Kim, Seong Wan;Kang, Sin Up;Cho, Seong Seup;Sung, Chan Yong
Korean Journal of Agricultural Science
/
v.10
no.2
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pp.310-323
/
1983
To study the effect of foaming agent on the production and property of light weight concrete, the tests of compressive, tensile, bending strengths and absorption rates of mortar were done under the different mixing ratio with J, A and D foaming agents. The results obtained were summarized as follows : 1. The strengths were decreased in richer mixing ratio and more addition of foaming agent. The decrease of strengths was the greatest at the level of 0.75% of foaming agent. The decreasing rate of strengths was in order of J, A and D foaming agent. 2. At the mixing ratio of 1:1, ${\sigma}_{28}$ and 0.75% of foaming agent, the compressive strength was decreased up to 34.9% by D, 47.8% by A and 86.8% by J foaming agent, respectively, the tensile strength was decreased up to 14.8% by D, 20.2% by A and 77.9% by J foaming agent, respectively, bending strength was decreased up to 19.9% by D, 35.0% by A and 79.1% by J foaming agent, respectively. The decrease of compressive strength was more severe than that of tensile and bending strengths. 3. The absorption rates were increased in poorer mixing ratio and more addition of foaming agent. The absorption rate was significantly higher at the early stage of immersed water. The absorption rate was in order of J, A and D foaming agent. 4. The decrease of strengths was inevitable in cement-mortar with foaming agent, but the cement mortar with foaming agent has such the properties of the light-weight, lnsulation, Keeping-warmth, sound proof and fire-proof that if could be utilized to the constructions which need low strengths.
Park, JongTak;Oh, Hongseob;Jung, Gwon Soo;Kang, Chang Ho
Journal of the Korean Recycled Construction Resources Institute
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v.8
no.1
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pp.8-16
/
2020
As the circulating fluidized bed combustor(CFBC) boilers system to generate electric power increase in order to reduce environmental pollution, a lot of CFBC fly ashes(CFFA) are produced. CFFA has limited use in concrete because it contains free CaO, which can cause cement expansion and rapid initial hydration. In this study, the microstructure and the initial development of compressive strength characteristics were experimentally analyzed to be used as a stimulant to replace natural gypsum by mixing with CFFA and phosphate gypsum to enhance the initial strength of portland blast furnace slag cement. The recycled gypsum was used as flue-gas desulfurization gypsum and phosphate gypsum. Experimental results show that the initial strength development is relatively lower when CFFA and dihydrate gypsum are mixed, but the strength improvement effect of the mixture with CFFA and anhydrous gypsum as an anhydritedII typed crystalized gypsum is similar to that of natural gypsum. As a result, it w as analyzed to have high possibility of use for stimulant of portland blast furnace slag cement.
Resin-modified glass ionomers were introduced in 1988 to overcome the problems of moisture sensitivity and low early mechanical strengths of the conventional glass ionomers, and to maintain their dinical advantages. The purpose of this study was to evaluate the bi-axial fracture strength of four resinmodified glass-ionomers(Fuji II LC, Vitremer, Dyract, VariGlass), one resin composite material(Z-100), and one conventional glass-ionomer(Fuji II). Three specimens of each material and shade combination were made according to the manufacturers' instructions. Materials were condensed into metal mold with a diameter of 10mm and a thickness of 2.0mm and pressed between two glass plates. Resin-modified glass ionomers were polymerized using a Visilux II light curing unit by irradiating for 60 seconds from both sides, and conventional glass ionomer was cured chemically. After specimens were removed from the molds, surfaces were polished sequentially on wet sandpapers up to No. 600 silicone carbide paper. The specimens were thermocycled for 2,000 cycles between $5^{\circ}C$ and $55^{\circ}C$ distilled water. After thermocycling, bi-axial fracture strengths were measured using a compressive-tensile tester(Zwick 1456 Z020, Germany) with the cross head speed of 0.5mm/minute. The results were as follows: 1. Two factors of the kind and color of materials had a main effect on bi-axial fracture strength (p<0.01), and bi-axial fracture strength was influenced significantly by the kinds of materials (p<0.01). But there was no significant interaction between two variables of the kind and color of materials (p>0.05). 2. Comparing the mechanical properties of the materials, the elastic modulus of Z100 was higher than any other material, and there was no difference in the displacement at fracture among materials. The bi-axial fracture strength of Z100 was significantly higher than any other material, and that of resin-modified glass ionomers was significantly higher than that of conventional glass ionomer (p<0.05). 3. In the same material group, the color of material had little influence on the mechanical properties.
Journal of the Korea institute for structural maintenance and inspection
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v.21
no.3
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pp.54-59
/
2017
GGBFS (Ground Granulated Blast Furnace Slag) is a byproduct with engineering advantages and HVSC (High Volume Slag Concrete) is widely attempted due to active utilization and reduction of eco-load. In the present work, characteristics of drying shrinkage and early-aged behavior are evaluated for the concrete with 65% replacement ratio of GGBFS and 50MPa of design strength. For the work, 3 different mix conditions are considered and several tests including slump flow, compressive strength, drying and autogeneous shrinkage are performed. From the test, OPC 100 mixture without replacement shows higher strength development before 7 days, however the strength reduction in concrete replaced with GGBFS is not significant due to sufficient free water for cement hydration. OPC 100 mixture also shows significant drying shrinkage due to a great autogeneous shrinkage before 3 days. In the concrete with GGBFS replacement, the drying shrinkage behavior is improved due to relatively small deformation by autogeneous shrinkage. The mixture (OPT BS 65) with lower w/b ratio (0.27) and unit content of water ($160kg/m^3$) shows more improved shrinkage behavior than BS 65 mixture which has simple replacement of GGBFS with 0.30 of w/b and $165kg/m^3$ of water unit content.
Influence of sulfate on the early hydration in the solidification treatment of abandoned mine tailings was characterized. Solidified specimens using hydrated lime as a binder were prepared with various amounts of added $Na_2SO_4$ and different curing days. Unconfined compressive strength measurement, heavy metal leaching test, XRD analysis were performed after 7-, 14- and 28-days curing. According to curing days strength of solidified specimens using only distilled water increased but those with addition of $Na_2SO_4$ decreased. External cracks of specimens developed definitely with increasing $Na_2SO_4$ concentration and curing days. Concentrations of Cu, Cd, Zn, and As in the leached solutions from solidified specimens decreased significantly but Pb was leached readily in cases of hydrated lime dosage more than 10 wt%. Gypsum and $MgSO_4$ were identified in the cracked solidified specimens by XRD analysis, and pillar-shaped crystals of SEM image were identified as gypsum in reference with EDS analysis. Crystallization of sulfate in the process of lime-tailing solidification caused cracking, which should be supplemented for solidification treatment of highly sulfur-contained tailing.
Journal of the Korean Recycled Construction Resources Institute
/
v.5
no.3
/
pp.275-281
/
2017
This study is to investigate experimentally the effect of refining of fly ash (FA) on the engineering properties of the cement mortar. Five different FAs are used including raw fly ash, refined fly ash, reject ash and their two different combinations. The cement mortars are fabricated with 1:1(binder to fine aggregate), 1 : 3 and 1 : 5 respectively, which are replaced 30% of FA by cement. Test results, indicated that, the flow of Ra showed lower flowability than Rf at all mixing ratios. Also in the case of Rj, it was expected to show low fluidity, but it showed flowability equal to or higher than Rf. Air contents are all formulations except Rf and Rj did not satisfy the target range. Using Ra, the refining process shows an air amount about 41% lower than Rf, in the case of Rj, it showed about 19% higher air content than Rf due to porous foreign matters inside the mortar. Compressive strength was in the early days 3 and 7, the strength was lower than that of Plain's OPC, after 28 days Rf exerts higher strength than other FAs, it was confirmed that higher strength than OPC can be secured at a mixing ratio of 1: 1 and 1: 3. For frost resistance, the use of unrefined FA resulted in decrease of frost resistance sharply due to loss of air content by the use of unrefined FA. Therefore, it is considered that the use of high quality FA through refining process will contribute positively to the economical formulation of concrete and the stability of the structure.
Lee Hyomin;Jun Ssang-Sun;Hwang Jin-Yeon;Jin Chi-Sub;Yoon Jihae;Ok Soo Seok
Journal of the Mineralogical Society of Korea
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v.17
no.3
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pp.277-288
/
2004
Alkali-silica reaction (ASR) is a chemical reaction between alkalies in cement and chemically unstable aggregates and causes expansion and cracking of concrete. In the Present study, we studied the effects of metakaolin, which is a newly introduced mineral admixture showing excellent pozzolainc reaction property, on the inhibition of ASR. We prepared mortar-bars of various replacement ratios of metakaolin and conducted alkali-silica reactivity test (ASTM C 1260), compressive strength test and flow test. We also carefully analyzed the mineralogical changes in hydrate cement paste by XRD qualitative analysis. The admixing of metakaolin caused quick pozzolanic reaction and hydration reaction that resulted in a rapid decrease in portlandite content of hydrated cement paste. The expansion by ASR was reduced effectively as metakaolin replaced cement greater than 15%. This resulted in that the amounts of available portlandite decreased to less than 10% in cement paste. It is considered that the inhibition of ASR expansion by admixing of metakaolin was resulted by the combined processes that the formation of deleterious alkali-calcium-silicate gel was inhibited and the penetration of alkali solution into concrete was retarded due to the formation of denser, more homogeneous cement paste caused by pozzolanic effect. Higher early strength (7 days) than normal concrete was developed when the replacement ratios of metakaolin were greater than 15%. And also, late strength (28 days) was far higher than normal concrete for the all the replacement ratios of metakaolin. The development patterns of mechanical strength for metakaolin admixed concretes reflect the rapid pozzolanic reaction and hydration properties of metakaolin.
Concrete is a durable and cost-benefit construction material, however performance degradation occurs due to steel corrosion exposed to chloride attack. Penetration of chloride ion usually decreases due to hydrates formation and reduction of pores, and the reduced chloride behavior is considered through decreasing diffusion coefficient with time. In the work, HPC (High Performance Concrete) samples are prepared with 3 levels of W/B (water to binder) ratios of 0.37, 0.42, and 0.27 and 3 levels of replacement ratios of 0%, 30% and 50%. Several tests containing chloride diffusion coefficient, passed charge, and compressive strength are performed considering age effect of 28 days and 180 days. Chloride diffusion is more reduced in OPC concrete with lower W/B ratio and GGBFS concrete with 50% replacement ratio shows significant reduction of chloride diffusion in higher W/B ratio. At the age of 28 days, GGBFS concrete with 50% replacement ratio shows more rapid reduction of chloride diffusion than strength development, which reveals that abundant GGBFS replacement has effective resistance to chloride penetration even in the early-aged condition.
Journal of the Korean Recycled Construction Resources Institute
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v.8
no.2
/
pp.235-244
/
2020
This study conducted a series of studies to offer a novel method of using CBS-dust that produced as by-product in the manufacture of cement. Four different contents of BS and CBS-dust were adopted for test parameters of this study. Mortar with 50% of W/B was fabricated. First, in the case of the fresh mortar, the flow decreased as the CBS-dust replacement rate increased, but the binder composition ratio BS 45% and 65% showed higher fl ow than Pl ain when repl acing CBS-dust 5%. In the case of air content, overall, the tendency was proportional to the CBS-dust replacement rate, and chloride tended to exceed the reference value at all replacement rates except for the CBS-dust 0% replacement. The compressive strength of the hardened mortar shows the resul t that the strength is improved when the CBS-dust is repl aced by 5% to 10%, and the CSH gel and structure formation is confirmed by microstructure analysis through the hydration reaction when the CBS-dust is replaced. Therefore, for a given condition CBS-dust is used as a early-strength admixture in a concrete secondary product that uses a large amount of admixture without reinforcing bars it can be an effective method for enhancing the strength of concrete as an alkali activator.
Journal of the Korea Institute of Building Construction
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v.9
no.4
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pp.55-61
/
2009
Recently, the number of high-rise buildings being built in Korea by major construction companies for residential and commercial use has been increasing. When constructing a high-rise building, it is necessary to apply massive amounts of concrete to form a mat foundation that can withstand the huge load of the upper structure. However, it is of increasing concern that due to limitations in terms of the amount of placing equipment, available job-sites and systems for mass concrete placement in the construction field, it is not always possible to place a great quantity of concrete simultaneously in a large-scale mat foundation, and for this reason consistency between placement lift cannot be secured. In addition, a mat foundation Is likely to crack due to the stress caused by differences inhydration heat generation time. To derive a solution for these problems, this study provides test results of a hydration heat crack reduction method by applying placement lift change and setting time control with a super retarding agent for mass concrete in a large-scale mat foundation. Mock-up specimens with different mixtures and placement liftswere prepared at the job-site of a newly-constructed high-rise building. The test results show that slump flow of concrete before and after adding the super retarding agent somewhat Increases as the target retarding time gets longer, while the air content shows no great difference. The setting time was observed to be retarded as the target retarding time gets longer. As the target retarding time gets longer, compressive strength appears to be decreased at an early stage, but as time goes by, compressive strength gets higher, and the compressive strength at 28 days becomes equal or higher to that of plain concrete without a super retarding agent. For the effect of placement lift change and super retarding agent on the reduction of hydration heat, the application of 2 and 4 placement lifts and a super retarding agent makes it possible to secure consistency and reduce temperature difference between placement lifts, while also extending the time to reach peak temperature. This implies that the possibility of thermal crack induced by hydration heat is reduced. The best results are shown in the case of applying 4 placement lifts.
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