정공 주입층 물질 AF의 에너지 갭이 OLED의 전기적 특성에 미치는 영향)

  • Han, Hyun-Seok;Kim, Jung-Sik;Kim, Weon-Jong;Lee, Jong-Yong;So, Byung-Mun;Kim, Tae-Wan;Hong, Jin-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.33-33
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    • 2010
  • Electrical properties of organic light-emitting diodes (OLEDs) were simulated by S.co's program. The OLEDs have stable operating parameters, high luminance, and high efficiency in simulation. The AF stands for amorphous fluoropolymer in simulation, and it was used as a hole-injection layer. In the five structure of OLEDs, an AF layer is sandwiched between the hole-transport layer and the ITO layer to increase the external quantum efficiency. By considering organic light-emitting diodes using an optimal energy gap of AF, it could contribute to the improvement of the efficiency of the device in the simulation.

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Analysis of Slip Displacement and Wear in Oscillating Tube supported by Plate Springs (튜브진동 시 판스프링 지지부의 미끄럼변위와 마멸 분석)

  • Kim Hyung-Kyu;Lee Young-Ho;Song Ju-Sun
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2003.11a
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    • pp.41-49
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    • 2003
  • Tube oscillation behaviour is experimentally investigated for the study on the fuel rod fretting that is caused by the flow-induced vibration in nuclear reactor. The experiment was conducted in all at room temperature. The specimen of tube assembly was supported by plate springs which simulated the spacer grids and fuel rods of a fuel assembly. To investigate the influence of contact condition between the grids and rods, normal load of 10 and 5 N, gaps of 0.1 and 0.3 mm were applied. The range of the oscillation at the center of the fuel rod specimen was varied as 0.2, 0.3 and 0.4 mm to simulate the fuel rod vibration due to flow. Displacements near the contact were measured with four displacement sensors during the tube oscillation. As results, the shape of oscillation (phase) varied depending on the contact condition. The oscillation displacement increased considerably from the contact to gap condition. The displacement increased further as the gap size increased. It is regarded that the spring shape influences the tube oscillation behaviour. Simple calculation showed that the slip displacement was very small. Therefore, cumulative damage concept is necessary for the fuel rod wear. The mechanism of plowing is thought required to explain the severe wear in the case of gap existence.

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A Study on properties of a-Si:H layers by photoelectron spectroscopic (a-Si:H 분광스펙트럼 특성연구)

  • Yang, Hyeon-Hun;Kim, Han-Wool;Kim, Joo Hoe;Kim, Chul Joong;Lee, Chang Gwon;So, Soon-Youl;Park, Gye-Choon;Lee, Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.61.1-61.1
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    • 2011
  • We report on a detailed study on gap-state distribution in thin amorphous silicon layers(a-Si:H) with film thickness between 5 nm and 20 nm c-Si wafers performed by UV excited photoelectron spectroscopy(UV-PES). We measured how the work function, the gap state density, the position of the Fermi-level and the Urbch-energy depend on the layer thickness and the doping level of the ultra thin a-Si:H(n) layer. It was found, that for phosphorous doping the position of the Fermi level saturates at $E_F-E_V$=1.47 eV. This is achieved at a gas phase concentration of 10000 ppm $PH_3$ in the $SiH_4/H_2$ mixture which was used for the PECVD deposition process. The variation of the doping level from 0 to 20000 ppm $PH_3$ addition results in an increase of the Urbach energy from 65 meV to 101 meV and in an increase of the gap state density at midgap($E_i-E_V$=0.86eV) from $3{\times}10^{18}$ to $2{\times}1019cm^{-3}eV^{-1}$.

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A Study on the Relationship between Oxygen and Carrier Concentration in a GZO Film on an Amorphous Structure (GZO 박막에 대한 비정질 구조에 따른 산소공공과 전하농도의 연관성에 대한 연구)

  • Kim, Do Hyoung;Kim, Hong Bae
    • Journal of the Semiconductor & Display Technology
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    • v.14 no.4
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    • pp.25-29
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    • 2015
  • In this study, RF magnetron sputtering was used to investigate the relationship between oxygen vacancy and carrier concentration in a GZO film on an amorphous structure. RF power was fixed at 50W and Ar flow was changed on a glass plate to create a thin film at room temperature. The transmittance of Al-adopted amorphous GZO was measured at 85% or higher; therefore, the transmittance was shown to be outstanding in all films. The hall mobility was also shown to be higher at the film showing the high transmittance at a short-wavelength, whereas the optical energy gap was shown to be higher at the film with high oxygen vacancy. The oxygen vacancy at the amorphous oxide semi-conductor increased the optical energy gap while it was not directly involved in increasing the mobility. The oxygen vacancy increases the carrier concentration while lowering the quality of amorphous structure; such factor, therefore affected the mobility. The increase of amorphous property is a direct way to increase the mobility of amorphous oxide semi-conductor.

Growth and temperature dependence of energy band gap for $CuAISe_2$ Single Crystal Thin Film by Hot Wall Epitaxy (Hot Wall Epitaxy(HWE)법에 의한 $CuAlSe_2$ 단결정 박막의 성장과 에너지 밴드갭의 온도 의존성)

  • Yun, Seok-Jin;Hong, Kwang-Joon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.121-122
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    • 2007
  • Single crystal $CuAlSe_2$ layers were grown on thoroughly etched sem-insulating GaAs(l00) substrate at $410^{\circ}C$ with hot wall epitaxy (HWE) system by evaporating $CuAlSe_2$ source at $680^{\circ}C$. The crystalline structure of the single crystal thin films was investigated by the photoluminescence and double crystal X-ray diffraction (DCXD). The carrier density and mobility of single crystal $CuAlSe_2$ thin films measured with Hall effect by van der Pauw method are $9.24{\times}l0^{16}\;cm^{-3}$ and $295\;cm^2/V{\cdot}s$ at 293K, respectively. The temperature dependence of the energy band gap of the $CuAlSe_2$ obtained from the absorption spectra was well described by the Varshni's relation, $E_g(T)\;=\;2.8382\;eV\;-\;(8.68\;{\times}\;10^{-4}\;eV/K)T^2/(T\;+\;155\;K)$.

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Temperature dependence of photocurrent spectra for $AgInS_2$ epilayers grown by hot wall epitaxy

  • Baek, Seung-Nam;Hong, Kwang-Joon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.123-124
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    • 2007
  • A silver indium sulfide ($AgInS_2$) epilayer was grown by the hot wall epitaxy method, which has not been reported in the liteniture. The grown $AgInS_2$ epilayer has found to be a chalcopyrite structure and evaluated to be high quality crystal. From the photocurrent measurement in the temperature range from 30 K to 300 K, the two peaks of A and B were only observed, whereas the three peaks of A, B, and C were seen in the PC spectrum of 10 K. These peaks are ascribed to the band-to-band transition. The valence band splitting of $AgInS_2$ was investigated by means of the photocurrent measurement. The temperature dependence of the energy band gap of the $AgInS_2$ obtained from the photocurrent spectrum was well described by the Varshni's relation, $E_g(T)=\;E_g(0)\;eV-(7.78\;{\times}\;10^{-4}\;eV/K)T^2/(T\;+\;116\;K\;K)$. Also, Eg(0) is the energy band gap at 0 K, which is estimated to be 2.036 eV at the valence band state A and 2.186 eV at the valence band state B.

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Seismic performance enhancement of a PCI-girder bridge pier with shear panel damper plus gap: Numerical simulation

  • Andika M. Emilidardi;Ali Awaludin;Andreas Triwiyono;Angga F. Setiawan;Iman Satyarno;Alvin K. Santoso
    • Earthquakes and Structures
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    • v.27 no.1
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    • pp.69-82
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    • 2024
  • In the conventional seismic design approach for a bridge pier, the function of the stopper, and shear key are to serve as mechanisms for unseating prevention devices that retain and transmit the lateral load to the pier under strong earthquakes. This frequently inflicts immense shear forces and bending moments concentrated at the plastic hinge zone. In this study, a shear panel damper plus gap (SPDG) is proposed as a low-cost alternative with high energy dissipation capacity to improve the seismic performance of the pier. Therefore, this study aimed to investigate the seismic performance of the pre-stressed concrete I girder (PCI-girder) bridge equipped with SPDG. The bridge structure was analyzed using nonlinear time history analysis with seven-scaled ground motion records using the guidelines of ASCE 7-10 standard. Consequently, the implementation of SPDG technology on the bridge system yielded a notable decrease in maximum displacement by 41.49% and a reduction in earthquake input energy by 51.05% in comparison to the traditional system. This indicates that the presence of SPDG was able to enhance the seismic performance of the existing conventional bridge structure, enabling an improvement from a collapse prevention (CP) level to an immediate occupancy (IO).