• Title/Summary/Keyword: Elongation Structure

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An Experimental Study for Electro-active Polymer Electrode and Actuator (전기활성 고분자 전극 및 구동기에 관한 실험적 연구)

  • Lee, Jun-Man;Ryu, Sang-Ryeoul;Lee, Dong-Joo;Lin, Zheng-Jie
    • Composites Research
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    • v.26 no.5
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    • pp.289-294
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    • 2013
  • A thinner is used to improve the multi-walled carbon nano-tube (CNT) and carbon black (CB) dispersion in a polymer matrix and to make a soft electrode. The electrical and mechanical properties of the soft electrodes are investigated as functions of CNT, CB and thinner content. The optimal mixing condition for the electrode is thinner 80, CNT 3.5, CB 18 (phr) on the basis of matrix (KE-12). The specific resistance of that is 73 (${\Omega}{\cdot}cm$), and tensile strength, tensile modulus, and elongation of that is 0.45 MPa, 0.21 MPa, and 184%, respectively. Also, a simple structure of the actuator with an optimized electrode and elastomer is fabricated and its characteristic is evaluated. At the operating voltage 25 kV, the displacement of an elastomer KE-12 is 2.24 mm, and that of an elastomer KE-12 with thinner 50 (phr) is 4.05 mm. It shows a higher displacement compared to that of 3M 4910 which has similar modulus. The actuator made with elastomer and electrode of the same material (KE-12) may have advantages for fatigue life and application.

Preparation and Characterization of PVdF Microporous Membranes with PEG Additive for Rechargeble Battery (Poly(ethylene glycol)를 첨가한 이차전지용 poly(vinylidene fluoride) 미세다공성 분리막의 제조와 물성)

  • Nam, Sang-Yong;Jeong, Mi-Ae;Yu, Dae-Hyun;Koh, Mi-Jin;Rhim, Ji-Won;Byun, Hong-Sik;Seo, Myung-Su
    • Membrane Journal
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    • v.18 no.1
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    • pp.84-93
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    • 2008
  • Poly(vinylidene fluoride) has received much attention in the last several years for the lithium secondary batteries. In this study, to enhance the porosity, PVdF was prepared by phase inversion method using as an additive, PEG (poly(ethylene glycol)), with N,N-dimethylformamid as a solvent. The pores are generated during the solvent and non-solvent exchange process in the coagulation bath filled with non-solvent (distilled water). The surface and cross-section of the membranes were observed with a scanning electron microscopy (SEM). The mechanical property of the membrane was determined by using an universal testing machine (UTM) and thermal property was verified by heat shrinkage. Uniformed sponge structure of PVdF-PEG membrane for the lithium secondary batteries was prepared with 10 wt% of PEG concentration in the PVdF-PEG solution. Porosity, elongation and tensile strengh of the membrane were 87%, 75.45%, and 275. 27 MPa respectively.

Mechanical and Oxygen Permeation Properties of Layered Double Hydroxide/Ethylene Vinyl Acetate Nanocomposite Membranes (Mg-Al Layered Double Hydroxide/Ethylene Vinyl Acetate 나노복합막의 기계적 특성과 기체투과 특성에 관한 연구)

  • Hwang, Ji-Young;Lee, Sang-Hyup;Lee, Jong-Suk;Hong, Se-Ryung;Lee, Hyun-Kyung
    • Membrane Journal
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    • v.23 no.2
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    • pp.151-158
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    • 2013
  • The effect of layered double hydroxides (LDH) on the gas separation properties of ethylene vinyl acetate copolymer was investigated. Mg-Al LDH/EVA nanocomposite membranes were prepared from solution intercalation using organically modified LDH (DS-LDH). Dodecyl sulfate (DS)-LDH was obtained by the intercalation of DS anion in the interlayer. The nanocomposite structure has been elucidated by X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy and scanning electron microscopy (SEM). XRD pattern clearly shows that the DS-LDH layers are disorderly well dispersed in the EVA matrix. The maximum tensile strength and elongation of the LDH/EVA nanocomposite membrane were found with the LDH content 3 wt%. The thermal properties of nanocompostie membrane were enhanced by the incorporation of LDH in EVA matrix. Gas permeation of LDH/EVA nanocomposite membranes with LDH contents of 1, 3, 5 wt% was studied for $O_2$ and $CO_2$ single gases. The presence of 3 wt% LDH decreased $O_2$ permeability by up to 53% compared to the EVA membrane. In spite of barrier property of nanocomposite membrane, however, the gas permeability for $CO_2$ was increased due to its strong affinity with the residual OH groups on the LDH.

Transcriptional Regulation of Genes by Enhancer RNAs (인핸서 RNA에 의한 유전자 전사 조절)

  • Kim, Yea Woon;Kim, AeRi
    • Journal of Life Science
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    • v.26 no.1
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    • pp.140-145
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    • 2016
  • Genes in multicellular organisms are transcribed in development, differentiation, or tissue-specific manners. The transcription of genes is activated by enhancers, which are transcription regulatory elements located at long distances from the genes. Recent studies have reported that noncoding RNAs are transcribed from active enhancers by RNA polymerase II (RNA Pol II); these are called enhancer RNAs (eRNAs). eRNAs are transcribed bi-directionally from the enhancer core, and are capped on the 5’ end but not spliced or polyadenylated on the 3’ end. The transcription of eRNAs requires the binding of transcription activators on the enhancer and associates positively with the transcription of the target gene. The transcriptional inhibition of eRNAs or the removal of eRNA transcripts results in the transcriptional repression of the coding gene. The transcriptional procedure of eRNAs causes enhancer- specific histone modifications, such as histone H3K4me1/2. eRNA transcripts directly interact with Mediator and Rad21, a cohesin subunit, generating a chromatin loop structure between the enhancer and the promoter of the target gene. The recruitment of RNA Pol II into the promoter and its elongation through the coding region are facilitated by eRNAs. Here, we will review the features of eRNAs, and discuss the mechanism of eRNA transcription and the roles of eRNAs in the transcriptional activation of target genes.

Preparation and characterization of poly(dimethylsiloxane) foam prepared by hydrogen condensation reaction (수소 축합 반응에 의한 폴리디메틸실록산 미세 발포체의 제조 및 물성분석 연구)

  • Lee, Soo;Moon, Sung Jin
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.4
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    • pp.802-812
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    • 2016
  • Silicone foam is very useful as flame resistant material for many industrial areas such as high performance gasketing, thermal shielding, vibration mounts, and press pads. A silicone foam was prepared through simultaneous crosslinking and foaming by hydrogen condensation reaction of a vinyl-containing polysiloxane (V-silicone) and a hydroxyl-containing polysiloxane (OH-silicone) with hydride containing polysiloxane (H-silicone) in the presence of platinum catalyst and imorganic filler at room temperature. This is more convenient process for silicone foam manufacturing than the conventional separated crosslinking and foaming systems. Funtionalized silicones we used in this experiment were consisted with a V-silicone containing 1,0 meq/g of vinyl groups and a viscosity of 20 Pa-s, an OH-silicone with 0.4 meq/g of hydroxyl groups and a viscosity from 50 Pa-s, and an H-silicone containing 7.5 meq/g of hydride groups and a viscosity of 0.06 Pa.s. The effects of compositions of functionalized silicones and additives, such as catalyst and filler on the structure and mechanical properties of silicone foam were studied. 0.5 wt% of Pt catalyst was enough to accelerate the foaming rate of silicone resins. The addition of OH-silicone with lower viscosity accelerates the initial foaming rate and decreases the foam density, but the addition of V-silicone with lower viscosity reduces the tensile strength as well as the elongation. The final foam density, tensile strength, and elogation of silicone foam prepared under the SF-3 condition increase maximum to $0.58g/cm^3$, $3,51kg_f/cm^2$, and 176 %, repectively. We found out the filler alumina also played an important role to improve the mechanical properties of silicone foams in our foaming system.

Relationships of Physiologieal Activity and Anatomical Structure to the Wilting Phenomena in Rice Plant 1. Reappearance of the Wilting Phenomena concerning to Physiological Aspects and Environment (수도품종의 위고현상과 생리 및 형태해부학적 구조와의 관련성에 관한 연구)

  • ;Jong-Hoon Lee
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.25 no.1
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    • pp.1-7
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    • 1980
  • In 1976, a newly released rice variety, Yushin, was planted in 300,000 ha of the 533,000 ha of cultivated total hecterage with new rice varieties. High productivity and quality were achieved by farmers around country. However, the wilting phenomena of Yushin occured in some regions where were employed poor cultural management, and flowed sewage into the paddy field from industrial factories. This study was identified some factors for the wilting phenomena of Yushin rice variety in morphological and physiological aspects. The Yushin variety showed greater internode elongation on low part of the stems that close related to lodge at heavier nitrogen levels, excessive number of spikelets per unit leaf blade weight i.e. higher sink/source ratio, and greater consumption of respiratory substrate by increased respiration rate of rice plant as compared with those of Tongil rice variety. In physilogical aspects, the Yushin variety was significantly declined root development and root activities under heavy nitrogen conditions. Yushin rice variety was decreased $K_2$O/N ratio, carbohydrate content in stem of rice plant, and physiological root activities specially in low light intensity, 50% light interception plots. Therefore, above factors were mainly promoted the wilting phenomena of Yushin rice variety.

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The Development of High Pressure Long Distance Fire-fighting Hose with Phosphorescent Performance (축광 성능을 갖는 고압용 장거리 호스 개발에 관한 연구)

  • Han, Yong-Taek;Na, Byung-Gyun;Choi, Jin-Seong;Min, Se-Hong
    • Fire Science and Engineering
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    • v.31 no.5
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    • pp.63-69
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    • 2017
  • This study describes the development of a long-distance hose for ultra-high pressure operation, which can be used in conjunction with an ultra-high pressure pump and can be effectively applied to the fire suppression of high-rise buildings and a long, large tunnels. Also, it has phosphorescent properties, which can help to secure the withdrawal route of the fire-fighters when they are threatened by the fire. We developed an ultra-high pressure hose aiming at a pressure of 3 MPa and a flow rate of 2000 lpm and developed an ultra-high pressure fire hose that can withstand this very high pressure by using a double jacket, triple polyurethane coating and warf (Wp) of 52. In order to ensure the performance of the developed ultra-high pressure hose, its structure, appearance, leakage at high pressure, length and elongation were inspected by a certified certification agency, who also subjected it to a peeling test, friction test, breaking pressure test and free fall test. Also, it was studied in addition to the luminescent high-pressure hose for fire-fighting. In the phosphorescence test, the luminance measurement value was more than the reference value of the luminance test after 40 minutes, which confirmed that its performance was satisfactory for fire-fighting products. In the future, if such an ultra-high pressure fire hose were commercialized and applied in the field, it could contribute to securing improved fire suppression and safer exit from fires, as compared to the fire hoses currently used in the suppression of fires in skyscraper buildings and long tunnels.

Preparation and Properties of Polyurethanes Containing Polycarbonate Polyol/Bio Polyol for Wet Type Artificial Leather (폴리카보네이트 폴리올/바이오 폴리올을 이용한 습식 인조피혁용 폴리우레탄의 제조 및 물성)

  • Sur, Suk-Hun;Ko, Jae-Wang;Choi, Pil-Jun;Lee, Jae-Yeon;Lee, Young-Hee;Kim, Han-Do
    • Clean Technology
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    • v.25 no.2
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    • pp.114-122
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    • 2019
  • The synthesis of bio polyol from renewable resources has attracted attention in recent years. In particular, it is important to take advantage of bio polyols in the synthesis of polymers. In this study, a series of dimethylformamide (DMF) based polyurethanes were synthesized using polycarbonate polyol/bio polyol (PO3G: polytrimethylene ether glycol prepared from 1, 3-propanediol produced by fermentation from corn sugar), methylene diphenyl diisocyanate (MDI) and 1,4-butandiol (BD). The properties of prepared polyurethane films and the cell structure of wet type artificial leather were investigated. As the bio polyol content increased, the tensile strength of polyurethane films decreased, however, the elongation at break increased significantly. As a result of thermal characteristics analysis, the glass transition temperature of polyurethanes increased when increasing the content of polycarbonate polyol. As a result of comparing the cell characteristics of wet type artificial leathers prepared in this study, it was found that the number and uniformity of cells formed in the artificial leather samples increased when increasing the content of polycarbonate polyol in polycarbonate polyol/bio polyol. From these results, it was found that DMF-based polyurethane containing an appropriate amount of bio polyol could be used for wet type artificial leather. The bio textile analysis system according to ASTM standard was used to measure the bio carbon content of polyurethane. The content of bio carbon increased proportionally with the increase of bio polyol content used in polyurethane synthesis.

Low-Temperature Characteristics of Type 4 Composite Pressure Vessel Liner according to Rotational Molding Temperature (타입 4 복합재 압력용기 라이너의 회전 성형 온도에 따른 저온 특성)

  • Jung, Hong-Ro;Park, Ye-Rim;Yang, Dong-Hoon;Park, Soo-Jeong;Kim, Yun-Hae
    • Composites Research
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    • v.35 no.3
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    • pp.147-152
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    • 2022
  • Low-temperature characteristics according to internal temperature conditions during rotational molding of Type 4 pressure vessel liners were studied in this paper. Since rotational molding has a sensitive effect on the formability of the liner depending on the temperature conditions, the temperature conditions for the polyamide used should be accurately set. The structural changes of polyamide as the liner material was analyzed the surface by atomic force microscope (AFM), and the crystallinity measured with a differential scanning calorimeter (DSC) is used to evaluate the change of the mechanical strength value at low temperature. In addition, the formability of the liner was confirmed by observation of the yellow index inside the liner. As a result, as the melting range of the internal temperature becomes wider, the yellow index shows a lower value, and the elongation and impact characteristics at low temperatures are improved. It was also confirmed that the structure of the polyamide was uniform and the crystallinity was high by AFM and DSC. These experimental results contribute to the improvement of characteristics at low temperatures due to changes in temperature conditions during rotational molding.

Preparation and Characterization of Sodium Caseinate (CasNa)/Transglutaminase (TG)-coated Papers for Packaging (포장용 Sodium Caseinate(CasNa)/Transglutaminase(TG) 코팅지 제조 및 특성 분석)

  • Hwang, Jihyeon;Kim, Dowan
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.28 no.2
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    • pp.81-87
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    • 2022
  • Paper is a promising alternative to petroleum-based plastic materials for sustainable packaging applications. However, paper exhibits poor gas and water vapor barrier properties, which restrict its effective application in the packaging industry. To enhance the properties of papers, sodium caseinate (CasNa)/transglutaminase (TG) coating solutions with various TG contents were prepared and coated on the papers. The chemical and morphological structures, mechanical properties, seal strength, and water vapor barrier properties of the coated papers were thoroughly investigated. The paper properties depended significantly on the chemical and morphological structures. Pristine CasNa and CasNa/TG coating solutions were evenly coated on the paper surfaces, without any cracks. The chemical structure of the CasNa/TG coated papers was slightly influenced by TG addition, resulting in increased elongation at break and enhanced water barrier properties. To promote the use of CasNa-coated papers in packaging applications, additional investigations must be performed to prevent gas and moisture permeation and enhance the mechanical strength of these papers via chemical reactions and introduction of organic/inorganic composites.