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Changes in Soil Properties Related to Soil Function due to Chemical Spills with Strong Acid and Base (강산 및 강염기 토양 유출에 따른 토양의 생태기능 관련 토양특성 변화)

  • Jeon, Inhyeong;Jung, Jae-Woong;Nam, Kyoungphile
    • Ecology and Resilient Infrastructure
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    • v.4 no.4
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    • pp.193-199
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    • 2017
  • In this study, changes of soil properties including soil texture, specific surface area, organic matter content, pH, cation exchange capacity and exchangeable cations content were investigated in response to strong acid or base accident. The properties changed significantly when the soil reacted with 10 M HCl or 1 M NaOH (i.e., when one gram of soil received 50 and 5 mmol of HCl or NaOH), respectively. When the soil reacted with 10 M HCl or 1 M NaOH solution, soil texture changed from sandy loam to loamy sand and specific surface areas decreased from $5.84m^2/g$ to 4.85 and $1.92m^2/g$, respectively. The soil organic matter content was reduced from 3.23% to 0.96 and 0.44%, and the soil pH changed from 5.05 to 2.35 and 10.65, respectively. The cation exchange capacity decreased from 10.27 cmol/kg to 4.52 and 5.60 cmol/kg, respectively. Especially, high concentrations of $Al^{3+}$ or $Na^+$ were observed in acidic or basic spills, respectively, which is likely to cause toxicity to terrestrial organisms. The results suggest that restoration of soil properties, as well as soil remediation, needs to be carried out to maintain the soil function in chemical spill sites.

Vegetation Characteristics of Coastal Sand Dune in the East Coast (동해안 해안사구의 식생특성)

  • Han, Young-Hoon;Lee, Yong-Ho;Kim, Jong-Bong;Cho, Kwang-Jin
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.16 no.1
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    • pp.55-69
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    • 2013
  • The phytosocialogical study on the coastal sand dune vegetation of the East Coast was carried out. 180 phytosociological relev$\acute{e}$s of 62 sites in the East Coast were used in this study. In addition, already published syntaxa and the phytosociological hierarchy in Korea and Japan were used and comparative analyses of syntaxonomy, synecology, syngeography, and syndynamics were performed in the study. In this study, the flora was investigated 30 families, 66 genera, 77 taxa and 3 vegetation types were identified : the coastal drift-line annual communities (Calystegio soldanellae-Salsoletum komarovii), the dune glasslands communities (Elymo-Caricetum kobomugi, Carex kobomugi typical community, Elymus mollis community, Calystegia soldanella community, Zoysia macrostachya community, Cynodon dactylon community, Carex pumila community), and the dune shrubs communities (Linario-Viticetum rotundifoliae, Vitex rotundifolia community, Rosa rugosa community). The aspect of transition in the coastal sand dune vegetation of the East Coast were identified as follows : (1) reduced constancy degree and cover degree of Glehnia littoralis in each community; (2) lack of Ischaemum anthephoroides in Linario-Viticetum rotundifoliae (3) simplified species composition in Vitex rotundifolia community. Unstable habitat condition by external interference seemed to has caused the reduction of 2 taxa, Glehnia littoralis and Ischaemum anthephoroides, that usually grow in the second dune. In addition, we found changes in the distribution of the dune shrub communities influenced by rising temperature of the East Coast as results of the global warming. The results on the distribution of the dune shrub communities in this study demonstrated that the limit of the Rosa rugosa community made $0^{\circ}$ 44'N to the North and the vegetative limit of the Vitex rotundifolia community made $0^{\circ}$ 28'N to the North, respectively compared with the previously phytosociological studies. This study investigated the coastal sand dune vegetation, syntaxonomy, habitat condition and human disturbunce of the East Coast, and this will provide important information as basic data for the coastal ecosystem.

Circulation Dynamics of Keum River Estuary II. Fluid Dynamic Characteristics (錦江 河口의 海水循環力學 弟2報 流體力學的 諸特性)

  • Chung, Jong Yul;Bhang, In Kweon
    • 한국해양학회지
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    • v.19 no.2
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    • pp.141-152
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    • 1984
  • In order to investigate the circulation dynamics of the Keum River estuary, 300velocity fields obtained at six sites over two tidal cycles by using instantaneous profiling technique were analyzed in detail. In this investigation, the variability of shear velocity, bottom shear stress, drag coefficient, and roughness length scale were confirmed. The measured values of the bottom boundary drag coefficient show wide range of variations, i.e., C$\_$100/=6.78${\times}$10$\^$-5/∼1.15${\times}$10$\^$-1/, and the mean of 300 measurements is 1.6${\times}$10$\^$-2/. The relationship between U* and C$\_$100/ also show the scatter in values. However, overall mean values over two tidal cycles at 6 stations show that if U* 1cm/s, C$\_$100/ is unpredictable, if U* 1cm/s, C$\_$100/ increase with U*. The values of Re$\_$100/ and C$\_$100/ have scatter. But the overall mean values over two tidal cycles show that if Re$\_$100/ 3.6${\times}$10$\^$5/, C$\_$100/ is unpredictable, if Re$\_$100/ 3.6${\times}$10$\^$5/, C$\_$100/=1.4${\times}$10$\^$-2/. Finally the flow regime of the Keum River estuary was classified as "subcritical fully turbulent" flow.

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Efficacy of 1:1000 Diluted Heparin versus 0.9% Normal Saline for Maintenance of Intermittent Intravenous Locks (희석된 헤파린과 생리식염수가 간헐적 말초정맥장치의 폐색, 유지기간 및 정맥염 발생에 미치는 영향)

  • Park Mi-Mi;Kim Chang-Hee;Cho Eun-Suk;Lee Mi-Jung;Kim Hae-Suk
    • Journal of Korean Academy of Fundamentals of Nursing
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    • v.7 no.2
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    • pp.208-221
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    • 2000
  • The objective of this research was to compare the flushing effects using 1:1,000 diluted heparin or 0.9% normal saline in relation to needle gauge and frequency of IV medications. The comparative categories were clotting, duration of patency, and incidence of phlebitis. The design of research was a Nonequivalent Control group, Post test, Nonsynchrorized Design. The independent variable was 0.9% normal saline flushing the IV locks and the dependent variables were clotting, duration of patency, and incidence of phlebitis. Subjects were medical-surgical inpatients over 15 years old and with peripherally placed IVs who were hospitalized in a university medical center. Exclusion criteria included foreigners and those who were rejected for this research. The final sample for data analysis included 295 IV sites in 194 patients; 154 were in the saline group and 141 were in the heparin group. Subjects were assigned to have IV locks is flushed with 0.9% normal saline in the experimental group and to have IV lock flushed with 1:1,000 diluted heparin(100 units) in the control group. In order to increase reliability, the nurses who were assigned to the units involved in the study received an explanation on the standard method for locking an IV, recording method for observational data and criteria for the detection of phlebitis. Data were collected for a period of 2 weeks, from March 16, 2000 to March 29, 2000. Total duration of IV was defined the time of IV insertion to the time of discontinuation. Phlebitis was defined as the presence of the following : pain, swelling. erythema at the insertion site. Chi-square was used to determine the association between the degree of clotting, duration of patency, and incidence of phlebitis for the diluted heparin or the normal saline and needle gauge and frequency of IV medications. The results are summarized as follows : (a) There was difference in the degree of clotting between two groups($X^2=5.882$, p=.015). (b) There was no difference in the degree of duration of patency between two groups($X^2=2.439$, p=.295). (c) There was no difference in the incidence of phlebitis between two groups($X^2=0.190$, p=.663). (d) There was difference in the degree of clotting($X^2=6.209$, p=.013) and in the degree of duration of patency($X^2=6.978$, p=.031) according the needle guage between the two groups. (e) There was difference in the incidence of phlebitis($X^2=5.008$, p=.025) according to the frequencies of IV injection between two groups.

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Petrologic and Mineralogic Studies on the Origin of Paleolithic Obsidian Implements from Wolseongdong, Korea (월성동 구석기 유적 출토 흑요석제 석기의 암석 및 광물학적 연구를 통한 원산지 추정)

  • Jang, Yun-Deuk;Park, Tae-Yoon;Lee, Sang-Mok;Kim, Jeong-Jin
    • Journal of the Korean earth science society
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    • v.28 no.6
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    • pp.733-742
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    • 2007
  • Petrological, mineralogical, and geochemical analyses were carried on the paleolithic obsidian implements excavated at Wolseongdong, Daegu, Korea. The obsidians has a homogeneous glassy texture that can be observed in a typical obsidian formed from a rapid cooling of silicic magma. Major element composition of the obsidians represent calc-alkaline series. Comparing those with other obsidians from domestic local excavation sites, Mt. Baekdu, and Kyusu of Japan, the Wolseongdong obsidians show similar element distribution pattern with others in spite of small difference in trace and rare Earth element contents. Sr isotopes of the obsidians considerably differ from those of the obsidians from southern part of the Korean Peninsula or from Mt. Baekdu. K-Ar age is approximately 30 Ma, which is much older than Mt. Baekdu (10 Ma). Therefore, considering the characteristics of obsidians found in the Korean Peninsula including mineralogy, petrology, trace element, and isotopes chronology, the obsidians can be divided into four groups: Mt. Baekdu, southern part of Korea (Kyusu of Japan), middle part of Korea, and Wolseongdong region. These groups suggest a possibility of more than four different origins of the obsidians found in the Korean Peninsular.

The Relationship between Rock Strength Characteristics and Net Penetration Rate of RBM by Pilot Test (시험시공을 통한 암석의 강도특성과 RBM의 순관입률과의 관계)

  • 이석원;조만섭;배규진
    • Journal of the Korean Geotechnical Society
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    • v.19 no.4
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    • pp.201-209
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    • 2003
  • For the purpose of research study, a vertical shaft of 98m in length and 3.05m in diameter was constructed in the layer of conglomerate by using the Raise Boring Machine (RBM). In order to estimate the net penetration rate of the RBM, which can be used in the stage of design, the in-situ test results were analysed and correlated to data from the boring log in situ and laboratory testing. Its average net penetration rate is 2.233mm/rev while its average advance rate is 0.382m/hr, which is lower than that of TBM(Tunnel Boving Machine). It turns out that the net penetration rate increases with the increase of strength characteristics in rock mass (e.g., uniaxial compression strength, tensile strength, etc.). Similarly, the net penetration rate increases linearly with the hardness of rock mass. These results are contrary to the results of the previous construction sites where the TBM was generally used in the layer of hard rock. However, the trend obtained in this study is in accordance with the findings of Barton suggesting the relationship between Q$_TBM$ and penetration rate in the layer of soft rock. Thus, the trend is valid in soft and/or weathered rocks.

Studies on Rehabilitation Progress of Vegetation on Landslide Scars - In Cases of Yongin-gun·Hwaseong-gun at Areas - (산사태지(山沙汰地)의 식생(植生) 회복과정(回復過程)에 관(關)한 기초적(基礎的) 연구(硏究) - 용인(龍仁)·화성군지역(華城郡地域)을 대상(對象)으로 -)

  • Woo, Bo-Myeong;Jeon, Gi-Seong;Choi, Hyeong-Tae;Jeong, Do-Hyun
    • Journal of Korean Society of Forest Science
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    • v.84 no.1
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    • pp.31-40
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    • 1995
  • The purpose of this study was to analyze the process of natural plant establishment and revegetation on the slopes of landslide scars, both untreated(l4 plots) and treated plots (14 plots) with rehabilitation measures in 1993 and 1994 at Yongin Hwaseong-gun region. While total of 61 species were identified at surveyed sites. in the region, the pioneer species on landslide scars were Lespedeza cyrtobotrya, Arundinella hirta, Artemisia princeps, Pteridium acquilinum, Erigeron canadensis. Rubus crataegifolius, Stephanandra incisa etc. The species diversity (H') and evenness(E') of the untreated scars were greater than those of the treated scars. Similarity indices in the untreated scars were higher than those in the treated scars, and succession indices showed similar value in both areas. As a conclusion, this study shows that the untreated scars were more influenced by the around-vegetation, and the native vegetations(plants) like Lespedeza cyrtobotrya, Arundinella hirta. Miscanthus sinensis, Artemisia princeps, Pteridium acquilinum, Erigeron canadensis. Rubus crataegifolius, Stephanandra incisa ete. could be more effectively used as plant vegetation for rehabilitation of landslide scars.

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Kinetics and Mechanism of the Oxidation of Sulfur Dioxide on Nickel Oxide-${\alpha}$-Ferric Oxide System (산화니켈-${\alpha}$ 형 산화철 상에서 이산화황의 산화 반응메카니즘)

  • Kyu Yong Lee;Yong Rok Kim;Sung Han Lee
    • Journal of the Korean Chemical Society
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    • v.27 no.3
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    • pp.183-188
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    • 1983
  • The catalytic oxidation of $SO_2$ has been investigated in the presence of vacuum-activated 10 mol % Ni-doped ${\alpha}-Fe_2O_3$ under various partial pressures of $SO_2\;and\;O_2$ at temperatures from 320 to $440{\circ}C$. Over the temperature range $320{\sim}440{\circ}C$, the activation energy is 13.8 $kcal{\cdot}mol^{-1}$. The oxidation rates have been correlated with 1.5 order kinetics; first order with respect to $SO_2$ and 0.5 order with respect to $O_2$. From the kinetic data and conductivity measurements, the adsorption, oxidation mechanism of $SO_2$ and the defect structure of vacuum-activated 10 mol % Ni-doped {\alpha}-Fe_2O_3$ are suggested. $O_2\;and\;SO_2$ appear to be adsorbed essentially as ionic species. Two surface sites, probably an $O^{2-}$ lattice and an oxygen vacancy which is induced by Ni-doping, might be required to adsorb $SO_2\;and\;O_2$. The conductivity measurements and kinetic data indicate that the adsorption process of $SO_2\;{(SO_2+O^{2-}}_{(latt)}{\rightleftharpoons}{{SO_3}^-}_{(ads)}+e')$ is the rate-determining step.

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Oxygen Sites in Quaternary Ca-Na Aluminosilicate Classes : O-17 Solid-State NMR Study (사성분계 비정질 Ca-Na 알루미노규산염의 산소주변의 원자구조 : O-17 고상핵자기 공명분광학분석)

  • Sung, So-Young;Lee, Sung-Keun
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.4 s.50
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    • pp.347-353
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    • 2006
  • The atomic-nano scale structures of multi-component aluminosilicate glasses have not been well understood in spite of its implications fur dynamics and generation of magma in the natural system due to lack of suitable spectroscopic and scattering experiments. Here, we report O-17 MAS and isotropic projection of 3QMAS NMR spectra for quaternary Na-Ca silicate glasses $[(CaO)_x(Na_2O)_{1-x}]\;(A1_2O_3)_{0.5}(SiO_2)_6,\;CNAS)$ at 14.1 Tesla where atomic configurations around bridging oxygen (Si-O-Si, Si-O-Al) and non bridging oxygen (Na-O-Si, Ca-O-Si, (Na, Ca)-O-Si) are partially resolved. With increasing Na content, the fraction of Na-O-Si increases while those for bridging oxygens remain constant. The Na/Ca ratio apparently affects the peak widths of bridging oxygen peaks (e.g., Si-O-Si)) and thus the topological entropy as well as chemical shifts of the bridging oxygen peaks, implying that both BOs and NBOs are strongly interacting with network modifying cations The effect of cation field strength on the degree of Al-avoidance was also discussed.

Archaeomagnetic Secular Variation of the Neolithic Age in Korea: Focusing on the Mid-Western Region Sites (한반도 신석기시대의 고고지자기 변동: 중서부지역 유적을 중심으로)

  • Sung, Hyong Mi
    • Journal of Conservation Science
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    • v.29 no.3
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    • pp.223-229
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    • 2013
  • It is not known in details for the A.D. period as the archaeomagnetic dating method to be fully facilitated in Korea but it has prepared for the revised shape of standard curve to trace the geomagnetic field variation, and there were cases to increase the survey on relics on the B.C. period to find out for the detailed archaeomagnetic field variation on the Bronze Age to the Early Iron Age. Furthermore, the survey cases on the relics on the Neolithic Age began to emerge a little by little archaeomagnetic field variation of the Neolithic Age through 34 pieces of the archaeomagnetic measurement data as making active advancement around mid-western region. Data is insufficient yet that it is difficult to find out the detailed trend of modification but it is estimated for approximate appearance. The archaeomagnetic field variation of the Neolithic Age made changes without breaking away from the scope of changes in the A.D. period as in the same way with the Bronze Age, and comparing to the variation of archaeomagnetic field for the Bronze Age, the magnetic inclination shifted within the scope of having almost no difference, but the declination is shown to skewed toward the east in its overall appearance. In addition, the comparison was made with the data of the Jomon Age in Japan and the archaeomagnetic measurement data of Korea has a little bit more depth for while the declination is skewed toward the east for 10 degree or more compared to those of Japan. However, in the part where the data is concentrated most intensely, the data for both countries has significant part to overlap to each other that the archaeomagnetic field variation of the Neolithic Age of Korea showed overall similar variation with certain partial changes when compared to those of Japan.