• Journal of the Korean Chemical Society
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• v.8 no.4
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• pp.158-163
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• 1964

Electronic spectra and quenching constants for ten N,N-dimethylanilines (DMA) have been determined. The $250m{\mu}$ absorption band (C band) of DMA was shown to be mainly responsible for the quenching. This band was confirmed as an $n{\to}{\pi}^{\ast}$ band through substituent and medium effects on the spectra shifts. The energy absorbed by this band then transfers to triplet and down to the lowest triplet state, $^{3}La$, where the energy is lost by non-radiative collisions.

• Nuclear Engineering and Technology
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• v.35 no.5
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• pp.497-505
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• 2003

This paper describes a computational approach to the quantification of primary damage under irradiation and demonstrates the effect of neutron energy spectra on the formation of the displacement cascade. The development of displacement cascades in ${\alpha}-Iron$ has been simulated using the MOLDY code - a molecular dynamics code for simulating radiation damage. The primary knock-on atom energy, key input to the MOLDY code, was determined from the SPECTER code calculation on two neutron spectra. The two neutron spectra include; (i) neutron spectrum in the instrumented irradiation capsule of the high-flux advanced neutron application reactor (HANARO), and (ii) neutron spectrum at the inner surface of the reactor pressure vessel steel for the Younggwang nuclear power plant No.5 (YG 5). Minor differences in the normalized neutron spectra between the two spectra produce similar values of PKA energy, which are 4.7 keV for HANARO and 5.3 keV for YG 5. This similarity implies that primary damage to the components of the commercial nuclear reactors should be well simulated by irradiation in the HANARO. Moreover, the application of the MD calculations corroborates this statement by comparing cascades simulation results.

• Structural Engineering and Mechanics
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• v.76 no.6
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• pp.709-724
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• 2020

The typical inerter system, the tuned viscous mass damper (TVMD), has been proven to be efficient. It is characterized by an energy-dissipation-enhancement effect, whereby the dashpot deformation of TVMD can be amplified for enhanced energy dissipation efficiency. However, existing studies related to TVMD have mainly been performed on elastic structures, so the working mechanism remains unclear for nonlinear structures. To deal with this, an energy-spectrum analysis framework is developed systematically for classic bilinear hysteretic structures with TVMD. Considering the soil effect, typical bedrock records are propagated through the soil deposit, for which the designed input energy spectra are proposed by considering the TVMD parameters and structural nonlinear properties. Furthermore, the energy-dissipation-enhancement effect of TVMD is quantitatively evaluated for bilinear hysteretic structures. The results show that the established designed input energy spectra can be employed to evaluate the total energy-dissipation burden for a nonlinear TVMD structure. Particularly, the stiffness of TVMD is the dominant factor in adjusting the total input energy. Compared with the case of elastic structures, the energy-dissipation-enhancement effect of TVMD for nonlinear structures is weakened so that the expected energy-dissipation effect of TVMD is replaced by the accumulated energy dissipation of the primary structure.

• Nuclear Engineering and Technology
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• v.49 no.6
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• pp.1354-1357
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• 2017

Characterization of special nuclear material may be performed using energy spectroscopy of either the neutron or gamma-ray emissions from the sample. Gamma-ray spectroscopy can be performed relatively easily using high-resolution semiconductors such as high-purity germanium. Neutron spectroscopy, by contrast, is a complex inverse problem. Here, results are presented for $^{252}Cf$ and PuBe energy spectra unfolded using a single EJ309 organic scintillator; excellent agreement is observed with the reference spectra. Neutron energy spectroscopy is also possible using a two-plane detector array, whereby time-of-flight kinematics can be used. With this system, energy spectra can also be obtained as a function of position. Spatial-dependent energy spectra are presented for neutron and gamma-ray sources that are in excellent agreement with expectations.

• Nuclear Engineering and Technology
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• v.55 no.9
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• pp.3401-3408
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• 2023

In this study, we used the Monte Carlo N-Particle program to simulate the gamma-ray spectra obtained from plastic scintillators holes filled with bismuth nanoparticles. We confirmed that the incorporation of bismuth nanoparticles into a plastic scintillator enhances its performance for gamma-ray spectroscopy using the subtraction method. The subtracted energy spectra obtained from the bismuth-nanoparticle-incorporated and the original plastic scintillator exhibit a distinct energy peak that does not appear in the corresponding original spectra. We varied the diameter and depth of the bismuth-filled holes to determine the optimal hole design for gamma-ray spectroscopy using the subtraction method. We evaluated the energy resolutions of the energy peaks in the gamma-ray spectra to estimate the effects of the bismuth nanoparticles and determine their optimum volume in the plastic scintillator. In addition, we calculated the peak-to-total ratio of the energy spectrum to evaluate the energy measuring limit of the bismuth nanoparticle-containing plastic scintillator using the subtraction method.

• Earthquakes and Structures
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• v.26 no.3
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• pp.219-228
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• 2024

This study examines damping modification factors (DMFs) of elastic input energy spectra corresponding to a set of 116 earthquake ground motions. Mean input energy per mass spectra and mean DMFs are presented for both considered ground motion components. Damping ratios of 3%, 5%, 10%, 20%, and 30% are used and the 5% damping ratio is considered the benchmark for DMF computations. The geometric mean DMFs of the two horizontal components of each ground motion are computed and coefficients of variation are presented graphically. The results show that the input energy spectra-based DMFs exhibit a dependence on the damping ratio at very short periods and they tend to be nearly constant for larger periods. In addition, mean DMF variation is obtained graphically for also the damping ratio, and mathematical functions are fitted as a result of statistical analyses. A strong correlation between the computed DMFs and the ones from predicted equations is observed.

• Nuclear Engineering and Technology
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• v.49 no.7
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• pp.1483-1488
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• 2017

In order to predict and control the environmental and health impacts of ionizing radiation in environmental sources such as groundwater, it is necessary to identify the radionuclides present. Beta-emitting radionuclides are frequently identified by measuring their characteristic energy spectra. The present work shows that self-attenuation effects from volume sources result in a geometry-dependent shift in the characteristic spectra, which needs to be taken into account in order to correctly identify the radionuclides present. These effects are shown to be compounded due to the subsequent shift in the photon spectra produced by the detector, in this case an inorganic solid scintillator ($CaF_2:Eu$) monitored using a silicon photomultiplier. Using tritiated water as an environmentally relevant, and notoriously difficult to monitor case study, analytical predictions for the shift in the energy spectra as a function of depth of source have been derived. These predictions have been validated using Geant4 simulations and experimental results measured using bespoke instrumentation.

• Proceedings of the Korean Nuclear Society Conference
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• 1997.05a
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• pp.102-107
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• 1997

A stiffness in a dynamical system is numerically studied to investigate a sensitivity of a reactor to the delayed neutron spectra with the Doppler feedback. To test numerical procedure, we adopted a case of a reactivity accident in a point reactor model. We found that the stiffness is sensitive to a reactivity insertion rate and the delayed neutron spectra in the Doppler feedback phase. Our numerical results show that global reactor characteristics are not very sensitive to the delayed neutron spectra even though their instantaneous ones are sensitive. We present the time evolution of each precursor group explicitly.

• Transactions on Electrical and Electronic Materials
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• v.14 no.6
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• pp.329-333
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• 2013

SiOC films were prepared by capacitively coupled plasma chemical vapor deposition, and the correlation between the binding energy by X-ray photoelectron spectroscopy and Arrhenius equation for ionization energy was studied. The ionization energy decreased with increase of the potential barrier, and then the dielectric constant also decreased. The binding energy decreased with increase of the potential barrier. The dielectric constant and electrical characteristic of SiOC film was obtained by Arrhenius equation. The dielectric constant of SiOC film was decreased by lowering the polarization, which was made from the recombination between opposite polar sites, and the dissociation energy during the deposition. The SiOC film with the lowest dielectric constant had a flat surface, which depended on how carbocations recombined with other broken bonds of precursor molecules, and it became a fine cross-linked structure with low ionization energy, which contributed to decreasing the binding energy by Si 2p, C 1s electron orbital spectra and O 1s electron orbital spectra. The dielectric constant after annealing decreased, owing to the extraction of the $H_2O$ group, and lowering of the polarity.

• Progress in Superconductivity and Cryogenics
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• v.21 no.3
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• pp.6-12
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• 2019

Extended Drude model has been used to obtain information of correlations from measured optical spectra of strongly correlated electron systems. The optical self-energy can be defined by the extended Drude model formalism. One can extract the optical self-energy and the electron-boson spectral density function from measured reflectance spectra using a well-developed usual process, which is consistent with several steps including the extended Drude model and generalized Allen's formulas. Here we used a reverse process of the usual process to investigate the extended Drude analysis when an additional low-energy interband transition is included. We considered two typical electron-boson spectral density model functions for two different (normal and d-wave superconducting) material states. Our results show that the low-energy interband transition might give significant effects on the electron-boson spectral density function obtained using the usual process. However, we expect that the low-energy interband transition can be removed from measured spectra in a proper way if the transition is well-defined or well-known.