• 한국지반공학회논문집
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• 제19권3호
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• pp.83-91
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• 2003

본 논문에서는 동전기초음파정화기술을 이용하여 오염지반내의 중금속 및 유기물질을 제거하는 연구를 수행하였는데, 지반내 오염물질의 이동 및 제거에 대한 동전기기술과 초음파기술의 복합효과 분석에 초점을 두었다. 일반적으로 오염지반내에서 동전기기술은 중금속을 제거하는데 탁월하며 초음파기술은 유기물질을 제거하는데 탁월한 것을 보고되어 있는바 이들 두 기술의 장점을 이용한 복합기술을 고안하게 되었다. 특수하게 고안된 실험장비를 이용하여 동전기기술과 초음파기술을 결합한 실내토양세척실험을 실시하였다. 본 실험에서는 단순, 동전기, 초음파, 동전기&초음파의 4조건에 대하여 토양세척실험을 실시하였다. 오염물질로는 중금속으로는 납, 유기물질로는 에틸렌글리콜을 사용하였다. 실험결과 동전기기술과 초음파기술을 도입한 경우 유출량, 투수계수, 오염물질 제거율이 단순기술에 비하여 상대적으로 크게 증가하는 것으로 나타났다. 본 연구를 통하여 동전기초음파정화기술을 현장에 적용할 수 있는 가시적인 결과를 얻게 되었다.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2002년도 총회 및 춘계학술발표회
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• pp.275-278
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• 2002

In this study, to increase removal efficiency of traditional electrokinetic treatment and to reduce contaminant load of wastewater that discharged through cathode compartment, enhanced electrode compartments were investigated. Hydroxide precipitation near the cathode electrode that encounter during traditional electrokinetic treatment were prevented by enhanced electrokinetic remediation test with newly invented electrode compartment. And heavy metal concentration in wastewater showed 0 ppm thus, additive post-treatment cost were not needed.

• 방사성폐기물학회지
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• 제7권3호
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• pp.153-160
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• 2009

방사성 토양을 복원하기 위해 원자력시설 주변 부지의 수리지질 특성을 분석하여 국내 방사성 토양 복원에 적합한 수직형 동전기세정장치를 개발하였다. 또한, 이 수직형 동전기세정장치를 이용한 실험을 통해 원자력시설 주변 방사성토양을 복원하기 위한 최적 세정제를 선정하고 단기간에 높은 제거효율을 확보할 수 있는 최적제염조건들을 도출하였다. 초산을 세정제로 사용하였을 때 토양으로부터 코발트와 세슘의 제거효율이 가장 높으므로 동전기제염을 위한 최적 세정제로 초산을 선정하였다 동전기세정제염 시 세정제 주입량을 증가 시켰을 때 토양으로부터 코발트와 세슘의 제거효율은 평균 약 4.6% 제거효율이 증가했고 토양폐액 발생량도 동전기제염의 1.5배 인 2.4mL/g이었다. 동전기토양셀의 전압구배를 2배로 증가시켜 4 V/cm를 적용시켰을 때, 코발트와 세슘의 제거효율은 각각 98.9%와 96.7%로 평균 약 4.3% 제거효율이 증가했다. 그리고 세정제 농도를 0.01M로부터 0.05M로 증가시킨 후 제염실험 결과 코발트의 제거효율은 상승했지만 세슘의 제거효율은 감소하였다. 위 실험결과 개발한 수직형 동전기세정장치의 최적제염조건으로 제염시간은 20일 동안 초산 $0.01M{\sim}0.05M$을 세정제로 사용하여 동전기토양셀의 전압구배는 4 V/cm를 가하고, 2.4mL/g의 세정제를 주입하는 것이다.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.91-96
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• 2001

Restoration of contaminated soils to an environmentally acceptable condition is important. One of the newer techniques in soil remediation is a method based on electrokinetic phenomena in soils. The technology uses electricity to affect chemical concentrations and water flow through the pores of soils. An important advantage of electrokinetic soil remediation over other in-situ processes such as soil flushing is the capability of control over the movement of the contaminants. Because the migration of the contaminants is confined by the electric field, there is little dispersion outside the treatment zone. Furthermore, the process is effective for soils with low and variable permeability. In the present study, the distributions of cadmium in the electrokinetic processing of kaolinite under the condition of constant applied voltage are investigated. Cadmium accumulates near the cathode without reducing the diffusion of hydroxide ion into the soil. In keeping the catholyte pH at neutrality, cadmium migrates toward the cathode without any accumulation of cadmium near the cathode and is successfully removed at the cathode reservoir. It was also found that the progress of electrokinetic processing of cadmium could be gasped to a certain extent by monitoring the local voltage and the current density.

• 한국지하수토양환경학회지:지하수토양환경
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• 제17권5호
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• pp.75-81
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• 2012

In this study, remediation of heavy metal contaminated soil was attempted by the electrokinetic process equipped with fixed or swappable electrode. Copper was more effectively removed with EDTA than citric acid. Zinc was much more removed than copper with both detergents. When electrokinetic with fixed electrode and detergents were applied to the contaminated soil, copper was removed about 28.52%~35.25% and zinc was removed about 63.44%~71.48%. When electrokinetics with swappable electrode and detergents were applied to the contaminated soil, the pseudo-first order reaction constants was higher about 16~50% than with fixed electrode in the case of zinc. It is conclusive that electrokinetics with swappable electrode could be an effective method for the remediation of heavy metal contaminated soil.

• Environmental Engineering Research
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• 제24권3호
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• pp.456-462
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• 2019

Hydrocarbon contamination is among the most challenging problems in soil remediation. Electrokinetic method can be a promising method to remediate hydrocarbon-contaminated soils. Electrokinetic method consists of different transport phenomena including electro-migration, electrophoresis, and electroosmotic flow. Electroosmotic flow is the main transport phenomenon for hydrocarbon removal in soil porous media. However, the main component of hydrocarbons is the hydrophobic organic which indicates low water solubility; therefore, it makes the electroosmotic flow less effective. The objective of the present study is to enhance electrokinetic remediation of diesel-contaminated silty sand by increasing the solubility of the hydrocarbons in the soil and then increase the efficiency. For this purpose, sodium dodecyl sulfate (SDS) was used as a catholyte. In this content, SDS 0.05 M was used as catholyte and $Na_2SO_4$ 0.1 M was used as an anolyte. Low (1 V/cm) and high (2 V/cm) voltage gradients were used in periodic and continuous forms. The best removal efficiency was observed for high voltage gradient (2 V/cm) in a periodic form, which was 63.86. This result showed that a combination of periodic voltage application in addition to the employment of SDS is an effective method for hydrocarbon removal from low permeable sand.

• 한국지하수토양환경학회지:지하수토양환경
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• 제6권4호
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• pp.13-23
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• 2001

본 연구는 중금속 오염지반의 정화를 목적으로, Electrokinetic(EK) 기법을 적용 할 때 지반 내에서 pH와 오염물 분포특성을 알아보았다. 시료 내에서의 EK 처리로 인한 납 제거 효과를 살펴본 결과 1V/cm의 전압경사 하에서 납은 음극으로 이동하여, 전극 간 시료의 80%정도 영역에서 제거율은 대략 75% 정도에 이르렀다. 그러나 이동된 납은 대부분이 음극영역에 침전되어 궁극적으로 음극수로 배출되어 제거되는 납의 양은 미미하였다. 이때, EK 정화처리는 시료의 대부분인 80% 정도에서 토양환경보전법 상의 규준치를 만족할 수 있으나, 음극쪽 20%지역은 별도의 향상기법을 적용하여 처리하는 기법이 필요하다.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 1999년도 추계학술발표회
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• pp.23-27
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• 1999

After kaolin clay was compulsorily contaminated by Sr$^{2+}$ solution, the remediation characteristics by electrokinetic method were analyzed. Meanwhile, the numerical code for analysis of electrokinetic migration was developed for modelling of the soil remediation. Experimental results are as follows After 3 day remidiation under 40 voltage, the front part of experimental cell was almost decontaminated, but the behind part didn't almost be decontaminated. Accordingly, the total remediation ratio of Sr$^{2+}$ from cell soil was about 42.6 %. Also, the total Sr$^{2+}$ remediation ratio from cell soil was about 84.8 % after 6 days, and about 97.1 % after 7 days. Meanwhile, the values calculated by the developed code almost agreed with experimental values.ues.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2001년도 추계학술발표회
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• pp.61-64
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• 2001

In the remediation of contaminated soil by electrokinetic process, transport characteristics of contaminants are major factors. Pb is highly fixed to entire soil and not moved readily. High concentration of Cd was analyzed in the cathodic section but anodic section's concentration was lower than initial concentration. Although the Cd had high treatment effect, 50% of total mass was concentrated in cathodic section and was not flowed out readily. Most of transported Cd may be adsorbed in the cathodic side soil due to increased pH at adjacent to catholyte.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2003년도 추계학술발표회
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• pp.310-313
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• 2003

The precipitation of heavy metals within the region of pH jump is inevitable in the conventional electrokinetic remediation technology. This study prevents the interest species from precipitating through the injection of flushing solutions in which HCl, acetic acid, citric acid, EDTA and SDS dissolved. The cumulative flow resulted from electroosmosis appear in order of Citric acid