• 전기화학회지
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• 제9권1호
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• pp.19-28
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• 2006

The phase-shift method for determining the Langmuir, Frumkin, and Temkin adsorption isotherms ($\theta_H\;vs.\;E$) of H for the cathodic $H_2$ evolution reaction (HER) at a Pt/0.1 M KOH solution interface has been proposed and verified using cyclic voltammetric, differential pulse voltammetric, and electrochemical impedance techniques. At the Pt/0.1 M KOH solution interface, the Langmuir and Temkin adsorption isotherms ($\theta_H\;vs.\;E$), the equilibrium constants ($K_H=2.9X10^{-4}mol^{-1}$ for the Langmuir and $K_H=2.9X10^{-3}\exp(-4.6\theta_H)mol^{-1}$ for the Temkin adsorption isotherm), the interaction parameters (g=0 far the Langmuir and g=4.6 for the Temkin adsorption isotherm), the rate of change of the standard free energy of $\theta_H\;with\;\theta_H$ (r=11.4 kJ $mol^{-1}$ for g=4.6), and the standard free energies (${\Delta}G_{ads}^{\circ}=20.2kJ\;mol^{-1}$ for $k_H=2.9\times10^{-4}mol^{-1}$, i.e., the Langmuir adsorption isotherm, and $16.7<{\Delta}G_\theta^{\circ}<23.6kJ\;mol^{-1}$ for $K_H=2.9\times10^{-3}\exp(-4.6\theta_H)mol^{-1}$ and $0.2<\theta_H<0.8$, i.e., the Temkin adsorption isotherm) of H for the cathodic HER are determined using the phase-shift method. At intermediate values of $\theta_H$, i.e., $0.2<\theta_H<0.8$, the Temkin adsorption isotherm ($\theta_H\;vs.\;E$) corresponding to the Langmuir adsorption isotherm ($\theta_H\;vs.\;E$), and vice versa, is readily determined using the constant conversion factors. The phase-shift method and constant conversion factors are useful and effective for determining the Langmuir, Frumkin, and Temkin adsorption isotherms of intermediates for sequential reactions and related electrode kinetic and thermodynamic data at electrode catalyst interfaces.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2006년도 제37회 하계학술대회 논문집 C
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• pp.1459-1460
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• 2006

A new gas jet Z-pinch EUV light source having double gas jet electrodes has been developed. It has two nozzles and two diffusers. The EUV beam is collected from the side of pinch plasma, generated in between the inner nozzle and corresponding diffuser. A cylindrical shell of He gas curtain produced by the outer nozzle is specially designed for shielding the debris and suppressing the inner gas expansion. We have succeeded in generating EUV energy of 1.22 mJ/sr/2%BW/pulse at 13.5nm. The estimated dimension of EUV source is to be FWHM diameter of 0.07 mm and length of 0.34 mm, and FW 1/e2 diameter of 0.15 mm and length of 1.2 mm.

• 해양환경안전학회지
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• 제26권2호
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• pp.219-226
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• 2020

선체구조의 품질검사 중 가장 일반적인 방법의 하나는 비파괴검사이다. 하지만 복합소재 선체는 강화재와 수지로 구성된 여러가지 재료가 섞여 있고 또 생산환경과 작업자에 따라 FRP(Fiber-Reinforced Plastics) 제작품질에 차이가 발생할 가능성이 크기 때문에 정확한 검사평가는 쉽지 않은 일이다. 특히 FRP 선박의 경우에는 다른 구조물보다 두께가 매우 두껍고 주로 수척층 공법을 이용하기 때문에 더욱 그렇다. 초음파 탐상의 조건 중 검사체의 밀도가 매우 중요하기 때문에 본 연구에서는 FRP 선박 제작에 널리 사용되고 있는 소재와 유리섬유강화재 중량 비율로 제작된 선박의 외판을 검사체로 선정하고, Pulse-Echo 초음파 탐상기를 활용하여 GFRP(Glass Fiber-Reinforced Plastics) 선체 외판의 초음파 탐상을 위한 적정 조건을 조사하였다. 1.00 MHz, 2.25 MHz, 5.00 MHz 세 종류 탐촉자로 A-Scan을 실시하였으며 선체 외판의 두께 검사결과와 비교분석함으로써 적정 초음파 탐상 조건을 찾고자 하였다. 연구결과 탐촉자의 초음파 주파수가 높아질수록 수신자의 반사파 음향 속력을 감소시켜야 더 정도 높은 두께 측정 결과를 얻을 수 있었으며, 상대적으로 낮은 초음파 주파수 탐촉자에서 더 적은 오차가 발생함을 확인할 수 있었다.

• 한국산학기술학회:학술대회논문집
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• 한국산학기술학회 2011년도 추계학술논문집 1부
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• pp.262-265
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• 2011

본 연구는 탈진 기류 분사 시스템의 최적화 설계에 관한 기초 연구의 일환으로 전산유체역학(CFD)을 이용하여 일반 블로우 튜브와 단순 벤츄리 조합의 충격 기류(Pulse air jet) 방식의 탈진 장치에 대한 탈진 성능과 벤츄리 입구에 기류 유도용 구조물을 설치한 경우의 탈진 성능을 비교하였다. 각 Case별로 벤츄리 내부로 유입되는 탈진 공기량을 예측한 결과, case 2의 벤츄리 형상 개조시 case 1 보다 벤츄리로 유입되는 탈진 공기량이 약 20% 증폭되는 것으로 나타났다. 또한 필터백 표면에서의 탈진 기류 전달 분포를 예측한 결과, 모든 case가 필터백의 국한된 영역으로 탈진 기류가 집중됨을 알 수 있었다. 또한, case 2의 경우가 case 1보다 오히려 탈진 기류의 전달 수준이 불량함을 알 수 있다. 이는 case 2의 경우 벤츄리 입구에 기류 유도용 구조물을 설치한 것이 탈진 공기량을 증폭시키는데에는 도움이 되나, 오히려 벤츄리 내부로 유입된 탈진 기류의 직진성을 보완하여 필터백 내부에서 탈진 기류의 확장을 방해하기 때문인 것으로 판단된다.

• 한국지열·수열에너지학회논문집
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• 제12권1호
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• pp.1-6
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• 2016

Characteristics of exhaust from chimney of electricity generator are analyzed based on CFD when Waveguide-Below-Cutoff (WBC) array is installed in order to achieve the certain level of electromagnetic pulse (EMP) shielding. The main purpose is prediction of average and maximum velocity of exhaust. The results reveal that: 1) When the specification of waveguide is given as 80-diameter, 400-length, and the gap of 20 mm, the shielding effectiveness (SE) is 140dB. The average and maximum velocity of exhaust in the chimney with WBC Array can be represented as exponential functions. 2) As the number of WBC increases, the velocity in the chimney dwindles. 3) Under the situation that WBC with 80 mm diameter is located at intervals of 20 mm, the average velocity can be approximated by $25.5344{\times}e^{(-0.0098{\times}N_{WBC})}$ with input velocity of 15 m/s. In addition, the determination coefficient is 0.915, which is sufficiently high.

• E2M - 전기 전자와 첨단 소재
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• 제10권5호
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• pp.434-439
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• 1997

It this paper, the piezoelectric and electro-induced strain properties of (P $b_{1-}$2x/3/B $i_{x}$ )[N $i_{1}$3/N $b_{2}$3/)$_{0.4}$( $Ti_{0.6}$Z $r_{0.4}$)$_{0.6}$] $O_3$ceramics (x=0, 0.005, 0.02) were investigated with the substitution of B $i^{3+}$, and the feasibility of the application for bimorph actuator was evaluated by measuring the dynamic properties of the piezoelectric bimorph fabricated with above ceramics. Dielectric constant was enhanced with the increase of B $i^{3+}$ substitution, and appeared the maximum value of 5032 at x=0.01 composition. Increasing the substitution of B $i^{3+}$, the electromechanical coefficient( $k_{p}$ , $k_{31}$ ) was increased up to the substitution of 0.5 mol% B $i^{3+}$, showed the value of 0.656, 0.439, respectively. The piezoelectric constant( $d_{33}$ $d_{31}$ ) had the highest value of 344, 825 with the substitution of 0.5 mol% B $i^{3+}$. The strain, generated by 60 Hz AC electric field, had the largest value of 1200($\times$10$^{-6}$ $\Delta$1/1) in the composition with the substitution of 0.5 mol% B $i^{3+}$. The dynamic properties of the bimorph actuator, fabricated with the composition substitution of 0.5 mol% B $i^{3+}$, showed the largest value of 325 $\mu$m at $\pm$150 V square pulse. square pulse.are pulse..

• 마이크로전자및패키징학회지
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• 제7권2호
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• pp.43-46
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• 2000

Nd:YAG laser of 355 nm wavelength, which amounts to 3.5 eV, produced by a harmonic generator was used to create Ag metallic particles as seeds for nucleation in photosensitive glass containing $Ag^+$ and $Ce^{3+}$ . The pulse widths and frequency of the laser were 8ns and 10 Hz, respectively. For crystalline growth, heat-treatment following laser irradiation was carried out at $570^{\circ}C$ for 1h. Then, the $LiAlSi_3O^8$ crystal phase appeared in the laser irradiated lithium aluminum silicate glass. We present the effect of laser-induced nucleation compared with spontaneous nucleation by heat treatment fur crystallization in the glass.

• Advances in concrete construction
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• 제6권4호
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• pp.407-422
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• 2018

The study evaluates properties of brick having coal ash and explores the possibility of utilization of coal bottom ash and coal fly ash as an alternative raw material in the production of coal ash bricks. Lower cement content was used in the investigations to attain appropriate strength and prohibit high carbon content that is cause of environmental pollution. The samples use up to 7% of cement whereas sand was replaced with bottom ash. Bricks were tested for compressive strength, modulus of rupture, ultrasonic pulse velocity (UPV), water absorption and durability. The results showed mix proportions of bottom ash, fly ash and cement as 1:1:0.15 i.e., M-15 achieved optimum values. The coal ash bricks were well bonded with mortar and could be feasible alternative to conventional bricks thus can contribute towards sustainable development.

• The Journal of the Acoustical Society of Korea
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• 제25권1E호
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• pp.14-19
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• 2006

Ultrasonic absorption and velocity spectra in bovine serum albumin (BSA) aqueous solutions have been measured at $20^{\circ}C$ over the frequency range 0.2-3 MHz in the pH range 1.5-13.2. The high-Q ultrasonic resonator and pulse-echo overlap methods were used. At acid pH's, excess absorption over that of pH 7 was explained by double relaxation. The pH dependences of the relaxation frequency and maximum absorption per wavelength, showed that the relaxation at about 200 kHz was related to the expansion of molecules and that about 3 MHz resulted from the proton transfer reaction of carboxyl group. At alkaline pH's, the excess absorption was explained by double relaxation. The relaxation at about 300 kHz was associated with a helix-coil transition, and that about 3 MHz was attributed to the proton transfer reaction of phenolic group. The rate constants and volume changes associated with these processes were estimated.

• Journal of Power Electronics
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• 제10권1호
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• pp.65-71
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• 2010

This paper presents the design and implementation of voltage source inverter type SVPWM based speed control of an induction motor using a fuzzy PI controller. This scheme enables us to adjust the speed of the motor by controlling the frequency and amplitude of the stator voltage; the ratio of the stator voltage to the frequency should be kept constant. A model of the fuzzy control system is implemented in real time with a Xilinx FPGA XC3S 400E. It is introduced to maintain a constant speed to when the load varies.