• 제목/요약/키워드: Energy Diffusion

검색결과 1,547건 처리시간 0.033초

Soild-state reaction in Ti/Ni multilayers

  • 이주열;이영백;김태하;김기원
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 1999년도 제17회 학술발표회 논문개요집
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    • pp.140-140
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    • 1999
  • Ti/Ni multilayered films (MLF) are ideal for neutron optics particularly in neutron guides and focusing devices. This system also possesses the tendency of amorphization through a solid-state reaction (SSR). This behaviors are closely related to the electronic structures and both magneto-optical (MO) and optical properties of metals depend strongly on their electron energy structures. Mutual inter-diffusion of the Tin and Ni atoms in the MLF caused by a low temperature annealing should decrease the thickness of pure Ni, as well as change the chemical and atomic order in the reactive zone. The application of the MO spectroscopy to the study of SSR in the MLF allows us to obtain an additional information on the changes in the atomic and chemical orders in the interface region. The optical one has no restriction on the magnetic state of the constituent sublayers. Therefore, the changes in magnetic, MO and optical properties of the Ti/Ni MLF due to SSR can be expected. To the best of our knowledge, the MO and optical spectroscopies were not used for this purpose. SSR has been studied in the series of the Ti/Ni MLFs with bilayer periods of 0.65-22.2nm and constant ratio of the Ti to Ni sublayers thickness by using MO and optical spectroscopies as well as an x-ray diffraction. The experimental MO and optical spectra are compared with the computer-simulated spectra, assuming various interface models. The relative changes in the x-ray diffraction spectra and MO properties of the Ti/Ni MLF caused by annealing are bigger for the multilayers with "thick" sublayers, or the SSR with the formation of amorphous alloy takes place mainly in the Ti/Ni multilayers with "thick" sublayers, while in the nominal threshold thickness of the Ni-sublayer for the observation of the equatorial Kerr effect in the as-deposited and annealed Ti/Ni MLFs of about 3.0 and 4.5nm thick is explained by the formation of amorphous alloy during the deposition or the formation of the nonmagnetic alloyed regions between pure components as a result of the SSR. For the case of Ti/Ni MLF the MO approach is more sensitive for the determination of the thickness of the reacted zone, while x-ray diffraction is more useful for structural analyses.structural analyses.

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이론과 실천으로서의 전환 : 네덜란드의 전환이론과 전환정책 (Transition as a Theory and Practice: Transition Studies and Policies in Netherlands)

  • 정병걸
    • 과학기술학연구
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    • 제15권1호
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    • pp.109-143
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    • 2015
  • 최근 혁신의 지속과 성공을 위해 기술혁신시스템을 어떻게 바꿀지가 중요한 논제로 등장했다. 실천적, 이론적 차원에서 혁신시스템의 변화에 관심이 높아지고 있는 시점에서 네덜란드의 전환은 큰 주목을 받고 있다. 네덜란드의 전환정책은 시스템의 근본적 변화를 추구하면서도 기존의 변화와는 상당히 다른 접근과 방식을 취하고 있기 때문이다. 대표적 전환으로는 지속가능한 에너지 전환, 생물다양성과 자연자원의 지속가능한 활용으로의 전환, 지속가능한 농업으로의 전환, 지속가능한 교통 등이 있다. 장기적 변화라는 점에서 네덜란드의 전환은 여전히 초기단계지만 전환에 대한 공감 확산, 적대적 행위자 간 연합 형성, 다양한 전환 네트워크의 형성이라는 긍정적 효과가 나타나고 있다. 하지만 여전히 해결이 필요한 문제도 있다. 이론과 실제의 연계, 전환 개념의 추상성과 모호성 극복, 장기적 비전과 단기적 행위의 연결, 폭넓은 민주적 참여 확보, 현존 레짐의 저항 극복, 집행 문제, 정부 내에서 전환에 대한 지지 확산의 문제 등이다. 이런 문제에도 불구하고 네덜란드의 전환은 시스템의 근본적 변화가 필요한 시점에서 많은 교훈을 주고 있다. 따라서 기존 시스템과 레짐에 의한 고착화를 해결하고 구조적 변화를 이끌어 내기 위해 네덜란드의 전환이론과 정책에서 배울 필요가 있다.

A Study of the Diffusion and Rise of Stack Plumes at Coastal Region by Using LIDAR Observation Data

  • Yoon, Ill-Hee
    • International Union of Geodesy and Geophysics Korean Journal of Geophysical Research
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    • 제26권1호
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    • pp.43-58
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    • 1998
  • The Kwinana Shoreline Fumigation Experiment (KSFE) took place at Fremantle, WA, Australia between January 23 and February 8, 1995. The CSIRO DAR LIDAR measured plume sections from near the Kwinana Power Station (KPS) stacks to up to about 5 km downstream. It also measured boundary layer aerosols and the structure of the boundary layer on some occasions. Both stages A and C of KPS were used as tracers at different times. The heart of the LIDAR system is a Neodymium-doped Yttrium-aluminum-garnet (Nd:YAG) laser operating at a fundamental wavelength of 1064 nm, with harmonics of 532 nm and 355 nm. For these experiments the third harmonic was used because the UV wavelength at 355 nm is eye safe beyond about 50 m. The laser fires a pulse of light 6 ns in duration (about 1.8 m long) and with an energy (at the third harmonic) of about 70 mJ. This pulse subsequently scattered and absorbed by both air molecules and particles in the atmosphere. A small fraction of the laser beam is scattered back to the LIDAR, collected by a telescope and detected by a photo-multiplier tube. The intensity of the signal as a function of time is a measure of the particle concentration as a function of distance along the line of the laser shot. The smoke plume was clearly identifiable in the scans both before and after fumigation in the thermal internal boundary layer (TIBL). Both power station plumes were detected. Over the 9 days of operation, 1,568 plumes scans (214 series) were performed. Essentially all of these will provide instantaneous plume heights and widths, and there are many periods of continuous operation over several hours when it should be possible to compile hourly average plume statistics as well. The results of four days LIDAR observations of the dispersion of smoke plume in the TIBL at a coastal site are presented for the case of stages A and C.

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분진필터링 적용을 위한 SiC 섬유의 고온 열화분석 (Degradation analysis of SiC fiber at elevated temperature for dust filtering applications)

  • 주영준;박청호;허스에르덴;김철진
    • 한국결정성장학회지
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    • 제27권1호
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    • pp.28-33
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    • 2017
  • SiC 섬유는 $1800^{\circ}C$까지 불활성과 공기 분위기에서 융해나 산화 문제 없이 사용할 수 있다. SiC 섬유는 분진 필터링 공정의 백필터로 상업화된 산업용 백 필터보다 훨씬 높은 온도인 $500^{\circ}C$ 이상의 온도에서 사용이 가능하다. 하지만 제강 산업과 화력발전소의 극한 환경에서 미세 분진과의 반응으로 인한 SiC 섬유의 열화에 대한 연구는 부족하다. 따라서 본 실험에서는 SiC 섬유를 제강 분진, 화력발전소 분진과 $500^{\circ}C$ 이상의 고온에서 반응시켜 섬유 표면의 열화된 형상을 SEM으로 관찰하고 섬유 표면 및 내부로의 산소 확산의 정도를 EDS로 분석하였다.

Electrochemical Behavior of Nanostructured Fe-Pd Alloy During Electrodeposition on Different Substrates

  • Rezaei, Milad;Haghshenas, Davoud F.;Ghorbani, Mohammad;Dolati, Abolghasem
    • Journal of Electrochemical Science and Technology
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    • 제9권3호
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    • pp.202-211
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    • 2018
  • In this work, Fe-Pd alloy films have been electrodeposited on different substrates using an electrolyte containing $[Pd(NH_3)_4]^{2+}$ (0.02 M) and $[Fe-Citrate]^{2+}$ (0.2 M). The influences of substrate and overpotential on chemical composition, nucleation and growth kinetics as well as the electrodeposited films morphology have been investigated using energy dispersive X-ray spectroscopy (EDS), current-time transients, scanning electron microscopy (SEM), atomic force microscopy (AFM) and X-ray diffraction (XRD) patterns. In all substrates - brass, copper and sputtered fluorine doped tin oxide on glass (FTO/glass) - Fe content of the electrodeposited alloys increases by increasing the overpotential. Also the cathodic current efficiency is low due to high rate of $H_2$ co-reduction. Regarding the chronoamperometry current-time transients, it has been demonstrated that the nucleation mechanism is instantaneous with a typical three dimensional (3D) diffusion-controlled growth in the case of brass and copper substrates; while for FTO, the growth mode changes to 3D progressive. At a constant overpotential, the calculated number of active nucleation sites for metallic substrates is much higher than that of FTO/glass; however by increasing the overpotential, the number of active nucleation sites increases. The SEM micrographs as well as the XRD patterns reveal the formation of Fe-Pd alloy thin films with nanostructure arrangement and ultra-fine grains.

A Study on Improvement and Degradation of Si/SiO2 Interface Property for Gate Oxide with TiN Metal Gate

  • Lee, Byung-Hyun;Kim, Yong-Il;Kim, Bong-Soo;Woo, Dong-Soo;Park, Yong-Jik;Park, Dong-Gun;Lee, Si-Hyung;Rho, Yong-Han
    • Transactions on Electrical and Electronic Materials
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    • 제9권1호
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    • pp.6-11
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    • 2008
  • In this study, we investigated effects of hydrogen annealing (HA) and plasma nitridation (PN) applied in order to improve $Si/SiO_2$ interface characteristics of TiN metal gate. In result, HA and PN showed a positive effect decreasing number of interface state $(N_{it})$ respectively. After FN stress for verifying reliability, however, we identified rapid increase of $N_{it}$ for TiN gate with HA, which is attributed to hydrogen related to a change of $Si/SiO_2$ interface characteristic. In contrast to HA, PN showed an improved Nit and gate oxide leakage characteristic due to several possible effects, such as blocking of Chlorine (Cl) diffusion and prevention of thermal reaction between TiN and $SiO_2$.

리튬 전지용 $MnO_2$ Cathode의 제조 및 전기화학적 특성 (The Preparation and Electrochemical Properties of $MnO_2$ Cathode for Lithium Rechargeable Battery)

  • 유영한;김영재;박준기;서부완;정인성;김주승;박복기;구할본;문성인
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1996년도 하계학술대회 논문집 C
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    • pp.1682-1684
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    • 1996
  • Recently, because diffusion of cordless machine and smart card and so on, and concern of unpolluted materials, one are concerned with Li secondary batteries. Li secondary batteries have high voltage, high energy density and high power density, and heavy metal pollution problems are little. Mn is low price and is distributed much quantity. Therefore, we investigated $MnO_2$. In this study, we worked the electrochemical properties and charge/discharge characteristics of $MnO_2/Li$ cells. In results, the more heating temperature is high, the more ${\gamma}-phase$ varied ${\beta}-phase$, and when $MnO_2$ is heated at $320^{\circ}C$ and super-s-black 20wt% is mixed, characteristics are the best.

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미세혈관 문합 후 순환계 질환 개선을 위한 원적외선 치료기의 열적 특성 평가 (Evaluation of Thermal Properties for the Far Infrared Therapy After Microvascular Anastomosis for the Treatment of Circulatory Diseases)

  • 양영규;오승현;김철웅
    • 대한기계학회논문집 C: 기술과 교육
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    • 제1권2호
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    • pp.179-186
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    • 2013
  • 혈액순환촉진, 심혈관계치료, 피부질환, 암세포억제 등의 의료분야에 원적외선 치료법이 광범위하게 활용되고 있다. 본 연구에서는 원적외선 치료에 효과적인 패널형 방사체의 발열부에 대한 열적 특성을 실험적으로 분석하였다. 발열선은 정상상태에서 절연피복에 $150mW/m^2$의 열유속으로 열에너지를 공급하여 절연피복은 발열선 온도의 20%에 도달하였다. 단열막 사용은 약 20%의 발열판 표면온도 증가효과가 있었으며 열시상수를 상승시켜 혈액순환촉진에 크게 기여하는 것으로 나타났다. 발열선의 배치간격이 발열부 설계에 중요한 인자이며 열확산의 중첩을 위해 발열판의 열전도계수와 밀도를 고려해야함을 알 수 있었다.

비정상 소화 과정에서의 화염 온도 및 OH 라디칼의 변화 (Changes of the Flame Temperature and OH Radical in the Unsteady Extinction Process)

  • 이은도;이기호;오광철;신현동
    • 대한기계학회논문집B
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    • 제28권12호
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    • pp.1557-1566
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    • 2004
  • A flame extinction phenomenon is a typical unsteady process in combustion. Flame extinction is characterized by various physical phenomena, such as convection, diffusion, and the production of heat and mass. Flame extinction can be achieved by either increasing the strain rate or curvature, by diluting an inert gas or inhibitor, or by increasing the thermal or radiant energy loss. Though the extinction is an inherently transient process, steady and quasi-steady approaches have been used as useful tools for understanding the flame extinction phenomenon. Recently, unsteady characteristics of flames have been studied by many researchers, and various attempts have been made to understand unsteady flame behavior, by using various extinction processes. Representative parameters for describing flame, such as flame temperature, important species related to reactions, and chemi-luminescence of the flame have been used as criterions of flame extinction. In these works, verification of each parameter and establishing the proper criterions of the extinction has been very important. In this study, a time-dependent flame temperature and an OH radical concentration were measured using optical methods, and the instantaneous change of the flame luminosity was also measured using a high-speed ICCD (HICCD) camera. We compare the unsteady extinction points obtained by three different methods, and we discuss transient characteristics of maximum flame temperature and OH radical distribution near the extinction limit.