• Transactions of the Korean Society of Mechanical Engineers B
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• v.32 no.2
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• pp.92-99
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• 2008

The "energy separation phenomenon" through a vortex tube has been a long-standing mechanical engineering problem whose operational principle is not yet known. In order to find the operational principle of the vortex tube, CFD analysis of the flow field in the vortex tube has been carried out. It was found that the energy separation mechanism in the vortex tube consists of basically two major thermodynamic-fluid mechanical processes. One is the isentropic expansion process at the inlet nozzle, during which the gas temperature is nearly isentropically cooled. Second process is the viscous dissipation heating due to the high level of turbulence in both flow passages toward cold gas exit as well as the hot gas exit of the vortex tube. Since the amount of such a viscous heating is different between the two passages, the gas temperature at the cold exit is much lower than that at the hot exit.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• v.y2005m4
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• pp.329-333
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• 2005

Total temperature distribution in high speed fee & wall jet regions was investigated using the total temperature probe. For the free jet, the distance of probe from the nozzle exit is changed in the range of 1, 2, 4 and 6 times o nozzle exit diameter. Energy separation phenomenon was observed on shear layer between jet and ambient. In wall jet region, impinging plate was fixed at Z/D=2 and total temperature distribution has been measured for various radial distance($R/D=1.25\sim2.0$). Energy separation phenomenon was found at wall jet boundary and near wall, and was compared with measured adiabatic wall temperature value.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.38 no.9
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• pp.731-737
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• 2014

A vortex chamber is a simple device that separates compressed gas into a high-temperature stream and a low-temperature stream. It is increasing in popularity as a next-generation heat exchanger, but the flow physics associated with it is not yet well understood. In the present study, both experimental and numerical analyses were performed to investigate the temperature separation phenomenon inside the vortex chamber. Static pressures and temperatures were measured using high-sensitivity pressure transducers and thermocouples, respectively. Computational fluid dynamics was applied to simulate 3D unsteady compressible flows. The simulation results showed that the temperature separation is strongly dependent on the diameter of the vortex chamber and the supply pressure at the inlet ports, where the latter is closely related to the viscous work. The previous concept of a pressure gradient wave may not be a reasoning for temperature separation phenomenon inside the vortex chamber.

• Korean Journal of Materials Research
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• v.31 no.8
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• pp.465-470
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• 2021

Deuterium is a crucial clean energy source required for nuclear fusion and is a future resource needed in various industries and scientific fields. However, it is not easy to enrich deuterium because the proportion of deuterium in the hydrogen mixture is scarce, at approximately 0.016 %. Furthermore, the physical and chemical properties of the hydrogen mixture and deuterium are very similar. Therefore, the efficient separation of deuterium from hydrogen mixtures is often a significant challenge when using modern separation technologies. Recently, to effectively separate deuterium, studies utilizing the 'Kinetic Quantum Sieving Effect (KQS)' of porous materials are increasing. Therefore, in this review, two different strategies have been discussed for improving KQS efficiency for hydrogen isotope separation performance using nanoporous materials. One is the gating effect, which precisely controls the aperture locally by adjusting the temperature and pressure. The second is the breathing phenomenon, utilizing the volume change of the structure from closed system to open system. It has been reported that efficient hydrogen isotope separation is possible using these two methods, and each of these effects is described in detail in this review. In addition, a specific-isotope responsive system (e.g., 2nd breathing effect in MIL-53) has recently been discovered and is described here as well.

• Korean Journal of Materials Research
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• v.28 no.9
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• pp.506-510
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• 2018

Nitrogen is a serious contaminant in natural gas because it decreases the energy density. The natural gas specification in South Korea requires a $N_2$ content of less than 1 mol%. Thus, cost-effective $N_2$ removal technology from natural gas is necessary, but until now the only option has been energy-intensive processes, e.g., cryogenic distillation. Using porous materials for the removal process would be beneficial for an efficient separation of $CH_4/N_2$ mixtures, but this still remains one of the challenges in modern separation technology due to the very similar size of the components. Among various porous materials, metal-organic frameworks (MOFs) present a promising candidate for the potential $CH_4/N_2$ separation material due to their unique structural flexibility. A MIL-53(Al), the most well-known flexible metal-organic framework, creates dynamic changes with closed pore (cp) transitions to open pores (ops), also called the 'breathing' phenomenon. We demonstrate the separation performance of $CH_4/N_2$ mixtures of MIL-53(Al) and its derivative $MIL-53-NH_2$. The $CH_4/N_2$ selectivity of $MIL-53-NH_2$ is higher than pristine MIL-53(Al), suggesting a stronger $CH_4$ interaction with $NH_2$.

• Progress in Superconductivity and Cryogenics
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• v.18 no.1
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• pp.14-18
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• 2016

Organic compounds have a problem that the separation of structural isomer in the preparation process requires high energy consumption. This study proposes a new separation method of structural isomer using Magneto- Archimedes method. Firstly, the levitation height of 1, 6-DDA and 1, 10-DDA was respectively calculated by simulation of the forces acting on the particles under magnetic field, and it was indicated that they could be separated by the difference of levitation height. To confirm the phenomenon experimentally, white powders of 1, 6-DDA and 1, 10-DDA were formed into pellets, and were soaked in manganese chloride solution. Then the solution was put on the center of the cryostat of HTS bulk magnet (maximum magnetic flux density is 3T). As a result, it was confirmed that the separation of structural isomer by difference of levitation height could be possible.

• Transactions of the Korean hydrogen and new energy society
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• v.17 no.2
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• pp.141-148
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• 2006

This study was carried out to analyze the microstructure characteristics of electrolyte membrane through XRD, SEM and AC impedance measurement for using in high temperature steam electrolysis(HTE). It was investigated that thermal stability and electric characteristics by sintering condition using dry and wet process, and confirmed growth of particle and density change by sintering temperature. The sintering temperature and behavior had an effect on the relative density of the ceramic and the average grain size. The more amount of dispersant in organic compound increase, the more the density increased. But the binder was shown opposite phenomenon. It was analyzed that electrolyte resistance and electrical characteristics using AC impedance. The electrical properties of YSZ grain boundary changed with the sintering temperature.

• Tribology and Lubricants
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• v.32 no.5
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• pp.166-171
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• 2016

Electric vehicle ownership is expanding for two reasons: its technology features have enhanced fuel economy, and the number of vehicle emissions regulations is increasing. Battery performance has a large influence on the capability of electric vehicles, and even though battery thermal management has been actively researched, specific technological improvements to battery performance are not being presented. For instance, many industrial applications utilize vortex tubes as components for refrigeration machines because of their numerous intrinsic benefits. If electric vehicles incorporate vortex tubes for battery cooling, performance and efficiency advancements are possible. This study uses a counter-flow vortex tube to investigate its temperature separation characteristics, based on the back pressure of the cold air exit and the difference between the inlet and back pressures. The experiment uses a vortex tube with the following parameters: six nozzle holes, a 20 mm inner vortex diameter (D), a 14D tube length, a 0.7D cold exit orifice diameter, and a nozzle area ratio of 0.142. The measurements prove that the temperature difference between the hot air and cold air decreased because of the flow resistance of the hot air and the backflow phenomenon at the cold air exit. The flow resistance causes the temperature difference to decrease, and the back pressure of the cold air exit influences the flow resistance. The results show that the back pressure significantly influences the efficiency of temperature separation.

• Journal of the Mineralogical Society of Korea
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• v.30 no.3
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• pp.103-112
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• 2017

In order to transform arsenopyrite into pyrrhotite and to decrease As content by less than 2,000 mg/kg, pulp sample and non-magnetic pulp sample were heated in a microwave oven at different heating times and were separated through wet-magnetic separation. As the microwave heating time increased, the phase of pyrrhotite was extended to become arsenopyrite entirely. The melting pores and micro-cracks occurred on the pyrrhotite due to hot spot phenomenon with microwave heating. The heated raw pulp sample (As content : 19,970.13 mg/kg) and non-magnetic pulp sample (As content : 19,970.13 mg/kg) which were heated in a microwave oven for 10 minutes were separated through wet-magnetic separation and magnetic fraction containing less than 2,000 mg/kg of As content was recovered only from the heated sample of magnetic separation. It was discovered that for the sulfide complex ore with As penalty imposed on, if microwave heating and wet-magnetic separation are effectively utilized, magnetic fraction. We expect to be able to obtain ore minerals with an arsenic content below the penalty charge.

• Membrane Journal
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• v.17 no.3
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• pp.269-275
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• 2007

Sodium type faujasite(FAU) zeolite membranes with a thickness of 5${\mu}m$ and a Si/Al molar ratio of 1.5 were prepared by the secondary growth process. The $CO_2/N_2$ separation in the vacuum mode was investigated at $30^{\circ}C$ for an equimolar $CO_2-N_2$ mixed gas before and after embedding 13X zeolite beads in the permeate side. The embedded 13X zeolite beads improved both $CO_2$ permeance and $CO_2/N_2$ separation factor, simultaneously. The phenomenon was explained by an increment in the $CO_2$ desorption rate at the FAU zeolite/$\alpha-Al_2O_3$ phase boundary due to an enhanced $CO_2$ escaping through the pore channels of the $\alpha-Al_2O_3$ support layer. In the present paper, it will be emphasized that a hybridization of a membrane with an adsorbent can provide a key to break through the trade-off between permeance and separation factor, generally shown in a membrane separation.