• Title/Summary/Keyword: Electrode Material

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Electrochemical Properties of Conducting Polymer for Supercapacitor (Supercapacitor용 도전성 고분자의 전기화학적 특성)

  • 강광우;김종욱;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.332-334
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    • 2000
  • The purpose of this study is to research and develop conducting polymer(CP) composite electrode for supercapacitor. Supercapacitor cell of CP composite electrode with 1M LiClO$_4$/ PC bring out good capacitor performance below 4V. The radius of semicircle of CP composite cell with PAn composite electrode adding 30wt% acetylene black was absolutely small. The total resistance of supercapacitor cell mainly depended on internal resistance of the electrode. The discharge capacitance of supercapacitor cell with PAn composite electrode adding 30wt% acetylene black in 1st and 50th cycles was 27F/g and 31F/g at current density of 1mA/$\textrm{cm}^2$. Supercapacitor cell with PAn composite electrode adding 30wt% acetylene black performed a good cycliability.

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Electrical Properties of Supercapacitor with Polyaniline and Polythiophene (Polyaniline과 Polythiophene을 사용한 supercapaccitor의 전기적 특성)

  • 강광우;김종욱;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.487-490
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    • 2000
  • The purpose of this study is to research and develop conducting polymer(CP) composite electrode for supercapacitor. Electrochemical capacitor(supercapacitor) cell of CP composite electrode with 1M LiClO$_4$PC bring out good capacitor performance below 4V. The radius of semicircle of CP composite cell with PAn composite electrode adding l5wt%SP270(PAnS15) and PT composite electrode adding 50wt%SP270 (PTS50) was absolutely small. The total resistance of supercapacitor cell mainly depended on internal resistance of the electrode. The discharge capacitance of supercapacitor cell with PTS50(+)/PAnS15(-) in 1st and 20th cycles was 38F/g and 28F/g at current density of 1mA/cm$^2$. Supercapacitor cell with PTS50(+)/PAnS15(-) showed good capacitance and stability with cycling.

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Electrochemical detection effect of hormone in body by using polymer coated boron doped diamond electrode (고분자 막이 코팅된 Boron doped diamond 전극에 의한 호르몬의 전기화학적 검출 효과)

  • Hwang, Jin-Hee;Cho, Eun-In;Park, Soo-Gil;Okajima, Takeyoshi;Ohsaka, Takeo;Fujishima, Akira
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.611-614
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    • 2003
  • The electrochemical oxidation of ascorbic acid(AA), serotonin(SE) and epinephrine(EP) have been performed at poly N,N-dimethylaniline(PDMA) film coated diamond electrode. This cationic polymer film is electrochemically deposited on boron-doped diamond electrode surface. Unlike the bard electrode, the polymer film-coated diamond electrode can well separate the oxidation potential of AA by 200mV. Thus this electrode can be successfully used for the simultaneoud detection of both species. Increases in the concentration of AA do not affect the reponse of EP and SE.

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Selective electrochemical detection effect of serotonin in blood by using boron doped diamond rotating disk electrode (Boron doped diamond RDE에 의한 혈액내의 serotonin의 전기화학적 선택적 검출 효과)

  • Hwang, Jin-Hee;Cho, Eun-In;Park, Soo-Gil;Okajima, Takeyoshi;Ohsaka, Takeo;Fujishima, Akira
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.930-933
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    • 2003
  • The electrochemical oxidation of ascorbic acid(AA), serotonin(StT) and epinephrine(EP) have been performed ae poly N,N-dimethylanliline(PDMA) film coated diamond electrode. This cationic polymer film is electrochemically deposited on boron-doped diamond electrode surface. Unlike the bard electrode, the polyaer film-coated diamond electrode can well separate the oxidation potential of AA by 330mV. Thus this electrode can be successfully used for the simultaneoud detection of both species. Increases in the concentration of AA donot affect the reponse of EP and ST.

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I-V characteristics of ground electrode fabricated using an aluminium scrap (알루미늄 스크랩을 이용하여 제작한 접지 전극의 전압-전류 특성)

  • 이우선;정용호;박진성
    • Electrical & Electronic Materials
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    • v.9 no.8
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    • pp.806-812
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    • 1996
  • I-V characteristics of ground electrode fabricated using an aluminium scrap are presented. We fabricated several shapes of aluminium scraps and aluminium electrodes. The results show that the current of aluminium electrode increased linearly by the voltage increase. AC breakdown voltage of copper plate electrode was higher than that of aluminium electrode. AC breakdown current of aluminium electrode was higher than that of copper plate electrode. As applied voltage increased, grounding resistance of aluminum electrode decreased linearly.

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The Partial Discharge Characteristics of the XLPE According to the Tilt of the Needle Electrode (침 전극 기울기에 따른 XLPE의 부분 방전 특성)

  • Shin, Jong-Yeol;Ahn, Byung-Chul;Hong, Jin-Woong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.1
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    • pp.28-33
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    • 2015
  • The needle electrode is inserted into the cross-linked polyethylene(XLPE) which is the ultra high voltage cable for electric power. By changing the tilt of the needle electrode, we investigated how the void and the thickness of the insulating layer influence the partial discharge(PD) characteristics and the insulating breakdown. In order to investigate the PD characteristics, The XLPE cable was used to the specimens and the tungsten electrode was used with the needle electrode. And the inner semi-conductive layer material of XLPE cable was used with the negative electrode by bonding with the use of conduction tape. The size of the specimens was manufactured to be $16{\times}40{\times}30[mm^3]$. We confirmed the effect on changing the PD characteristics according to the changing voltage and the tilt of the electrode after applying the voltage on the electrode from 1[kV] to 40[kV] at room temperature. In the PD characteristics, it was confirmed that the PD current of air void specimens with tilt was unstable more than that of no void specimens with tilt. It was also confirmed that the breakdown voltage was decreased because the effect of air void is more active than the change of the needle electrode tilt in the specimen with air void inside the insulation.

A Study on Diagnosis of Partial Discharge Type Using Wavelet Transform-Neural Network (웨이블렛-신경망을 이용한 부분방전 종류와 진단에 관한연구)

  • Park, Jae-Jun;Jeon, Hyun-Gu;Jeon, Byung-Hoon;Kim, Sung-Hong;Kwon, Dong-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.894-899
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    • 2002
  • In this papers, we proposed the new method in order to diagnosis partial discharge type of transformers. For wavelet transform, Daubechies filter is used, we can obtain wavelet coefficients which is used to extract feature of statistical parameters (maximum value, average value, dispersion, skewness, kurtosis) about high frequency current signal per 3-electrode type (needle-plane electrode, IEC electrode and Void electrode.). Also. these coefficients are used to identify Signal of internal partial discharge in transformer. As a result. from compare of high frequency current signal amplitude and average value. we are obtained results of IEC electrode> Void electrode> Needle-Plane electrode. otherwise. In case of skewness and kurtosis, we are obtained results of Void electrode> IEC electrode > Needle-Plane electrode. As Improved method in order to diagnosis partial discharge type of transformers, we use neural network.

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Effect of Ceramic-Electrode Interface on the Electrical Properties of Multilayer Ceramic Actuators (적층형 세라믹 액츄에이터의 세라믹-전극간 계면이 전기적 특성에 미치는 영향에 대한 연구)

  • 하문수;정순종;송재성;이재신
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.10
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    • pp.896-901
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    • 2002
  • The polarization and strain behavior of multilayer ceramic actuators fabricated by tape casting using a PNN-PZT ceramics were investigated in association with electrode size and internal layer number. Spontaneous polarization and strain decreased with increasing electrode size. In addition, the increase of internal layer number brought reduced spontaneous polarization and increased the field-induced strain. Because the actuators structure is designed to stack ceramic layer and electrode layer alternatively, the ceramic-electrode interfaces may act as a resistance to motion of domain wall. To analyze the effect of ceramic-electrode interface, the diffraction intensity ratio of (002) to (200) planes was calculated from X-ray diffraction patterns of samples subjected to a voltage of 200 V. The diffraction intensity ratio of (002) to (200) planes was decreased with increasing electrode size and internal layer number. The diffraction intensity ratio and straining behavior analyses indicate that the Polarization and strain were affected by the amount of 90°domain decreasing with increasing electrode size and internal layer number. Consequently, the change of polarization and displacement with respect to electrode size and layer number is likely to be caused by readiness of the domain wall movement around the interface.

Effects of Conductive Material on $LiCoO_2$ Cathode for the Lithium ion Battery (리튬이온전지용 $LiCoO_2$ 정극의 도전재료에 따른 특성)

  • Coh Chil Hoon;Moon Seong In;Hyung Yoo Eup;Yun Mun Soo;Park Chun Jun;Yun Duk Hyun;Yun Suong Kyu
    • Journal of the Korean Electrochemical Society
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    • v.2 no.2
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    • pp.88-92
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    • 1999
  • The apparent density. self-separation of the electrode composite from current collector in the electrolyte solution and specific resistance of electronic conduction of the electrode composite were examined by the variation of content of conductive material such as graphitic and black carbons in $LiCoO_2$ composite electrode for lithium ion battery. Increasing the content of conductive material, the apparent density of Lico02 composite electrode was decreased and that of $LiCoO_2$ in composite electrode was only rapidly decreased compared to that of composite. $LiCoO_2$ composite electrodes containing more than 4.1 weight percent of super s black as a conductive material were seU-separated by the immersion into 1 mol/I $LiPF_6$ in propylene carbonate and diethyl carbonate (1:1 volume ratio). Specific resistances related to the electronic conduction of composite electrode were decreased by the increasing the content i)f conductive material. Specific resistance of the composite electrode including $2\~3\%w/w$ of super s black as conductive material was similar to that of $12\%w/w$ of Lonza KS6. In the range of this study, super s black as conductive material is better than Lonza KS6 on battery capacity because of apparent density of $LiCoO_2$ in electrode composite including super s black is higher than that of Lonza KS6.

Simulation Results of Piezoelectric Microspeakers due to Structural Changes (구조변화에 따른 압전형 마이크로스피커의 모의해석)

  • Jeong, Kyong-Shik;Ur, Soon-Chul;Cho, Hee-Chan;Yi, Seung-Hwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.327-327
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    • 2007
  • This paper reports the simulation results of piezoelectric microspeakers due to structural changes(diaphragm materials, corrugation width and electrode shapes). When we compared the dependence of diaphragm material properties, the microspeaker with LTO(Low Temperature Oxide) diaphragm shows higher deflection than that of silicon nitride diaphragm, even though the resonant frequencies are almost same in both cases. In case of circular-electrode microspeaker, the deflection of diaphragm is about $16\;{\mu}m$ at 20 V, and it decreases as the corrugation width is decreased. However, the deflection of diaphragm with the square-electrode reveals almost twice times higher value at the same applied voltage than the circular one, and it increases as the corrugation depths are decreased from $30\;{\mu}m\;to\;10\;{\mu}m$. The first resonant frequency of microspeakers present about 1.8 kHz in circular-electrode and 1.2 kHz in square-electrode, respectively.

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