• 한국응용과학기술학회지
• /
• 제35권4호
• /
• pp.1379-1385
• /
• 2018

The hand held voltammetry systems searched diabetic assay using glucose sensor of fluorine nafion doped carbon nanotube electrode (FCNE). An inexpensive graphite carbon pencil was used as an Ag/AgCl reference and Pt counter electrode. Upon combining and using three electrode systems, optimum square wave (SW) stripping results were attained to 1.0-9.0 ug/L with 8 points. Statistic RSD precision was of 6.02 % with n=15 in 0.1 mg/L glucose. After a total of 200 second accumulation times, analytical detection limit of 0.8 ug/L was obtained. This developed technique was applied to urine samples from diabetic patients urine for fluid analysis, it was determined that the sensor can be used with a diagnostics in the ex vivo of live cells and non treated biological fluid.

• 제어로봇시스템학회:학술대회논문집
• /
• 제어로봇시스템학회 2005년도 ICCAS
• /
• pp.453-456
• /
• 2005

Significance verification of electric fabric compared with existing electrode is very useful for the wearable and ubiquitous healthcare. In this paper, we verified the significance between Ag/AgCl electrode and electric fabric in dry-normal condition through heart rate variability analysis. We can find 98 % or more similarity about low frequency and high frequency which is important parameter for the heart rate variability analysis between two different electrodes in experiment. From this result, we confirmed that the power spectral density of low frequency, high frequency component from the electric fabric has high similarity compared with the result of heart rate variability from Ag/AgCl electrode in dry-normal condition.

• Journal of Welding and Joining
• /
• 제29권1호
• /
• pp.115-122
• /
• 2011

This study is to propose an in-process monitoring system for micro resistance spot welding processes using minute accelerometer. A minute accelerometer is mounted on the upper moving electrode tip holder. With its high sensitivity and frequency response characteristics, accelerometer output signal has been successfully recorded and integrated twice to reflect electrode expansion during micro spot welding processes. The analysis of electrode expansion pattern was attempted to find its correlation with spot weld quality. Major previous findings1-6) regarding spot weld quality assessment with the electrode expansion signal in large scale resistance spot welding processes were proved to be true in this in-process monitoring system.

• Journal of Electrochemical Science and Technology
• /
• 제15권1호
• /
• pp.111-131
• /
• 2024

Lignin-derived porous carbon has been identified as a versatile electrode material for supercapacitors (SCs) in energy storage systems (ESSs) owing to their intrinsic advantages including good electrical conductivity, low cost, high thermal and chemical stability, and high porosity, which stem from high surface, appropriate pore distribution, tailored morphologies, heterostructures, and diverse derivates. In this review, to provide a fundamental understanding of the properties of lignin, we first summarize the origin, historical development, and basic physicochemical properties. Next, we describe essential strategies for the preparation of lignin-derived porous carbon electrode materials and then highlight the latest advances in the utilization of lignin-derived porous carbon materials as advanced electrode materials. Finally, we provide some of our own insights into the major challenges and prospective research directions of lignin-derived porous carbon materials for supercapacitors. We believe that this review will provide general guidance for the design of next-generation electrode materials for supercapacitors.

• 융합정보논문지
• /
• 제11권2호
• /
• pp.117-123
• /
• 2021

수계 아연 이온 전지의 신규 전극 활물질로서 헥사시아노 철산철(Fe4[Fe(CN6)]3, FeHCF)의 전기화학적 특성에 미치는 전해질 농도의 영향에 관하여 조사하였다. FeHCF 전극의 전기화학 반응 및 구조적 안정성에 전해질 농도가 크게 영향을 준다는 것이 전위 주사, 충전-방전 시험, X-선 회절 분석에 의해 확인되었다. 1.0-7.0 mol dm-3의 전해질 용액에서는 농도가 증가함에 따라 FeHCF 전극의 충전 및 방전 용량이 증가하였으나 사이클이 진행됨에 따라 서서히 감소하였다. 반면에 9.0 mol dm-3의 전해질 용액에서는 초기 용량은 상대적으로 작았으나 사이클 특성이 우수하였다. 전자의 전해질 용액에서 5사이클 진행된 FeHCF 전극은 반응 전과 비교하여 결정 구조에 변화가 있었으며, 후자의 경우에는 변화가 없었다. 이것은 FeHCF 전극의 전기화학적 성능이 전해질 용액 중에 존재하는 아연 이온의 수화 구조와 크게 관련이 있음을 시사하는 것이다.

• Korean Chemical Engineering Research
• /
• 제54권6호
• /
• pp.817-821
• /
• 2016

Levodopa or L-3,4-dihydroxyphenylalanine (L-DOPA) is the direct precursor of the neurotransmitter dopamine. L-DOPA is a well-known neuroprotective agent for the treatment of Parkinson's disease symptoms. L-DOPA was synthesized using the enzyme, tyrosinase, as a biocatalyst for the conversion of L-tyrosine to L-DOPA and an electrochemical method for reducing L-DOPAquinone, the product resulting from enzymatic synthesis, to L-DOPA. In this study, three electrode systems were used: A glassy carbon electrode (GCE) as working electrode, a platinum, and a Ag/AgCl electrode as auxiliary and reference electrodes, respectively. GCE has been modified using electropolymerization of pyrrole to facilitate the electron transfer process and immobilize tyrosinase. Optimum conditions for the electropolymerization modified electrode were a temperature of $30^{\circ}C$ and a pH of 7 producing L-DOPA concentration 0.315 mM. After 40 days, the relative activity of an enzyme for electropolymerization remained 38.6%, respectively.

• 한국전기전자재료학회논문지
• /
• 제30권6호
• /
• pp.401-405
• /
• 2017

Because silicon thin film solar cells have a high absorption coefficient in visible light, they can absorb 90% of the solar spectrum in a $1-{\mu}m$-thick layer. Silicon thin film solar cells also have high transparency and are lightweight. Therefore, they can be used for building integrated photovoltaic (BIPV) systems. However, the contact electrode needs to be replaced for fabricating silicon thin film solar cells in BIPV systems, because most of the silicon thin film solar cells use metal electrodes that have a high reflectivity and low transmittance. In this study, we replace the conventional aluminum top electrode with a transparent aluminum-doped zinc oxide (AZO) electrode, the band level of which matches well with that of the intrinsic layer of the silicon thin film solar cell and has high transmittance. We show that the AZO effectively replaces the top metal electrode and the bottom fluorine-doped tin oxide (FTO) substrate without a noticeable degradation of the photovoltaic characteristics.

• 한국지반공학회:학술대회논문집
• /
• 한국지반공학회 2008년도 춘계 학술발표회 초청강연 및 논문집
• /
• pp.242-250
• /
• 2008

Lining systems are used for two purpose in landfills : as covers to minimize leachate generation and surface water contamination by providing a barrier from precipitation and other percolating waters, and as containment liners to contain leachate and minimize its downward migration into underlying groundwater. So identifying leaks in landfill liners is an essential part of waste management. There are many leakage detection systems to monitor and seek leakage location, such as two electrode method, electrode grid method, diffusion hoses, capacitance sensors and tracers sensing cables. However, most of them can be applied in the new landfill construction sites because sensors must be installed prior to work. This paper presents a new type of leakage detection system, so called fence type electrode arrangement system, to monitor leakage and to seek leakage location in working landfill as well as new landfill. This system is based on the measurement of an electrical current flowing through leakage point. Series of laboratory tests are performed to investigate an availability of this system and this paper present some of these results.

• 정보저장시스템학회논문집
• /
• 제1권1호
• /
• pp.108-114
• /
• 2005

The generation of fine relics of suspensions is a significant interest as it holds the key to the fabrication of electronic devices. These processes offer opportunities for miniaturization of multilayer circuits, for production of functionally graded materials, ordered composites and far small complex-shaped components. Some novel printing methods of depositing ceramic and metal droplets were suggested in recent years. In an electro-hydrodynamic printing, the metallic capillary nozzle can be raised to several kilovolts with respect to the infinite ground plate or pin-type electrode positioned a few millimeters from the nozzle tip. Depending on the electrical and physical properties of the liquid, for a given geometry, it Is possible to generate droplets in any one of three modes, dripping, cone-jet and multi-jet. In this experiment, an alumina suspension flowing through a nozzle was subjected to electro-hydrodynamic printing using pin-type electrodes in the cone-jet mode at different applied voltages. The pin-type electrodes of 1, 100, 1000${\mu}m$ in diameter were used to form fine ceramic patterns onto the substrates. Various feature sizes with applied voltages and electrode diameters were measured. The feature sizes increased with the electrode diameter and applied voltages. The feature size was as fine as $30 {\mu}m$.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.2
• /
• pp.1184-1187
• /
• 2003

Electrochemical capacitors are becoming attractive energy storage systems particularly for applications involving high power requirements such as hybrid systems consisting of batteries and electrochemical capacitors for electric vehicle propulsion. A new type electric double layer capacitor (EDLC) was constructed by using carbon nanofibers (CNFs) and DAAQ(1,5-diaminoanthraquinone) electrode. Carbonaceous materials are found in variety forms such as graphite, diamond, carbon fibers etc. While all the carbon nanofibers include impurities such as amorphous carbon, nanoparticles, catalytic metals and incompletely grown carbons. We have eliminated of Ni particles and some carbonaceous particles in nitric acid. Nitric acid treated CNFs could be covered with very thin DAAQ oligomer from the results of CV and TG analyses and SEM images. DAAQ oligomer film exhibited a specific capacity as 45-50 Ah/kg in 4M $H_2SO_4$. We established Process Parameters of the technique for the formation of nano-structured materials. Furthermore, improved the capacitive properties of the nano structured CNFs electrodes using controlled solution chemistry. As a result, CNFs coated by DAAQ composite electrode showed relatively good electrochemical behaviors in acidic electrolyte system with respect to specific capacity and scan rate dependency.