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X-ray Absorption and Photoemission Spectroscopy Study of Nd1/2A1/2Mn1-yCryO3(A=Ca, Sr)

  • Kang, J.S.;Kim, J.H.;Han, S.W.;Kim, K.H.;Choi, E.J.;Sekiyama, A.;Kasai, S.;Suga, S.;Kimura, T.
    • Journal of Magnetics
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    • v.8 no.4
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    • pp.142-145
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    • 2003
  • Valence states and electronic structures of Cr-doped $Nd_{1/2}A_{1/2}Mn_{1-y}Cr_{y}O_3$(NAMO; A=Ca, Sr) manganites have been investigated using x-ray absorption spectroscopy (XAS) and high-resolution photoemission spectroscopy (PES). All the Cr-doped NAMO systems exhibit the clear metallic Fermi edges in the Mn $e_{g}$ PES spectra near $E_{F}$. The spectral intensity at $E_{F}$ is higher for Cr-doped N $d_{l}$ 2/S $r_{l}$ 2/Mn $O_3$(NSMO) than for Cr-doped N $d_{l}$ 2/C $a_{l}$ 2/Mn $O_3$ (NCMO), reflecting the stronger metallic nature for NSMO than for NCMO. The measured Cr 2p XAS spectra are found to be very similar to that of C $r_2$ $O_3$, indicating that Cr ions in Cr-doped NAMO are in the trivalent C states ( $t^3$$_{2g}$). The Cr 2p XAS data are consistent with the Cr 3d PES spectra located at ∼1.3 eV below $E_{F}$ and having no emission near $E_{F}$.

The Relation between the Phase-Shift Profile for the Intermediate Frequencies and the Langmuir Adsorption Isotherm (중간주파수에서 위상이동 변화와 Langmuir흡착등온식 사이의 관계)

  • Chun Jang Ho;Mun Kyeong Hyeon;Cho Chong Dug
    • Journal of the Korean Electrochemical Society
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    • v.3 no.1
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    • pp.25-30
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    • 2000
  • The relation between the phase-shift profile for the intermediate frequencies and the Langmuir adsorption isotherm at the poly-$Pt/0.1\;M\;H_2SO_4$ aqueous electrolyte interface has been studied using ac impedance measurements, i.e., the phase-shift methods. The suggested interfacial equivalent circuit consists of the serial connection of the electrolyte resistance ($R_S$), the faradaic resistance $(R_F)$ and the equivalent circuit element $(C_P)$ of the adsorption pseudocapacitance $(C_\varphi)$. The delayed phase shift $(\varphi)$ depends on both the cathode potential (E) and frequency (f), and is given by $\varphi=-tan^{-1}[1/2{\pi}f(R_s+R_F)C_p]$. The phase-shift profile $(\varphi\;vs.\;E)$ for the intermediate frequency (ca. 6Hz) can be used as an experimental method to determine the Langmuir adsorption isotherm (9 vs. E). The equilibrium constant (K) for H adsorption and the standard free energy $({\Delta}G_{ads})$ of H adsorption at the poly-$Pt/0.1\;M\;H_2SO_4$ electrolyte interface are $1.8\times10^{-4}\;and\;21.4kJ/mol$, respectively. The H adsorption is attributed to the over-potentially deposited hydrogen (OPD H).

ON H$\grave{a}$JEK-R$\grave{e}$NYI-TYPE INEQUALITY FOR CONDITIONALLY NEGATIVELY ASSOCIATED RANDOM VARIABLES AND ITS APPLICATIONS

  • Seo, Hye-Young;Baek, Jong-Il
    • Journal of applied mathematics & informatics
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    • v.30 no.3_4
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    • pp.623-633
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    • 2012
  • Let {${\Omega}$, $\mathcal{F}$, P} be a probability space and {$X_n|n{\geq}1$} be a sequence of random variables defined on it. A finite sequence of random variables {$X_n|n{\geq}1$} is said to be conditionally negatively associated given $\mathcal{F}$ if for every pair of disjoint subsets A and B of {1, 2, ${\cdots}$, n}, $Cov^{\mathcal{F}}(f_1(X_i,i{\in}A),\;f_2(X_j,j{\in}B)){\leq}0$ a.s. whenever $f_1$ and $f_2$ are coordinatewise nondecreasing functions. We extend the H$\grave{a}$jek-R$\grave{e}$nyi-type inequality from negative association to conditional negative association of random variables. In addition, some corollaries are given.

Long Term Formaldehyde Emission Trend of Wood Panels Manufactured by F/U Molar Ratios in Urea Resin Adhesive (요소수지의 F/U 몰비별로 제조된 목질패널의 포름알데히드 장기 방출 경향)

  • Park, Heon
    • Journal of the Korea Furniture Society
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    • v.11 no.2
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    • pp.73-78
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    • 2000
  • This study was carried out to measure formaldehyde emission with the passing of two years from plywood, sliver-board and strand-board bonded with urea resins which were made of 6 f/U molar ratios. The urea resins were manufactured by six kinds of formaldehyde/urea molar ratio of 1.0, 1.2, 1.4, 1.6, 1.8 and 2.0. 1. The plywood with molar ratio of 1.0 satisfied the KS F3101 $F_2$ directly after manufacture. The plywood with molar ratio of 1.2 satisfied m 3 days. The plywood with molar ratio of 1.4 satisfied the $F_3$ in 3 days and the $F_2$ in 600 days. And the plywood with molar ratio of 1.8 and 2.0 satisfied the $F_3$ in 365 days, but didn't satisfy the $F_2$ in 730 days. 2. Sliver-board with molar ratio of 1.0 and 1.2 satisfied the KS F3104 $E_2$ right after manufacture. Sliver-board with molar ratio of 1.4 and 1.6 satisfied in 150 and 360 days, respectively. Sliver-board with molar ratio of 1.8 and 2.0 satisfied in 730 days. 3. Strand-board with molar ratio of 1.0 and 1.2 satisfied the KS F3104$ E_2$ directly after manufacture. Strand-board with molar ratio of 1.4 and 1.6 satisfied in 150 days. But Strand-board with molar ratio of 1.8 and 2.0 didn't satisfied in 730 days.

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INTEGER POINTS ON THE ELLIPTIC CURVES INDUCED BY DIOPHANTINE TRIPLES

  • Park, Jinseo
    • Communications of the Korean Mathematical Society
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    • v.35 no.3
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    • pp.745-757
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    • 2020
  • A set {a1, a2, …, am} of positive integers is called a Diophantine m-tuple if aiaj + 1 is a perfect square for all 1 ≤ i < j ≤ m. In this paper, we find the structure of a torsion group of elliptic curves Ek constructed by a Diophantine triple {F2k, F2k+2, 4F2k+1F2k+2F2k+3}, and find all integer points on the elliptic curve under assumption that rank(Ek(ℚ)) = 2.

AN ALGEBRA WITH RIGHT IDENTITIES AND ITS ANTISYMMETRIZED ALGEBRA

  • Choi, Seul-Hee
    • Honam Mathematical Journal
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    • v.30 no.2
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    • pp.273-281
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    • 2008
  • We define the Lie-admissible algebra NW$({\mathbb{F}}[e^{A[s]},x_1,{\cdots},x_n])$ in this work. We show that the algebra and its antisymmetrized (i.e., Lie) algebra are simple. We also find all the derivations of the algebra NW$(F[e^{{\pm}x^r},x])$ and its antisymmetrized algebra W$(F[e^{{\pm}x^r},x])$ in the paper.

An Acoustic Study of Relative Articulatory Positions of English Vowels and Korean Vowels

  • Ahn, Soo-Woong
    • Speech Sciences
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    • v.8 no.4
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    • pp.171-184
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    • 2001
  • American English vowels and Korean vowels were compared by the plotformant method. For American English vowels, six General American English speakers pronounced English words in the b_t environment. For Korean vowels eight Kyongsang dialect speakers and eight Seoul dialect speakers pronounced Korean words in the environments of k_t, p_t and t_t. The formant plots were obtained by plotting F1/F2 tokens of 13 American English vowels on the F1xF2 plane. In spite of personal variations the 13 vowel spaces of all six American English speakers maintained their relative positions with some overlaps. Clear distinctions were made between i-I, e-$\varepsilon$, u-$\sigma$, and o-c. The domain of c and $\alpha$ overlapped for three American English speakers, but it did not for three other speakers. The 8 Korean vowel spaces of Kyongsang dialect speakers and Seoul dialect speakers were very similar and maintained their relative positions. No distinction was made between e and $\varepsilon$. In contrast with American English e which is a neutral vowel, Korean e was a back vowel. The comparison of 13 American English vowel positions and 8 Korean Vowel positions is expected to shed some light on the errors of English vowel pronunciation of Korean learners.

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SYMBOLIC DYNAMICS AND UNIFORM DISTRIBUTION MODULO 2

  • Choe, Geon H.
    • Communications of the Korean Mathematical Society
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    • v.9 no.4
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    • pp.881-889
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    • 1994
  • Let ($X, \Beta, \mu$) be a measure space with the $\sigma$-algebra $\Beta$ and the probability measure $\mu$. Throughouth this article set equalities and inclusions are understood as being so modulo measure zero sets. A transformation T defined on a probability space X is said to be measure preserving if $\mu(T^{-1}E) = \mu(E)$ for $E \in B$. It is said to be ergodic if $\mu(E) = 0$ or i whenever $T^{-1}E = E$ for $E \in B$. Consider the sequence ${x, Tx, T^2x,...}$ for $x \in X$. One may ask the following questions: What is the relative frequency of the points $T^nx$ which visit the set E\ulcorner Birkhoff Ergodic Theorem states that for an ergodic transformation T the time average $lim_{n \to \infty}(1/N)\sum^{N-1}_{n=0}{f(T^nx)}$ equals for almost every x the space average $(1/\mu(X)) \int_X f(x)d\mu(x)$. In the special case when f is the characteristic function $\chi E$ of a set E and T is ergodic we have the following formula for the frequency of visits of T-iterates to E : $$ lim_{N \to \infty} \frac{$\mid${n : T^n x \in E, 0 \leq n $\mid$}{N} = \mu(E) $$ for almost all $x \in X$ where $$\mid$\cdot$\mid$$ denotes cardinality of a set. For the details, see [8], [10].

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IDEMPOTENCE PRESERVING MAPS ON SPACES OF TRIANGULAR MATRICES

  • Sheng, Yu-Qiu;Zheng, Bao-Dong;Zhang, Xian
    • Journal of applied mathematics & informatics
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    • v.25 no.1_2
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    • pp.17-33
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    • 2007
  • Suppose F is an arbitrary field. Let ${\mid}F{\mid}$ be the number of the elements of F. Let $T_{n}(F)$ be the space of all $n{\times}n$ upper-triangular matrices over F. A map ${\Psi}\;:\;T_{n}(F)\;{\rightarrow}\;T_{n}(F)$ is said to preserve idempotence if $A-{\lambda}B$ is idempotent if and only if ${\Psi}(A)-{\lambda}{\Psi}(B)$ is idempotent for any $A,\;B\;{\in}\;T_{n}(F)$ and ${\lambda}\;{\in}\;F$. It is shown that: when the characteristic of F is not 2, ${\mid}F{\mid}\;>\;3$ and $n\;{\geq}\;3,\;{\Psi}\;:\;T_{n}(F)\;{\rightarrow}\;T_{n}(F)$ is a map preserving idempotence if and only if there exists an invertible matrix $P\;{\in}\;T_{n}(F)$ such that either ${\Phi}(A)\;=\;PAP^{-1}$ for every $A\;{\in}\;T_{n}(F)\;or\;{\Psi}(A)=PJA^{t}JP^{-1}$ for every $P\;{\in}\;T_{n}(F)$, where $J\;=\;{\sum}^{n}_{i-1}\;E_{i,n+1-i}\;and\;E_{ij}$ is the matrix with 1 in the (i,j)th entry and 0 elsewhere.

Non-Newtonian Intrinsic Viscosities of Biopolymeric and Non-biopolymeric Solutions (II)

  • Jang, Chun-Hag;Kim, Chang-Hong;Ree, Taik-Yue
    • Bulletin of the Korean Chemical Society
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    • v.8 no.4
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    • pp.332-335
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    • 1987
  • This paper is a continuation of our previous $paper,^1$ and deals with Eq.(1) (see the text), which was theoretically derived in the $paper,^1$$ [{\eta}]^f\; and\; [{\eta}]^0$ is the intrinsic viscosity at stress f and f = O, respectively. Equation (1) predicts how $[{{\eta}}]^f / [{\eta}]^0$ changes with stress f, relaxation time ${\beta}_2$ of flow unit 2 and a constant $c_2$ related with the elasticity of molecular spring of flow unit 2. In this paper, Eq.(1) is applied to a biopolymer, e.g., poly (${\gamma}$-benzyl L-glutamate), and nonbiopolymers, e.g., polyisobutylene, polystyrene, polydimethylsiloxane and cellulose triacetate. It was found that the $c_2$ factor is zero for non-biopolymers while $c_2{\neq}0$ for biopolymers as found $previously.^1$ Because of the non-Newtonian nature of the solutions, the ratio $[{{\eta}}]^f / [{\eta}]^0$ drops from its unity with increasing f. We found that the smaller the ${\beta}_2,$ the larger the $f_c$ at which the viscosity ratio drops from the unity, vice versa.