• Title/Summary/Keyword: Electron Flow

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FORMULATION AND STABILITY TEST OF ANTIAGING CREAM CONTAINING METHANOL FRACTION OIL OF PANGIUM EDULE.REINW. AS A RADICAL SCAVENGER AGENT

  • Djajadisastra, J.;Anwar, E.;Milani, E.
    • Proceedings of the SCSK Conference
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    • 2003.09b
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    • pp.303-306
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    • 2003
  • Indonesia is a tropical country having a temperature range of 25-35$^{\circ}C$ which can affect the skin and causes damages like aging. This aging process is due, at least, to free radical reactions. For this reason, many attempts had been done to find out creams containing natural antioxidant compound which have a potential of free radical scavenger. Kluwek, a fermented form of foot ball fruit or picung (Pangium edule.Reinw), had been proved to contain antioxidant compound in its methanol fraction oil to which antiaging cream was formulated. Stability evaluation was conducted for cream with Kluwek oil compared to base cream, including organoleptic (colour and odour), pH, viscosity, particle size, centrifugation test and flow characteristics either in room temperature (27$^{\circ}C$) or stress condition (4$^{\circ}C$ and 5$0^{\circ}C$) for 8 weeks continuously, and six times cycling test at 4$^{\circ}C$ and 5$0^{\circ}C$ every 24 hours. The results showed that cream with Kluwek oil and base cream were stable at temperature 27 and 4$^{\circ}C$, cycling test and centrifugation test, but not stable at 5$0^{\circ}C$. Free radical evaluation was done by Electron Spin Resonance and the result showed that cream with Kluwek oil had less free radicals compared to base cream.

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Study on Fluid Distribution in Slot-die Head Using CFD (CFD를 이용한 슬롯 다이 헤드 내부의 유체 분포 분석)

  • Yoo, Suho;Kim, Gieun;Shin, Youngkyun;Park, Jongwoon
    • Journal of the Semiconductor & Display Technology
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    • v.21 no.4
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    • pp.39-44
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    • 2022
  • Using a CFD (computational fluid dynamics) simulation tool, we have offered a design guideline of a slot-die head having a simple T-shaped cavity through an analysis of the fluid dynamics in terms of cavity pressure and outlet velocity, which affect the uniformity of coated thin films. We have visualized the fluid flow with a transparent slot-die head where poly(3,4-ethylenedioxythiophene):poly(4-styrenesulfonate) (PEDOT:PSS) is injected. We have shown that the fluid dynamics inside the slot-die head depends sensitively on the cavity depth, cavity length, land length, and channel gap (i.e., shim thickness). Of those, the channel gap is the most critical parameter that determines the uniformity of the pressure and velocity distributions. A pressure drop inside the cavity is shown to be reduced with decreasing shim thickness. To quantify it, we have also calculated the coefficient of variation (CV). In accordance with Hagen-Poiseuille's laws and electron-hydraulic analogy, the CV value is decreased with increasing cavity depth, cavity length, and land length.

Study on the Separation of N2/SF6 Mixture Gas Using Polyimide Hollow Fiber Membrane (폴리이미드 중공사 막을 이용한 N2/SF6 혼합기체 분리에 관한 연구)

  • Kim, Dae-Hoon;Kim, Guang-Lim;Jo, Hang-Dae;Park, Jong-Soo;Lee, Hyung-Keun
    • Korean Chemical Engineering Research
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    • v.48 no.5
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    • pp.660-667
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    • 2010
  • In this research polyimide, Matrimid 5218, hollow fiber membrane was used to recover sulfur hexafluoride($SF_6$) which is one of the six greenhouse gases from $N_2/SF_6$ mixture gas. Fibers were spun from using dry-wet phase inversion method. The module was manufactured by fabricating fibers after surface coating with silicone elastomer. The scanning electron microscopy(SEM) studies showed that the produced fibers typically had an asymmetric structure; a dense top layer supported by a sponge-like substructure. The developed module had a permeance of 0.78-1.36 GPU for $N_2$ with $N_2/SF_6$ selectivity of 2.44-5.08 at various pressure and temperature. For recovery of $SF_6$, a membrane module and 10 vol.% $SF_6$ from $N_2/SF_6$ mixture gas was used. The effects of various operating condition such as pressure, temperature, and retentate side flow rate were tested. When pressure and temperature were increased and retentate flow rate was decreased, the $SF_6$ purity in recovered gas was increased up to 37.5 vol.% with decreasing recovery ratio. When retentate flow rate was increased pressure and temperature was decreased, the $SF_6$ recovery ratio in retentate side was increased up to 89% with decreasing the $SF_6$ purity in retentate side.

The Influence of Oxygen Gas Flow Rate on Growth of Tin Dioxide Nanostructures (이산화주석 나노구조물의 성장에서 산소가스 유량이 미치는 영향)

  • Kim, Jong-Il;Kim, Ki-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.10
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    • pp.1-7
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    • 2018
  • Tin dioxide, $SnO_2$, is applied as an anode material in Li-ion batteries and a gas sensing materials, which shows changes in resistance in the presence of gas molecules, such as $H_2$, NO, $NO_2$ etc. Considerable research has been done on the synthesis of $SnO_2$ nanostructures. Nanomaterials exhibit a high surface to volume ratio, which means it has an advantage in sensing gas molecules and improving the specific capacity of Li-ion batteries. In this study, $SnO_2$ nanostructures were grown on a Si substrate using a thermal CVD process with the vapor transport method. The carrier gas was mixed with high purity Ar gas and oxygen gas. The crystalline phase of the as-grown tin oxide nanostructures was affected by the oxygen gas flow rate. The crystallographic property of the as-grown tin oxide nanostructures were investigated by Raman spectroscopy and XRD. The morphology of the as-grown tin oxide nanostructures was confirmed by scanning electron microscopy. As a result, the $SnO_2$ nanostructures were grown directly on Si wafers with moderate thickness and a nanodot surface morphology for a carrier gas mixture ratio of Ar gas 1000 SCCM : $O_2$ gas 10 SCCM.

Laser-induced plasma emission spectra of halogens in the helium gas flow and pulsed jet (헬륨 가스 플로우와 가스 펄스 젯에서 할로겐족 원소들의 레이저유도 플라즈마 방출 스펙트럼)

  • Lee, Yonghoon;Choi, Daewoong;Gong, Yongdeuk;Nam, Sang-Ho;Nah, Changwoon
    • Analytical Science and Technology
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    • v.26 no.4
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    • pp.235-244
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    • 2013
  • Detection of halogens using laser-induced breakdown spectroscopy (LIBS) in open air is very difficult since their strong atomic emission lines are located in VUV region. In NIR region, there are other emission lines of halogens through electronic transitions between excited states. However, these lines undergo Stark broadening severely. We report the observation of the emission lines of halogens in laser-induced plasma (LIP) spectra in NIR region using a helium gas flow. Particularly, the emission lines of iodine at 804.374 and 905.833 nm from LIPs have been observed for the first time. In the helium ambient gas, Stark broadening of the emission lines and background continuum emission could be suppressed significantly. Variations of the line intensity, plasma temperature, and electron density with the helium flow rate was investigated. Detection of chlorine and bromine in flame retardant of rubbers was demonstrated using this method. Finally, we suggest a pulsed helium gas jet as a practical and ecomonical helium gas source for the LIBS analysis of halogens in open air.

Dependance of Ionic Polarity in Semiconductor Junction Interface (반도체 접합계면이 가스이온화에 따라 극성이 달라지는 원인)

  • Oh, Teresa
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.6
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    • pp.709-714
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    • 2018
  • This study researched the reasons for changing polarity in accordance with junction properties in an interface of semiconductors. The contact properties of semiconductors are related to the effect of the semiconductor's device. Therefore, it is an important factor for understanding the junction characteristics in the semiconductor to increase the efficiency of devices. For generation of various junction properties, carbon-doped silicon oxide (SiOC) was deposited with various argon (Ar) gas flow rates, and the characteristics of the SiOC was varied based on the polarity in accordance with the Ar gas flows. Tin-doped zinc oxide (ZTO) as the conductor was deposited on the SiOC as an insulator to research the conductivity. The properties of the SiOC were determined from the formation of a depletion layer by the ionization reaction with various Ar gas flow rates due to the plasma energy. Schottky contact was good in the condition of the depletion layer, with a high potential barrier between the silicon (Si) wafer and the SiOC. The rate of ionization reactions increased when increasing the Ar gas flow rate, and then the potential barrier of the depletion layer was also increased owing to deficient ions from electron-hole recombination at the junction. The dielectric properties of the depletion layer changed to the properties of an insulator, which is favorable for Schottky contact. When the ZTO was deposited on the SiOC with Schottky contact, the stability of the ZTO was improved by the ionic recombination at the interface between the SiOC and the ZTO. The conductivity of ZTO/SiOC was also increased on SiOC film with ideal Schottky contact, in spite of the decreasing charge carriers. It increases the demand on the Schottky contact to improve the thin semiconductor device, and this study confirmed a high-performance device owing to Schottky contact in a low current system. Finally, the amount of current increased in the device owing to ideal Schottky contact.

The Mechanical Properties of WC-CoFe Coating Sprayed by HVOF (고속화염용사코팅으로 제조된 WC-CoFe 코팅의 기계적 특성에 관한 연구)

  • Joo, Yun-Kon;Cho, Tong-Yul;Ha, Sung-Sik;Lee, Chan-Gyu;Chun, Hui-Gon;Hur, Sung-Gang;Yoon, Jae-Hong
    • Journal of the Korean Society for Heat Treatment
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    • v.25 no.1
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    • pp.6-13
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    • 2012
  • HVOF thermal spray coating of 80%WC-CoFe powder is one of the most promising candidate for the replacement of the traditional hard chrome plating and hard ceramics coating because of the environmental problem of the very toxic $Cr^{6+}$ known as carcinogen by chrome plating and the brittleness of ceramics coatings. 80%WC-CoFe powder was coated by HVOF thermal spraying for the study of durability improvement of the high speed spindle such as air bearing spindle. The coating procedure was designed by the Taguchi program, including 4 parameters of hydrogen and oxygen flow rates, powder feed rate and spray distance. The surface properties of the 80%WC-CoFe powder coating were investigated roughness, hardness and porosity. The optimal condition for thermal spray has been ensured by the relationship between the spary parameters and the hardness of the coatings. The optimal coating process obtained by Taguchi program is the process of oxygen flow rate 34 FRM, hydrogen flow rate 57 FRM, powder feed rate 35 g/min and spray distance 8 inch. The coating cross-sectional structure was observed scanning electron microscope before chemical etching. Estimation of coating porosity was performed using metallugical image analysis. The Friction and wear behaviors of HVOF WC-CoFe coating prepared by OCP are investigated by reciprocating sliding wear test at $25^{\circ}C$ and $450^{\circ}C$. Friction coefficients (FC) of coating decreases as sliding surface temperature increases from $25^{\circ}C$ to $450^{\circ}C$.

Weldability with Process Parameters During Fiber Laser Welding of a Titanium Plate (I) - Effect of Type and Flow Rate of Shielding Gases on Weldability - (티타늄 판재의 파이버 레이저 용접시 공정변수에 따른 용접특성 (I) - 실드가스 종류 및 유량에 따른 영향 -)

  • Kim, Jong Do;Kim, Ji Sung
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.40 no.12
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    • pp.1047-1053
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    • 2016
  • In this study, welding of pure titanium was carried out by using a continuous wave fiber laser with a maximum output of 6.3 kW. Because brittle regions form easily in titanium as a result of oxidation or nitriding, the weld must be protected from the atmosphere by using an appropriate shielding gas. Experiments were performed by changing the type and the flow rate of shielding gases to obtain the optimal shielding condition, and the weldability was then evaluated. The degree of oxidation and nitriding was distinguished by observing the color of beads, and weld microstructure was observed by using an optical microscope and a scanning electron microscope. The mechanical properties of the weld were examined by measuring hardness. When the weld was oxidized or nitrified, the bead color was gray or yellow, and the oxygen or nitrogen content in the bead surface and overall weld tended to be high, as a result of which the hardness of the weld was thrice that of the base metal. A sound silvery white bead was obtained by using Ar as the shielding gas.

Characterizing Compressive Strength Development in Cement Mortar Utilizing Red Mud Neutralized with Sulfuric Acid (황산 중화 레드머드를 사용한 시멘트 모르타르의 압축강도 발현특성)

  • Kang, Suk-Pyo;Hong, Seong-Uk;Kim, Sang-Jin;Park, Kyu-Eun
    • Journal of the Korea Institute of Building Construction
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    • v.23 no.3
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    • pp.231-240
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    • 2023
  • In this research, our goal was to explore the potential use of cement mortar augmented with liquid red mud. To facilitate this, we neutralized liquid red mud(LR) - exhibiting a pH of 10-12 - using sulfuric acid to yield sulfuric acid neutralized red mud(SR). We then evaluated the flow, setting time, and compressive strength of the cement mortar combined with liquid red mud, while also performing a thorough examination of its chemical properties through X-ray diffraction(XRD) and scanning electron microscopy(SEM). The flow tests indicated a decrease in flow values for both MS-LR and MS-SR in comparison to the Plain. Analogously, the setting time for MS-LR and MS-SR was found to be abbreviated when juxtaposed with the Plain. With regards to compressive strength, MS-LR demonstrated a surge in strength at the 1-day mark, while MS-SR displayed a diminution at the 1-day and 3-day timepoints compared to the Plain. XRD analysis illustrated that after 28 days, the XRD patterns of Plain and MS-SR bore significant resemblance, though a new peak was detected in MS-LR. SEM imagery highlighted that the microstructures of Plain and MS-SR were alike, but MS-LR manifested a distinct microstructure, characterized by a finely fibrous formation. Based on these observations, we infer that the replacement of cement mortar with liquid red mud neutralized with sulfuric acid contributes to a noticeable enhancement in strength, thereby verifying its suitability for this application.

Anaerobic Reductive Dechlorination of Tetrachloroethylene (PCE) in Two-in-series Semi-continuous Soil Columns (반연속 흐름 2단 토양 컬럼에서의 사염화 에틸렌(PCE)의 혐기성 환원탈염소화)

  • Ahn, Young-Ho;Choi, Jeong-Dong;Kim, Young;Kwon, Soo-Youl;Park, Hoo-Won
    • Journal of Soil and Groundwater Environment
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    • v.11 no.2
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    • pp.68-76
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    • 2006
  • Anaerobic reductive dechlorination of tetrachloroethylene (PCE) to ethylene was investigated by performing laboratory experiments using semi-continuous flow two-in-series soil columns. The columns were packed with soils obtained from TCE-contaminated site in Korea. Site ground water containing lactate (as electron donor and/or carbon source) and PCE was pumped into the soil columns. During the first operation with a period of 50 days, injected mass ratio of lactate and PCE was 620:1 and incomplete reductive dechlorination of PCE to cis-DCE was observed in the columns. However, complete dechlorination of PCE to ethylene was observed when the mass ratio increased to 5,050:1 in the second operation, suggesting that the electron donor might be limited during the first operation period. Dechlorination rate of PCE to cis-DCE was $0.62{\sim}1.94\;{\mu}mol$ PCE/L pore volume/d and $2.76\;{\mu}mol$ cis-DCE/ L pore volume/d for that for cis-DCE to ethylene, resulting that net dechlorination rate in the system was 1.43 umol PCE/L pore volume/d. During the degradation of cis-DCE to ethylene, the concentration of hydrogen in column groundwater was $22{\sim}29\;mM$ and $10{\sim}64\;mM$ for the degradation of PCE to cis-DCE. These positive results indicate that the TCE-contaminated groundwater investigated in this study could be remediated through in-situ biological anaerobic reductive dechlorination processes.