• Title/Summary/Keyword: Elementary reaction

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Short Reaction Mechanism for Premixed CH4-Air Flames at High Pressure (고압에서 예혼합 CH4-Air 화염의 축소 반응 메카니즘)

  • Lee, Su-Gak;Lee, Ki-Yong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.6
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    • pp.647-653
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    • 2012
  • A short reaction mechanism for premixed $CH_4$-air flames at high pressure was developed using a reduction method based on the combined application of the simulation error minimization connectivity method and the iterative species-removal sensitivity method. It consisted of 43 species and 554 elementary reactions under the condition that it produces less than 5% of the maximum error. The flame structures obtained using a detailed reaction mechanism and the short reaction mechanism were compared for $CH_4$-air flames with various initial temperatures and equivalence ratios at high pressure, and the results were in good agreement. Therefore, the short reaction mechanism developed could reproduce the flame speeds, temperatures, and concentrations of major and minor species at high pressure.

A Computational Study about Effects of Operating parameters and EGR compositions on Autoignition Reactivity for DME HCCI Combustion

  • Jamsran, Narankhuu;Lim, Ocktaeck
    • 한국연소학회:학술대회논문집
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    • 2012.11a
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    • pp.305-307
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    • 2012
  • This study was computationally explored how the fuel autoignition reactivity was affected by operating parameters such as fuel, pressure, intake temperatures, engine speed and EGR compositions for HCCI combustion. This is done for DME and CHEMKIN-PRO was used as a solver. At first, influence of the operating parameters and EGR compositions were showed. And then, in order to clarify the mechanism of them on autoignition reactivity, data-sets of kinetic were analyzed to investigate the elementary reaction path for heat release at transient tempeatures by using contribution matrix.

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Ignition Delay Times in $C_2H_2-O_2$-Ar Mixture behind a Reflected Shock Wave

  • 류지철;서희;강준길;오규형
    • Bulletin of the Korean Chemical Society
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    • v.18 no.10
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    • pp.1071-1075
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    • 1997
  • Detonation characteristics of acetylene were studied behind reflected shock waves in the temperature range 800-1350 K by monitoring OH emission and pressure profiles. For a comprehensive measurement of ignition delay time, the mixture composition was varied in a wide range of Ar mole % was varied from 0.625 to 2.5 in stoichiometric ratio of C2H2-O2-Ar. A computer simulation study was also performed to elucidate the important elementary steps determining ignition behavior. The 33-reaction mechanism provides a good agreement in delay time between the observed and the calculated ones.

Teaching the Comprehension of Word Problems through Their Mathematical Structure in Elementary School Mathematics (초등수학에서 문장제의 수학적 구조 파악을 통한 문장제 이해 지도 방안)

  • Ra, Woo-Seong;Paik, Suck-Yoon
    • Journal of Elementary Mathematics Education in Korea
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    • v.13 no.2
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    • pp.247-268
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    • 2009
  • The purpose of this study was to examine the mathematical components of word problems and the structure of the components, to examine the characteristics of the understanding of mathematics high achievers about word problems, and ultimately to devise a teaching method geared toward facilitating learner understanding of the word problems. Given the findings of the study, the following conclusion was reached: First, word problems could be categorized according to their mathematical components, namely the mathematical structure of multiple variables provided to learners for their problem solving. And learner's reaction might hinge on the type of word problems. Second, the mathematics high achievers relied on diverse strategies to understand the mathematical components of word problems to solve the problems. The use of diverse strategies made it possible for them to succeed in problem solving. Third, identifying the characteristics of the understanding of the mathematics high achievers about word problems made it possible to layout successful lesson plans that stressed understanding of the mathematical structure of word problems. And the teaching plans enabled the learners to get a better understanding of the given word problems.

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Onset and Propagation of Hydrogen-Air Premixed Flame with Multiple Kinetics (다단 반응을 고려한 수소-공기 예혼합 화염의 발생 및 전파)

  • Han Cho Young;Baek Seung Wook
    • Journal of computational fluids engineering
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    • v.9 no.1
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    • pp.25-33
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    • 2004
  • Flame onset and propagation within hydrogen premixed gas mixture are numerically investigated in an rectangular enclosure. A detailed chemistry for hydrogen reaction is applied to anticipate the thermochemical behavior of intermediate species appropriately. To facilitate computation, 10 species and 16 elementary reaction steps for hydrogen combustion are taken into account. On the basis of 30% of hydrogen concentration in hydrogen-air mixture, the effects of position and quantity of ignition sources on the flame evolution are analyzed. From the simulation results, the methods to decrease the potential hazard caused by the flame propagation are suggested.

An Analysis of Reaction Time in the Perception of Korean and English Words Utilizing the E-Prime Program

  • Cha, Kyung-Whan;Youn, Young-Chul;Yu, Hyeon;Shim, Jae-Hwang
    • Speech Sciences
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    • v.14 no.1
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    • pp.63-72
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    • 2007
  • In this study, the researchers evaluate the hypothesis that the reaction time (RT) in the brain is largely dependent on age and gender. The researchers tested English and Korean words using two types: reading as visual stimuli, and listening as auditory stimuli. The E-Prime program installed in functional magnetic resonance imaging (f-MRI) was used. There are 136 Korean subjects in three groups: 30 children (5th and 6th grade elementary school students), 76 young adults (college students), and 30 adults (35-53 years old). In the listening test, the variation for the two languages was different among the three age groups, regardless of gender, whereas the data did not show meaningful differences in the reading test. The findings will provide some meaningful information regarding perception and acquisition of a foreign language.

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Identification of L-Ascorbic Acid 2-Ο-$\alpha$-Glucoside, a Stable Form of Ascorbic Acid, in Kimchi

  • JUN, HONG-KI;KYUNG-MI BAE;YOUNG-HEE KIM
    • Journal of Microbiology and Biotechnology
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    • v.8 no.6
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    • pp.710-713
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    • 1998
  • A material with the same high performance liquid chromatography (HPLC) retention profile as authentic ascorbic acid 2-Ο-$\alpha$-glucoside (AA-2G) was detected in kimchi. This material was identified as AA-2G by testing its susceptibility to $\alpha$-glucosidase hydrolysis, the HPLC profile, and through the elementary analysis. Among several strains of bacteria isolated from fermented kimchi, four strains could produce cydodextrin glucanotransferase (CGTase) which catalyzes the transglucosylation reaction of ascorbic acid. By using starch as the glycosyl donor, AA-2G was produced as the major product through this reaction.

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Flame Propagation within Hydrogen Premixed Gas mixture According to Ignition Condition (점화 조건에 따른 수소 예혼합기에서의 화염 전파)

  • Han, Cho-Young;Kim, Jeong-Soo;Lee, Kyun-Ho;Kim, Byung-Kyo
    • Proceedings of the KSME Conference
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    • 2003.11a
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    • pp.350-355
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    • 2003
  • Flame onset and propagation within hydrogen premixed gas mixture are numerically investigated in an rectangular enclosure. A detailed chemistry for hydrogen reaction is applied to anticipate the thermochemical behavior of intermediate species appropriately. To facilitate computation, 10 species and 16 elementary reaction steps for hydrogen combustion are taken into account. On the basis of 30 % of hydrogen concentration in hydrogen-air mixture, the effects of position and quantity of ignition sources on the flame evolution are analyzed. From the simulation results, the means that can lessen the possible hazard caused by flame propagation are suggested.

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Chemical Mechanism Reduction and Validation of Methyl Butanoate by Automatic Reduction Procedure (Methyl Butanoate의 상세 화학 반응 메커니즘 자동 축소화를 통한 기초 반응 메커니즘의 생성 및 검증)

  • Lee, Youngjae;Huh, Kang Y.
    • Journal of the Korean Society of Combustion
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    • v.21 no.3
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    • pp.16-23
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    • 2016
  • In this study, skeletal mechanisms are produced by directed relation graph with specified threshold value and sensitivity analysis based on species database from the directed relation graph. Skeletal mechanism is optimized through the elimination of unimportant reaction steps by computational singular perturbation importance index. Reduction is performed for the detailed mechanism of methyl butanoate consisting of 264 species and 1219 elementary reactions. Validation shows acceptable agreement for auto-ignition delays in wide parametric ranges of pressure, temperature and equivalence ratio. Methyl butanoate has been proposed as a simple biodiesel surrogate although the alkyl chain consists of four carbon atoms. The resulting surrogate mechanism for n-heptane and MB consists of 76 species and 226 reaction steps including those for NOx.

Numerical Studies on the Combustion Characteristics and Pollutant Formation for the DME Fueled Diesel Engine (DME 연료 디젤엔진의 연소 및 공해물질 배출 특성 해석)

  • Yu, Yong-Wook;Lee, Jeong-Won;Kim, Yong-Mo
    • Journal of ILASS-Korea
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    • v.13 no.1
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    • pp.28-33
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    • 2008
  • The present study is mainly motivated to investigate the vaporization, auto-ignition and combustion processes in high-pressure diesel engines. In order to realistically simulate the dimethyl ether (DME) fueled diesel engine, the high pressure vaporization model is utilized and the interaction between turbulence and chemistry is treated by employing the Representative Interactive Flamelet (RIF) model. The detailed chemisty consisted of 336 elementary reaction steps and 78 species is used for DME/air reaction. Numerical results indicate that the RIF model with high pressure vaporization model successfully predicts the essential feature of the combustion processes and pollutants formations in the DME fueled diesel engines.

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