• Title/Summary/Keyword: Electrode treatment

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A Basic Study of Plasma Reactor of Dielectric Barrier Discharge for the Water Treatment (수처리용 유전체장벽 플라즈마 반응기에 대한 기초 연구)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Science International
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    • v.20 no.5
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    • pp.623-630
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    • 2011
  • This study investigated the degradation of N, N-Dimethyl-4-nitrosoaniline (RNO, indicator of the generation of OH radical) by using dielectric barrier discharge (DBD) plasma. The DBD plasma reactor of this study consisted of a quartz dielectric tube, titanium discharge (inner) and ground (outer) electrode. The effect of shape (rod, spring and pipe) of ground electrode, diameter (9~30 mm) of ground electrode of spring shape and inside diameter (4~13 mm) of quartz tube, electrode diameter (1~4 mm), electrode materials (SUS, Ti, iron, Cu and W), height difference of discharge and ground electrode (1~15.5 cm) and gas flow rate (1~7 L/min) were evaluated. The experimental results showed that shape of ground electrode and materials of ground and discharge electrode were not influenced the RNO degradation. The thinner the diameter of discharge and ground electrode, the higher RNO degradation rate observed. The effect of height gap of discharge between ground electrode on RNO degradation was not high within the experimented value. Among the experimented parameters, inside diameter of quartz tube and gas flow rate were most important parameters which are influenced the decomposition of RNO. Optimum inside diameter of quartz tube and gas flow rate were 7 mm and 4 L/min, respectively.

Comparison between Acid and Heat Treatment for Capacity Enhancement of RuO2/MWNT Composite Electrode Materials for Ultracapacitor (울트라캐패시터용 RuO2/MWNT 복합 전극재료의 용량개선을 위한 산처리 및 열처리 효과 비교)

  • Kim, Yong-Tae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.1
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    • pp.65-69
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    • 2010
  • In this study, we compared two methods(an acid treatment in strong acid reflux and a heat treatment in air atmosphere) for hydrophilic surface treatment of multi-walled carbon nanotubes(MWNT) to enhance the capcity of $RuO_2$/MWNT composite electrode materials for ultracapacitor. Both treatments generated a number of defects on the surface of MWNT by the breakage of $\pi$ bond in graphene layer at which carboxyl groups were introduced. However, the degree of hydrophilicity generated by strong acid treatment was higher than that by heat treatment in air, which was revealed by the quantitative measurement of surface carboxyl groups by using Boehm titration. The increased hydrophilicity save rise to an improved dispersity of $RuO_2$ nanoparticles on MWNT. Finally, the improved dispersity resulted in the capacity enhancement of composite electrode materials for ultracapacitor.

Development of Activated Graphite Felt Electrode Using Ozone and Ammonia Consecutive Post Treatments for Vanadium Redox Flow Batteries (오존, 암모니아 순차적 처리를 통한 바나듐 레독스 흐름 전지용 활성화 카본 펠트 전극 개발)

  • CHOI, HANSOL;KIM, HANSUNG
    • Journal of Hydrogen and New Energy
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    • v.32 no.4
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    • pp.256-262
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    • 2021
  • A carbon felt electrode was prepared using ozone and ammonia sequential treatment and applied as an electrode for a vanadium redox flow battery (VRFB). The physical and electrochemical analyses demonstrate that the oxygen groups facilitate nitrogen doping in the carbon felt. Carbon felt (J5O3+NH3), which was subjected to ammonia heat treatment after ozone treatment, showed higher oxygen and nitrogen contents than carbon felt (J5NH3+O3), which was subjected to ammonia heat treatment first and then ozone treatment. From the charging/discharging of VRFB, the J5O3+NH3 carbon felt electrode showed 14.4 Ah/L discharge capacity at a current density of 150 mA /cm2, which was 15% and 33% higher than that of J5NH3+O3 and non-activated carbon felt (J5), respectively. These results show that ozone and ammonia sequential treatment is an effective carbon felt activation method to increase the performance of the vanadium redox flow battery.

The study on characteristics of corona ignitor for surface treatment of insulator (절연재료의 표면개질을 위한 코로나 발생기의 특성에 관한 연구)

  • ;;;;Y.Tabata;J.S Chang
    • Electrical & Electronic Materials
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    • v.8 no.4
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    • pp.504-508
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    • 1995
  • The purpose of this research is to study on characteristics of corona ignitor which was designed for ignition of plasma, used at hard coating, surface treatment and thin film preparation, at high pressure. Corona ignitor composed of hollow type inner electrode and ring type external electrode. Though corona voltage increased with increasing distance between electrodes, corona discharge can be controlled stably. The gas flow in hollow type inner electrode and the construction between electrodes affect a length of corona flame and corona phenomenon. It is possible to ignite the . plasma, usually generated at low pressure(10 Torr), at high pressure(100 Torr) by corona ignitor.

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A Novel Carbon Nanotube FED Structure and UV-Ozone Treatment

  • Chun, Hyun-Tae;Lee, Dong-Gu
    • Journal of Information Display
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    • v.7 no.1
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    • pp.1-6
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    • 2006
  • A 10" carbon nanotube field emission display device was fabricated with a novel structure with a hopping electron spacer (HES) by screen printing technique. HES plays a role of preventing the broadening of electron beams emitted from carbon nanotubes without electrical discharge during operation. The structure of the novel tetrode is composed of carbon nanotube emitters on a cathode electrode, a gate electrode, an extracting electrode coated on the top side of a HES, and an anode. HES contains funnel-shaped holes of which the inner surfaces are coated with MgO. Electrons extracted through the gate are collected inside the funnel-shaped holes. They hop along the hole surface to the top extracting electrode. In this study the effects of the addition of HES on emission characteristics of field emission display were investigated. An active ozone treatment for the complete removal of residues of organic binders in the emitter devices was applied to the field emission display panel as a post-treatment.

Treatment of the Chromium Containing Wastewater by Electrolysis (전기분해에 의한 크롬폐수처리)

  • 전종남;전범용;윤용수;정일현
    • Journal of environmental and Sanitary engineering
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    • v.12 no.3
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    • pp.131-138
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    • 1997
  • In this study, the effect of the various operating conditions on the removal of $Cr^{6+}$ from $Cr^{6+}$ containing wastewater which has strong toxicity by using electrolysis with iron electrode as anode and aluminum electrode as cathode was investigated. The removal efficiency of $Cr^{6+}$ was increased as the pH was decreased, as the distance of electrode was decreased and the voltage was increased. The reaction temperature slightly affected the removal efficiency. The optimum conditions for the treatment of $Cr^{6+}$ containing wastewater were initial pH 3, 5 volt and the distance of electrode was 1cm. The feasibility of the electrochemical treatment to the $Cr^{6+}$ containing industrial wastewater was verified from this study.

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Change of Capacitance on Maganese Dioxide Electrode for Supercapacitor by Oxidation Treatment (수퍼커패시터용 산화망간전극의 산화처리에 의한 용량 변화)

  • 김한주;홍지숙;신달우;김용철;김성호;박수길
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.946-949
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    • 2000
  • Amorphous MnO$_2$$.$ nH$_2$O in 1M KOH aqueous electrolyte proves to be an excellent electrode for a faradic electrochemical capacitor cycled between -0.5 and +1.0 versus Ag/AgCl. In order to observe morphology and crystalline structure of MnO$_2$powder, we analyzed it by XRD and SEM. The effect of oxidation treatment on MnO$_2$electrode was observed by different oxidation voltages. A maximum capacitance of 364F/g was obtained by 1.1V oxidation treatment. This capacitance was attributed solely to a surface redox mechanism

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Study on Plasma Treatment of electrode for CCFL (CCFL 전극의 플라즈마 처리에 관한 연구)

  • Park, Hyun-Sik
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.3
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    • pp.1308-1312
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    • 2011
  • CCFL(Cold Cathode Fluorescent Lamp)for BLU of LCD and special lighting has been widely utilized. The removal of oxide film formed on electrode of CCFL in manufacturing process is required. In this pape Plasma treatment was carried out to remove the oxide film. To ensure the optimum process, the analysis of sheet resistance, XRD, AFM and solder test was conducted. A minimum sheet resistance and the maximum percentage of the solder coverage ratio were measured in optimal process conditions such as plasma power consumption 600W and processing time of 70 seconds. As the plasma treatment is confirmed to be due to removal of copper oxide, this process is expected to be used as a treatment of electrode for CCFL.

The Effect of Pre-Treatment Methods for the Life Time of the Insoluble Electrodes (불용성 전극의 전처리 방법이 전극의 수명에 미치는 영향)

  • Park, Mi-Jung;Lee, Taek-Soon;Kang, Meea;Han, Chi-Bok
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.6
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    • pp.291-298
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    • 2016
  • Electrochemical water treatment process as a useful treatment method for the removal of non-degradable matter has been consistently studied for several decades. Key process of electrochemical water treatment are oxidation reaction from an anode and reduction from a cathode. In this study, the effect of pre-treatment methods in the insoluble electrode manufacturing process for the water treatment has been evaluated for the life time of electrode The results of this study showed that pre-treatment methods of a base metal such as surface roughness, clean method and interlayer formation influenced to life time of electrode when the same condition (catalyst electrode layer coating method and material system) was applied for pre-treatment methods. This study was conducted by using $IrO_2/Ti$ electrode In the test of sand-blasting process, an electrode manufactured by using sanding media of different sizes resulted in the most effective electrode life time when the size of alumina was used for $212{\sim}180{\mu}m$ praticle size (#80). The most effective method was considered using arc plasma in the additional roughness control and cleaning process, sputtering method to form Ta type interlayer formation process.

The Treatment of Textile Wastewater by Electrocoagulation Process (전해응집공정을 이용한 염색폐수의 처리)

  • 이용택;한승우;조영개;이현문;김태근;손인식;양병수
    • Journal of Environmental Science International
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    • v.9 no.4
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    • pp.359-363
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    • 2000
  • This research studied the characteristics and applicability of electrocoagulation using aluminium electrode for the color and COD removal in textile wastewater. Electrocoagulation reactor used two different electrode, Fe and Al, since in the general chemical wastewater treatment, aluminium and ferrous salts were used as coagulants. Aluminium electrode showed higher removal efficiency of color and COD than ferrous electrode did. The COD and color removal efficiency improved at the 0.192A/$dm^2$ current density. Thus, the electrocoagulation process with bipolar aluminium electrode showed better efficiency in the decolorization and COD removal rate of textile wastewater effluent than custom coagulants did.

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