• Journal of the Korean Society for Marine Environment & Energy
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• v.5 no.1
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• pp.51-67
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• 2002

In order to understand behaviors of heavy metals around the artificial Lake Shihwa in the vicinity of Kyunggi Bay in Korea in relation with huge environmental changes due to construction of huge artificial lake, water samples were collected from Lake Shihwa and its tributaries from 1996 to 1998 and analyzed. Due to extreme pollutant discharge from various kinds of anthropogenic sources such as the Banweol and Shihwa Industrial Complexes and cities, the Shihwa and its tributaries have been polluted in waters with various heavy metals. The enrichment factors of particulate heavy metals in water of streams and storm sewers were very high. All of the heavy metals observed in the waters showed relatively high temporal and spatial variations. In surface waters of the lake during the desalination after the dike establishment, spatial distributions of heavy metal concentrations were mainly controlled by various biogeochemical factors as well as input of industrial and municipal wastewaters, while, physical mixing was minor factor Pb and Co showed a strong affinity to particle phase, however the affinity to dissolved phase was dominated in Ni, Cu and Cd. Water quality of the artificial Lake Shihwa has been deteriorated by direct discharge of untreated wastewater and heavy metals have been accumulated in the lake system. Therefore, luther environmental improvement plan should be programmed subsequently.

• Proceedings of the Materials Research Society of Korea Conference
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• 2012.05a
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• pp.72-72
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• 2012

Lithium rechargeable batteries have been widely used as key power sources for portable devices for the last couple of decades. Their high energy density and power have allowed the proliferation of ever more complex portable devices such as cellular phones, laptops and PDA's. For larger scale applications, such as batteries in plug-in hybrid electric vehicles (PHEV) or power tools, higher standards of the battery, especially in term of the rate (power) capability and energy density, are required. In PHEV, the materials in the rechargeable battery must be able to charge and discharge (power capability) with sufficient speed to take advantage of regenerative braking and give the desirable power to accelerate the car. The driving mileage of the electric car is simply a function of the energy density of the batteries. Since the successful launch of recent Ni-MH (Nickel Metal Hydride)-based HEVs (Hybrid Electric Vehicles) in the market, there has been intense demand for the high power-capable Li battery with higher energy density and reduced cost to make HEV vehicles more efficient and reduce emissions. However, current Li rechargeable battery technology has to improve significantly to meet the requirements for HEV applications not to mention PHEV. In an effort to design and develop an advanced electrode material with high power and energy for Li rechargeable batteries, we approached to this in two different length scales - Atomic and Nano engineering of materials. In the atomic design of electrode materials, we have combined theoretical investigation using ab initio calculations with experimental realization. Based on fundamental understanding on Li diffusion, polaronic conduction, operating potential, electronic structure and atomic bonding nature of electrode materials by theoretical calculations, we could identify and define the problems of existing electrode materials, suggest possible strategy and experimentally improve the electrochemical property. This approach often leads to a design of completely new compounds with new crystal structures. In this seminar, I will talk about two examples of electrode material study under this approach; $LiNi_{0.5}Mn_{0.5}O_2$ based layered materials and olivine based multi-component systems. In the other scale of approach; nano engineering; the morphology of electrode materials are controlled in nano scales to explore new electrochemical properties arising from the limited length scales and nano scale electrode architecture. Power, energy and cycle stability are demonstrated to be sensitively affected by electrode architecture in nano scales. This part of story will be only given summarized in the talk.

• Journal of Environmental Impact Assessment
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• v.28 no.6
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• pp.592-603
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• 2019

This study is about the implementation of low energy sewage management technology through effective control of blower which consumes the most energy in sewage treatment. In calculating the amount of oxygen required for microorganisms, unlike the existing method using the operating index in the bioreactor or TMS data in the discharge port, the CODcr and NH₄⁺-N concentration changes in sewage flowing into the sewage treatment plant were detected in advance before entering the bioreactor and the amount of air was controlled based on this. The pre-sensing was found to have a high correlation compared with conventional products. As a result of blower control, it was possible to save about 9.9% energy more than the manual control. Consequently, this study suggested the possibility of blower's real-time control combined with pre-sensing technology. Also, it is expected that the low energy sewage treatment can be applied to sewage treatment facilities dependent on operation by manpower, and it will contribute to the reduction of greenhouse gas emissions.

• Nuclear Engineering and Technology
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• v.50 no.3
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• pp.356-367
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• 2018

A series of tests dedicated to station blackout (SBO) accident scenarios have been recently performed at the $Prim{\ddot{a}}rkreislauf-Versuchsanlage$ (primary coolant loop test facility; PKL) facility in the framework of the OECD/NEA PKL-3 project. These investigations address current safety issues related to beyond design basis accident transients with significant core heat up. This work presents a detailed analysis using the best estimate thermal-hydraulic code TRACE (v5.0 Patch4) of different SBO scenarios conducted at the PKL facility; failures of high- and low-pressure safety injection systems together with steam generator (SG) feedwater supply are considered, thus calling for adequate accident management actions and timely implementation of alternative emergency cooling procedures to prevent core meltdown. The presented analysis evaluates the capability of the applied TRACE model of the PKL facility to correctly capture the sequences of events in the different SBO scenarios, namely the SBO tests H2.1, H2.2 run 1 and H2.2 run 2, including symmetric or asymmetric secondary side depressurization, primary side depressurization, accumulator (ACC) injection in the cold legs and secondary side feeding with mobile pump and/or primary side emergency core coolant injection from the fuel pool cooling pump. This study is focused specifically on the prediction of the core exit temperature, which drives the execution of the most relevant accident management actions. This work presents, in particular, the key improvements made to the TRACE model that helped to improve the code predictions, including the modeling of dynamical heat losses, the nodalization of SGs' heat exchanger tubes and the ACCs. Another relevant aspect of this work is to evaluate how well the model simulations of the three different scenarios qualitatively and quantitatively capture the trends and results exhibited by the actual experiments. For instance, how the number of SGs considered for secondary side depressurization affects the heat transfer from primary side; how the discharge capacity of the pressurizer relief valve affects the dynamics of the transient; how ACC initial pressure and nitrogen release affect the grace time between ACC injection and subsequent core heat up; and how well the alternative feeding modes of the secondary and/or primary side with mobile injection pumps affect core quenching and ensure stable long-term core cooling under controlled boiling conditions.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.62 no.6
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• pp.798-802
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• 2013

In a conventional DC power supply used for CO2 laser, the circuit elements such as a rectifier bridge, a current-limiting resistor, a high voltage switch, energy storage capacitors ans a high-voltage isolation transformer using high turn ratio are necessary. Consequently, those supplies are expensive and require a large space. Thus, laser resonator and power supply should be optimally designed. In this paper, we propose a new power supply using high frequency resonance phenomena for CW(Continuous wave) CO2 laser (maximum output of 23W with discharge length of 450mm). It consists of a transformer including leakage inductance, magnetizing inductance and half-bridge converter, a three-stage Cockcroft-Walton and PFC(Power factor correction) circuit. The output ripple voltage can be controlled the minimum of 0.24% under the high frequency switching of 231kHz. Furthermore, the output efficiency was improved to 16.4% and the laser output stability of about 5.6% was obtained in this laser system.

• Korea-Australia Rheology Journal
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• v.12 no.1
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• pp.55-67
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• 2000

In this paper, an experimental study of the rheological behavior of granular flow in a new type of storage silo is presented. The main characteristic of the new design is a hexagonal shape chosen with the objective of minimizing the stresses applied to the stored grains, and to reduce grain damage during the filling and emptying processes. Measurements of stress distribution and flow patterns are shown for a variety of granular materials. Because of the design of the silo, the granular material adopts its natural rest angle at all times eliminating collisional stresses and impacts between grains. A homogeneous, low friction flow is naturally achieved which provides a controlled stress distribution throughout the silo during filling and emptying. Secondary dynamic stresses, which are responsible for wall failure in conventional silos of the vertical type, are completely eliminated. A comparison between the two geometries is presented with data obtained for these silos and a number of granular materials. The discharge pattern inhibits powder formation in the silo and the filling system virtually eliminates unwanted material packing. Finally, notwithstanding the rheological advantages of this new design, the hexagonal cells that constitute the silo have many other advantages, such as the possible use of solar energy to control the humidity inside them. The cell type design allows for versatile storage capabilities and the elevation above the ground provides unlimited transportation facilities during emptying.

• Nano
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• v.13 no.12
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• pp.1850141.1-1850141.11
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• 2018

Sodium ion batteries based on the more sodium source reserve than that of lithium have been designed as promising alternatives to lithium ion batteries. However, several problems including unsatisfied specific capacity and serious cyclic stability must be solved before the reality. One of the effective approaches to solve the abovementioned problems is to search for suitable anode materials. In this work, we designed and prepared $FeSe_2$ nanoflakes via a simple hydrothermal method which can be adjusted in composition by Fe precursor. As a potential anode for sodium storage, the optimized $FeSe_2$ electrode was further evaluated in different electrolytes of $NaClO_4$ in propylene carbonate/fluoroethylene carbonate and $NaCF_3SO_3$ in diethylene glycol dimethyl ether. The capacity was about $470mAh\;g^{-1}$ and $535mAh\;g^{-1}$ at $0.5A\;g^{-1}$, respectively, in the voltage between 0.5 V and 2.9 V in the cycle of stabilization phase. Superior performance both in capacity and in stability was obtained in ether-based electrolyte, which affords the property without plugging the intermediates of transition metal dichalcogenides during charge/discharge processes.

• Journal of Electrochemical Science and Technology
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• v.10 no.2
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• pp.223-230
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• 2019

A facile method for surface coating with $Li_2TiF_6$ which has a high lithium-ion conductivity, on $LiMn_2O_4$ spinel cathode material for high performance lithium ion batteries. The surface coating is performed by using a co-precipitation method with $Li_2CO_3$ powder and $H_2TiF_6$ solution under room temperature and atmospheric pressure without special equipment. Total coating amount of $Li_2TiF_6$ is carefully controlled from 0 to 10 wt.% based on the active material of $LiMn_2O_4$. They are evaluated by a systematic combination of analyses comprising with XRD, SEM, TEM and ICP. It is found that the surface modification of $Li_2TiF_6$ is very beneficial to high cycle life and excellent rate capability by reducing surface failure and supporting lithium ions transportation on the surface. The best coating condition is found to have a high cycle life of $103mAh\;g^{-1}$ at the 100th cycle and a rate capability of $102.9mAh\;g^{-1}$ under 20 C. The detail electrochemical behaviors are investigated by AC impedance and galvanostatic charge and discharge test.

• Journal of the Korean Society for Marine Environment & Energy
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• v.4 no.2
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• pp.25-34
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• 2001

/sup 226/Ra and /sup 228/Ra analysis were carried out at the representative station of Masan Bay from May to August, 1999. The high activities of /sup 226/Ra and /sup 228/Ra in the surface water were appeared in rainy season (August, 1). However, there is no significant variation in concentrations in the other season. A high negative linear correlation between /sup 226/Ra activities and salinity in the surface water suggests that /sup 226/Ra activity in the surface water was controlled by simple mixing between the two end-members low salinity high /sup 226/Ra activity water of inner Bay and a high salinity low /sup 226/Ra activity water of the continental shelf water out of Bay. /sup 226/Ra activities below the surface mixed layer were higher than those of expected level from the /sup 226/Ra versus salinity. And also /sup 228/Ra//sup 226/Ra ratios in the bottom water were lower compared to those in surface water due to the presence of potential source of /sup 226/Ra below the surface mixed layer. However, it is known that /sup 228/Ra compared to /sup 226/Ra is enriched in bottom sediments and pure water. Therefore, the most probable sources for low /sup 228/Ra//sup 226/Ra activity ration is submarine ground water discharge. Further studies are required to quantify the various sources of /sup 226/Ra and /sup 228/Ra and their relative contributions.

• Journal of the Korean Society for Marine Environment & Energy
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• v.8 no.3
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• pp.148-157
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• 2005

In order to understand distribution characteristics and pollution of heavy metals in the artificial Lake Shihwa in the vicinity of Kyunggi Bay in relation with huge environmental changes, various environmental samples including seawaters, surface sediments and settling particulate matters were collected from Lake Shihwa in 2004. Due to extreme pollutant discharge from various anthropogenic sources such as the Banweol and Shihwa Industrial Complexes and cities, the highest metal concentrations in the samples such as waters, sediments and settling particulate matter were found in inner part of the lake. High metal contents (Cu, Zn and Hg) in sediments were observed at Sts. 2-4 and 9. The contents of Cr, Co, Ni, Cu, Zn and Pb in SPMs were high at St. 5 and low in the outer part of the lake. Spatial distribution of heavy metals were mainly controlled various biogeochemical factors and physical mixing as well as input of industrial and municipal wastewaters. Although tile environmental qualities of heavy metals in the lake have been improved partially due to inflow of outer seawater, it is not clear to reach a good environmental quality. Therefore, further environmental programs should be conducted continuously for environmental improvement.