• 한국토양환경학회지
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• 제1권2호
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• pp.83-90
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• 1996

토양내에서의 가스나 증기상의 오염물질의 이동은 여러 가지 현상에 의해서 일어나고 있으나 농도차에 의해서 일어나는 확산이 가장 중요하다. 그런데 토양내에서의 확산은 토양 입자들로 인한 확산 부피의 감소, 또 확산경로의 불규칙성, 확산 경로에 있어서 단면적의 변화 등으로 인해 대기중에서 일어나는 확산과는 다른 면을 보인다. 본 논문에서는 이러한 현상을 설명하기 위하여 흔히 사용되는 굴절계수(toruosity), 유효확산계수(effective diffusion coefficient)의 서로 다른 그러나 같은 이름으로 사용되는 많은 정의들과 다양한 수학적 모델들에 대한 비교 검토가 이루어졌다. 굴절계수나 유효확산계수를 사용할 때는 각각의 경우 정의와 각 식의 특징에 대하여 세밀한 검토와 주의가 행하여져야 한다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2001년도 봄 학술발표회 논문집
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• pp.677-682
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• 2001

In this study, a method to evaluate diffusion coefficient of chloride ion in cracked concrete is proposed. For cracked concrete having either anisotropic or isotropic crack network, each crack of saturated concrete is considered as a V shape crack, and an effective diffusion coefficient is expressed with diffusion coefficients of cracked part and noncracked part and a so-called crack spacing factor. A comparison with experimental results shows that the diffusion coefficient for cracked concrete is accurately predicted by the effective diffusion coefficient. Prediction results also show that the cracks in concrete markedly change the diffusion properties and accelerate penetration of drifting species. The method in this paper can be effectively used to consider the effect of cracks on concrete diffusion coefficient of cracked concrete.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 1996년도 경북지부 결성 및 추계학술발표회 논문집
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• pp.58-62
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• 1996

To check the variability of the effective diffusion coefficient in the unsaturated porous soil media. a Monte Carlo simulation was done for the equation suggested by Millington and Quirk(1961). The results shows that the probability density function of D$_{c}$/D$_{o}$ is positively skewed. It means the chance of having less effective diffusion coefficient values in the soil media than mean value is high. Also, the distribution types of D$_{c}$/D$_{o}$ are about same regardless of assumed distribution types of input parameters.ers.ers.

• 한국지반환경공학회 논문집
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• 제3권1호
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• pp.13-26
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• 2002

본 연구에서는 아연 및 카드뮴의 확산계수에 미치는 온도영향에 대한 연구를 위해 $15^{\circ}C$와 $55^{\circ}C$에서 확산실험을 수행하였다. 온도변화에 따른 유효확산계수의 변화를 비교할 경우 두 금속 모두에서 $55^{\circ}C$에서의 유효확산계수가 $15^{\circ}C$에서의 확산계수에 비해 최대 10배까지 큰 것으로 나타났다. 그리고 온도증가에 따른 확산속도의 증가와 더불어 중금속들의 흡착량 또한 증가하는 것으로 나타났다. 그러므로 지연인자를 얻는 방법의 차이에 따라 비교적 흡착량을 과다하게 평가하는 흡착실험을 통해 얻은 지연인자를 이용하여 유효확산계수를 산정할 경우 확산계수를 과대평가 할 수 있다. 그리고 연속추출 실험 결과, 아연의 경우에는 탄산염 형태로의 분배경향이 가장 크게 나타났고, 카드뮴의 경우에는 이온교환형태로의 분배가 가장 크게 나타났다. 특히 실험을 수행한 온도가 증가함에 따라 아연 확산실험의 경우에는 탄산염 형태와 유기물 형태로의 분배가 증가하는 것으로 나타났다. 반면 카드뮴 확산실험의 경우에는 온도변화와 무관하게 60%이상이 이온교환 형태로 분배됨을 알 수 있었다.

• 한국표면공학회지
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• 제44권5호
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• pp.207-212
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• 2011

In this study, the change in diffusion coefficient and wear characteristic with depth in the carbonitriding layer of SCM415 steel was discussed. To determine the diffusion coefficient, depth profile of carbon was measured from the surface using the Glow Discharge Spectrometer. In otherwise, measurements of carbide fraction, micro vickers hardness of surface and observation of microstructure have been implemented through the SEM image. $Fe_3$(C,N) layer and effective depth were increased as the time for carbonitriding takes longer. According to wear experiment, the results showed that wear resistance was improved by $Fe_3$(C,N) layer and effective depth.

• 한국방송∙미디어공학회:학술대회논문집
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• 한국방송공학회 2009년도 IWAIT
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• pp.492-497
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• 2009

Computer-Generated Hologram (CGH) is made for three dimensional image of a virtual object. Error diffusion method is used for the phase quantization of CGH, and it is known to be effective to the image quality improvement of the reconstructed image. However, the image quality of the reconstructed image from the CGH using error diffusion method depends on the selection of error diffusion coefficient. In this paper, we derived the relational expression to obtain the error diffusion coefficient from the position of the input object and size of the input object for CGH. As a result, the method of this thesis was able to obtain an excellent reconstructed image compared with the case to derive the error diffusion coefficient from only the position of the input image.

• 대한기계학회논문집B
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• 제20권9호
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• pp.3015-3029
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• 1996

The notion of effective transport property of a heterogeneous medium implies that the medium is large enough that the ergodic theorem holds and local fluctuation of the property can be neglected. In case that the medium is not large enough compared to its characteristic microstructure length scale, the effective property fluctuates and differs from the value of the medium being large enough. As a representative transport phenomenon, diffusion was considered and the fluctuation of varying effective diffusion property, diffusion coarseness $C_k$, was defined as a quantifying parameter. Scaled effective diffusion property, $^*$>/k$_1$ and $C_k$ were computed for the two phase random media consisting of matrix of diffusion coefficient k$_1$ and spheres of diffusion coefficient k$_2$. Numerical simulations were performed by use of the so-called first passage time technique and data were collected for existing microstructure models of hard spheres(HS), overlapping spheres(OS) and penetrable concentric shells(PCS).

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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• pp.269-272
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• 2006

Chloride ion diffusion is the most important thing of occuring deterioration in RC structure. So it is important to decide the precise chloride ion diffusion coefficient in order to predict the durability life in RC structure. The purpose of this study is to analyze the established data, which are restricted by chloride diffusion coefficient, and to calculate chloride ion diffusion coefficient using RCPT test. To examine the prediction of the concrete structure durability by an FEM analysis and the chloride diffusion coefficient as a variable. Each surface finishing materials were effective on the increment of chloride penetration resistance, but showed a little different effect depending on the type of surface finishing material.

• Computers and Concrete
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• 제15권3호
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• pp.461-471
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• 2015

The permeability is the most direct indicator to reflect the durability of concrete, and the testing methods based on external electric field can be used to evaluate concrete permeability rapidly. This study aims to use an experiment method to accurately predict the permeability of concrete box beam during service. The ion migration experiments and concrete surface resistivity are measured to evaluate permeability of five concrete box beams, and the relations between these results in service concrete and electric flux after 6 hours by ASTM C1202 in the laboratory are analyzed. The chloride diffusion coefficient of concrete, concrete surface resistivity and concrete 6 hours charge have good correlation relationship, which denote that the chloride diffusion coefficient and the surface resistivity of concrete are effective for evaluating the durability of concrete structures. The chloride diffusion coefficient of concrete is directly evaluated permeability of concrete box beam in service and may be used to predict the service life, which is fit to engineering applications and the concrete box beam is non-destructive. The concrete surface resistivity is easier available than the chloride diffusion coefficient, but it is directly not used to calculate the service life. Therefore the mathematical relation of the concrete surface resistivity and the concrete chloride diffusion coefficient need to be found, which the service life of reinforced concrete is obtained by the concrete surface resistivity.

• International Journal of Concrete Structures and Materials
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• 제4권2호
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• pp.105-108
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• 2010

In order to determine the effect of the use of limestone sand on chloride ion ingress in mortar, specimens were cast with two different sands: siliceous sand (used as reference) and limestone crushed sand (used for this study). To compare and assess the resistance of this mortar to chloride penetration, two different diffusions tests were employed: slow migration and rapid migration (AASHTO test). In this study, calculation of the effective diffusion coefficient is proposed using a model based on Nernst. Planck equation. The diffusion coefficients from each sample were compared. The results for all tests show that the diffusion coefficients for siliceous sand mortar are larger than those obtained with limestone sand. It appears also that the diffusion coefficient varies as a function of the W/C ratio.