• Title/Summary/Keyword: Elastomers

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The effect of silver ion-releasing elastomers on mutans streptococci in dental plaque

  • Kim, Yae-Jin;Lee, Dong-Yul;Lee, Jin-Yong;Lim, Yong-Kyu
    • The korean journal of orthodontics
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    • v.42 no.2
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    • pp.87-93
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    • 2012
  • Objective: The purpose of this study was to investigate the antimicrobial effect of silverized elastomers on mutans streptococci in dental plaque. Methods: Forty patients undergoing orthodontic treatment were randomly placed into 1 of 2 groups. We examined the maxillary right and left central incisors and premolars, and the mandibular right and left canines of all participants. We ligated the right maxillary and left mandibular teeth of the participants in group 1 with silverized elastomers and ligated their contralateral teeth with conventional elastomers. We ligated the left maxillary teeth and right mandibular teeth of group 2 participants with silverized elastomers. Each participant visited the clinic 4 times at 3-week intervals. We applied the elastomers to the teeth on one side of each patient's mouth during their first visit. During the second visit, the elastomers were removed for microbiological analysis and replaced with steel ligatures. During the third visit, we used silverized elastomers to ligate the teeth contralateral to those treated on the first visit. The elastomers were removed during the fourth visit, and microbiological analyses were performed. We compared the quantity of bacteria on silverized and conventional elastomers at the 0.05 level of significance. Results: The percentage of mutans streptococci was not significantly different in cultures of dental plaque from the silverized and the conventional elastomers (p > 0.05). Conclusions: There was no significant difference between the antimicrobial effect of the silverized elastomers and that of the conventional elastomers.

Identification Method of the Dynamic Characteristics of Pre-deformed Elastomers (초기 변형이 있는 방진고무의 동특성 규명 방법)

  • Ahn, Tae-Kil;Kim, Kug-Weon
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.13 no.12
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    • pp.918-922
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    • 2003
  • Elastomers are extensively used in various machine design application, mainly for vibration/shock/noise control devices. However. there are still a lot of difficulties in designing the elastomeric components applied in complex shapes and under pre-deformed states. One of the most Influential factors related to mechanical properties of elastomers are pre- and dynamic strains. Consequently, a large number of experiments have to be conducted to identify dynamic properties of elastomers considering their combined effects. In this paper, we present an efficient experimental method to identify mechanical properties of elastomers considering effects of pre- and dynamic strains. This method is capable of predicting the dynamic characteristics of elastomers under arbitrary strain states from reduced experimental data.

Physical and chemical Cross-Linking Effects in Thermoplastic Polyurethane Elastomers with Different Macroglycol

  • Heo, Jae-Ho;Jeong, Du-Gam;Kim, Eun-Young;Kim, Han-Do
    • Proceedings of the Korean Fiber Society Conference
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    • 1997.10a
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    • pp.126-130
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    • 1997
  • A series of Thermoplastic polyurethane elastomers was prepared via a two-step polymerization process. The NCO/OH feed ratio of polyurethane synthesized in this study was varied from 1 to 1.3. Studies have been made on the effects of chemical and physical cross-linkina, and the properties of thermoplastic polyurethane elastomers based on isophorone diisocyanate (IPDI)/1,4-butanediol (BD)/poly(propylene glycol) (PPG, MW:2000), isophorone diisocyanate (IPDI)/BD /poly(oxytetramethylene) glycol (PTMG, MW:2000) was compared. These materials were characterized using FTIR spectrometer, dynamic mechanical thermal analyzer, and tensile retraction tester. PTMG based polyurethane elastomers showed higher elasomeric behavior than PPG based polyurethane elastomers at the same NCO/OH ratio. This feature has been connected with the specific nature of the polyols. The permanent set(%) was decreased with increasing maximum elongation from 50% to 300%.

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Selection Attributes and Trends of Thermoplastic Elastomers for Automobile Parts

  • Kim, Seongkyun;Park, Joon Chul;Jo, Mi Young;Park, Jun Il;Bae, Jae Yeong;Choi, Seok Jin;Kim, Il
    • Elastomers and Composites
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    • v.52 no.1
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    • pp.48-58
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    • 2017
  • Thermoplastic elastomers (TPEs), a unique class of polymers, combine the processing ease of thermoplastics with the advanced properties of thermoset rubbers. TPEs can be remelted several times without any significant loss of properties, and can be molded into complex shapes using conventional processing equipment. Due to their characteristics, TPEs are ideal for use in a variety of applications in the automotive field. Although the TPE market of the Republic of Korea is currently at its niche, the increasing manufacturing push from major companies is expected to open up multiple opportunities for these products in the automotive sector. This manuscript highlights a detailed technological trend of the global automotive thermoplastic elastomers market.

Friction and Wear Properties of Improved Polyurethane Based Magneto-Rheological Elastomer (향상된 폴리우레탄 기반 자기유변탄성체의 마찰 마모 특성연구)

  • Lian, Chenglong;Hong, Sung-Geun;Lee, Kwang-Hee;Lee, Chul-Hee;Kim, Cheol-Hyun
    • Tribology and Lubricants
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    • v.28 no.6
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    • pp.333-339
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    • 2012
  • Typical magneto-rheological (MR) elastomers consist of silicon-based material. A number of studies have been carried out to evaluate the vibration and tribological characteristics of silicon-based MR e-lastomers. However, these elastomers have quite low strength, so they have low wear resistance. In this study, polyurethane-based MR elastomers with performances better than those of MR elastomers. Experiments have been conducted on different MR elastomers (Pu MR elastomer, Pu-Si MR elastomer, and Pu-wrapped-Si MR elastomer) and different predefined magnetic directions (Non-Direction, Vertical Direction, and Horizontal Directionality) to evaluate the friction and wear performance under a magnetic field. The results show that Pu-wrapped-Si MR elastomer with a horizontal predefined magnetic field has the best performance in terms of wear.

The Use of Chemical Additives to Protect SBS Rubbers Against Ozone Attack

  • Moakes, C.A.
    • Elastomers and Composites
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    • v.34 no.2
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    • pp.177-182
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    • 1999
  • SBS thermoplastic elastomers offer an inexpensive alternative to vulcanised rubbers for many undemanding applications. They are, however, particularly susceptible to attack from atmospheric ozone leading to cracking as soon as any strain is applied. In most rubber applications some strain is unavoidable. In this paper a compounding approach to protecting SBS thermoplastic rubbers against ozone is described. An explanation is offered for why a protective effect Is observed only when certain combinations of additive are used. SBS elastomers are the most affordable class of thermoplastic rubbers. To achieve finished products resistant to ozone and without compromising the light colours often demanded, recourse must be made to blending with other saturated elastomers or replacement by hydrogenated (SEBS) types. The latter is a significantly more expensive alternative. Under laboratory conditions where the rate of ozone attack is increased by several decades, unprotected SBS begins to crack within a few hours. Several different protective agents are examined here, the best of which, a cyclic enol ether, $Vulkazon^{(R)}$ AFD, can extend the resistance to any cracking to several weeks by the use of a few percent by weight of additive. The systems reported neither discolour the polymer nor stain other materials with which it may be in contact. Use of the protective systems described here could enable SBS elastomers to compete in many applications with the more expensive SEBS polymers.

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Biaxial Tensile Behaviors of Elastomeric Polymer Networks

  • Shinzo, Kohjiya
    • Elastomers and Composites
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    • v.38 no.2
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    • pp.175-179
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    • 2003
  • For the total description of mechanical behaviors of elastomers, it is necessary to know the so-called rheological constitutive equation i.e. the strain-energy density function (W) in case of elastomers, which necessitates biaxial tensile results of elastic body. This paper first describes the experimental results of biaxial tensile measurements on poly(siloxane) model networks. W was estimated from its differential form i.e. the $1^{st}$ differential of W is stress. The W was found to reproduce the experimental stress-strain results, and the W estimated for silica filled poly(siloxane) networks suggest a different behavior between conventional precipitated silica and in situ formed silica. The difference suggests the different surface property of the two silicas.

Preparation of Nylon Elastomer and Its Application in the Electrospinning Process (나이론탄성체 제조와 전기방사응용)

  • Park, Jun-Seo;Ketpang, Kriangsak
    • Elastomers and Composites
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    • v.44 no.3
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    • pp.274-281
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    • 2009
  • Nylon 6 and nylon elastomer were prepared by anionic polymerization route. Nylon elastomers, composed of hard segment of polyamide(PA) and soft segment of polyether(PE), were synthesized by use of TDI terminated polyol with caprolactam. The morphology of the electrospun webs of nylon and nylon elastomers, observed by FE-SEM, showed that the porous electrospun web was composed of nanofibers, whose diameter were in the range of 100 to 180 nm. Their behavior of melting and crystallization and the chemical structure of nylon elastomers were investigated by DSC and ATR FT-IR. Result of tensile testing indicated that nylon has higher tensile strength and lower elongation than nylon elastomers. Atmospheric plasma(APP) with $O_2$ and $N_2$ as reactive gas modified the surface of electrospun nylon and electrospun nylon elastomers allowing them higher hydrophilicity, while APP with $CH_4$ as reactive gas modified the surface of polymers allowing higher hydrophobicity.

A Study on the Vibration Characteristics of MR Elastomers Based on Silicon (실리콘기반 자기유변탄성체의 진동특성 연구)

  • Park, Jeong-Heon;Lee, Chul-Hee;Kim, Cheol-Hyun;Cho, Won-Oh
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.21 no.8
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    • pp.714-719
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    • 2011
  • This paper presents vibration characteristics of magnetorheological(MR) elastomer, whose elastic modulus are controllable by applied magnetic field. By using this property, the material can be applied to vibration absorber, so that the stiffness of the absorber can be changed and actively controlled according to the magnetic flux density. However, the various performances of MR elastomer depends on different polarized direction of particles by applied magnetic field and dimension during the manufacturing process. In this paper, in order to obtain the optimal characteristics of MR elastomer, MR elastomers with different types and dimensions are prepared for a series tests. Using this test setup, extent of natural frequency shifted against magnetic field at various excitation frequencies can be measured. Specimens are prepared with 3 types, as cylinder samples exposed to magnetic field vertically, horizontally and unexposed during cure, respectively. Also, a set of design variables are considered to produce MR elastomers. Through the modal tests of mass structure with MR elastomer, the optimal design as well as the polarization direction of MR elastomer is obtained among the various dimensions and 3 directional types of MR elastomers.

A Study on the Vibration Characteristics of MR Elastomers Based on Silicon (실리콘기반 자기유변탄성체의 진동특성연구)

  • Park, Jeong-Heon;Lee, Chul-Hee;Kim, Cheol-Hyun;Cho, Won-Oh
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2011.04a
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    • pp.752-757
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    • 2011
  • This paper presents vibration characteristics of magnetorheological (MR) elastomer, whose elastic modulus are controllable by an applied magnetic field. By using this property, the material can be applied to vibration absorber, so that the stiffness of the absorber can be changed and actively controlled according to the magnetic flux density. However, the various performances of MR elastomer depends on different magnetically polarization direction and dimension during the manufacturing process. In this paper, in order to obtain the optimal characteristics of MR elastomer, MR elastomers with different types and dimensions are prepared for a series tests. Using this test setup, extent of natural frequency shifted against magnetic field at various excitation frequencies can be measured. Specimens prepared with 3 types which are exposed to magnetic field vertically, horizontally and unexposed during cure. Also, a set of design variables are considered to produce MR elastomers. Through the modal tests of mass structure with MR elastomer, the optimal design as well as the polarization direction of MR elastomer is obtained among the various dimensions and 3 directional types of MR elastomers.

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