• Title/Summary/Keyword: Dye-Function

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Adsorption Thermodynamics, Kinetics and Isosteric Heat of Adsorption of Rhodamin-B onto Granular Activated Carbon (입상 활성탄에 의한 Rhodamin-B의 흡착 열역학, 동력학 및 등량 흡착열에 관한 연구)

  • Lee, Jong Jib
    • Applied Chemistry for Engineering
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    • v.27 no.2
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    • pp.199-204
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    • 2016
  • The adsorption of Rhodamine-B dye using granular activated carbon from aqueous solution was investigated. Adsorption experiments were carried out as a function of the adsorbent dose, pH initial concentration, contact time and temperature. The equilibrium adsorption data showed a good fit to Langmuir isotherm model. Based on the estimated Langmuir separation factor ($R_L$ = 0.0164~0.0314), our adsorption process could be employed as an effective treatment method. The kinetics of adsorption followed the pseudo first order model. Also, the negative values of Gibbs free energy (-4.51~-13.44 kJ/mol) and positive enthalpy (128.97 kJ/mol) indicated that the adsorption was spontaneous and endothermic process. The isosteric heat of adsorption increased with increase in the surface loading indicating lateral interactions between the adsorbed dye molecules.

Effects of Elastic Taping and Non-elastic Taping on Static Balance Control Ability, Dynamic Balance Control Ability, and Navicular bone Drop in Young Adults

  • Lim, Jong-Gun;Lee, Hyun-Woo;Lee, Dongyeop;Hong, Ji-Heon;Yu, Jae-Ho;Kim, Jin-Seop;Kim, Seong-Gil
    • Journal of the Korean Society of Physical Medicine
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    • v.17 no.2
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    • pp.1-10
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    • 2022
  • PURPOSE: This study examined the effects of the low dye taping technique on the static and dynamic balancing ability and navicular bone drop when the low dye taping technique was divided into elastic and non-elastic taping. METHODS: The subjects of the study were 31 volunteers without musculoskeletal disorders. The length (L) and anterior (A), posteromedial, and posterolateral values of the arch in the NO (normal eyes open), NC (normal eyes closed), PO (pillow with eyes open), and PC (pillow with close eyes closed) states were evaluated when barefoot and when Kinesio tape and non-elastic tape were applied. The measurements were analyzed using repeated ANOVA and an independent t-test. Post hoc tests were performed using a Fisher's LSD. RESULTS: A significant difference was found in the arch L and A values using a foot scanner (p < .05). In addition, there was a significant difference in dynamic balance in the three directions (p < .05), and no difference was found in the case of static balance. As a result, non-elastic tape application helps improve the dynamic balance ability and arch of the foot. CONCLUSION: The non-elastic tape technique is helpful for the foot arch function, and there is no difference in the static balance ability between Kinesio tape and non-elastic tape. Nevertheless, non-elastic tape is more helpful for the dynamic balance ability than Kinesio taping.

Estimation of Electrical Parameters of OD Organic Semiconductor Diode from Measured I-V Characteristics

  • Moiz, Syed Abdul;Ahmed, Mansoor M.;Karimov, Kh. S.
    • ETRI Journal
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    • v.27 no.3
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    • pp.319-325
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    • 2005
  • In this paper the effect of temperature on the electrical properties of organic semiconductor disperse orange dye 25 (OD) have been examined. Thin films of OD have been deposited on $In_{2}O_{3}$ substrates using a centrifugal machine. DC current-voltage (I-V) characteristics of the fabricated devices $(Al/OD/In_{2}O_{3)$ have been evaluated at varying temperatures ranging from 40 to $60^{\circ}C$. A rectification behavior in these devices has been observed such that the rectifying ratio increases as a function of temperature. I-V characteristics observed in $Al/OD/In_{2}O_{3)$ devices have been classified as low temperature $({\leq} 50^{\circ}C)$ and high temperature characteristics (approximately $60^{\circ}C$). Low temperature characteristics have been explained on the basis of the charge transport mechanism associated with free carriers available in OD, whereas high temperature characteristics have been explained on the basis of the trapped space-charge-limited current. Different electrical parameters such as traps factor, free carrier density, trapped carrier density, trap density of states, and effective mobility have been determined from the observed temperature dependent I-V characteristics. It has been shown that the traps factor, effective mobility, and free carrier density increase with increasing values of temperature, whilst no significant change has been observed in the trap density of states.

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Dyeability and Function of Silk Fabrics Using Myrica Rubra rind Extract (소귀나무 수피(양매피) 추출물을 이용한 견직물의 염색성과 기능성)

  • Lee, Jung Eun
    • Fashion & Textile Research Journal
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    • v.20 no.5
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    • pp.608-615
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    • 2018
  • The purpose of this study is to investigate the dyeability and functional properties of dyed fabric with the extract of Myrica rubra rind. For this purpose, the ultraviolet and visible spectra of the bark extracts were investigated. The dyeing temperature, dyeing time, mordant type, mordanting order, mordant concentration and dyeability were investigated. The color fastness based on washing, dry-cleaning, rubbing and light were evaluated by the types of Myrica rubra rind extract used. In addition, the deodorization and antibacterial activity were measured, and the functionality of the silk fabric dyed with the extract of the Myrica rubra rind was evaluated. The result shows that the color strength of the dye was excellent when the Myrica rubra rind was dyed at $80^{\circ}C$ for 80 minutes. The mordant dye color strength was high in the order of Fe mordant> Cu mordant> Al mordant. The dyeability of Al and Cu mordant was high during pre-mordanting compared to Fe mordant, and the dyeability of Fe mordant was high during post-mordanting than Cu and Al mordant. The deodorant property of the dyed fabric stained with the Myrica rubra rind extract was 92.4% and that of antibacterial property was 99.9% for Staphylococcus aureus and Klebsiella pneumoniae bacteria respectively.

A Study on Function of Natural Dyeing with Cotton Fabrics Using Jeju scoria (제주 송이를 이용한 천연염색 면직물의 기능성 연구)

  • Im, Eun-Suk;Lee, Hye-Sun
    • Textile Coloration and Finishing
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    • v.23 no.3
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    • pp.179-186
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    • 2011
  • For the application of Jeju scoria scattered around the island as a natural dye, cotton fabrics were dyed with the dye and their properties were measured including dyeability, colorfastness, antibacterial activity, deodorization efficiency, ultraviolet protection, and far-infrared emission. The dyed cotton fabrics were in yellowish red and optimal dyeing conditions were obtained with a colorant concentration of 25%(o.w.b) at a temperature of $80^{\circ}C$ for the dyeing time of 120 minutes. The ratings of colorfastness to light, rubbing, perspiration, and washing were 8, 5, 5, and 4~5 respectively. After 15 wash cycles, colorfastness remained as much as 4~5 rating. The cotton fabric dyed with Jeju scoria demonstrated excellent antimicrobial activity and deodorization efficiency of 99.9% and 93.9% respectively. Ultraviolet protection factor was 50+. Far-infrared emission rate and far-infrared emission intensity were 90% and 362(W/$m^2{\cdot}{\mu}m$) respectively. The Jeju scoria can be introduced as a new colorant for the natural dyeing of cotton.

Application of the Central Composite Design and Response Surface Methodology to the Treatment of Dye Using Electrochemical Oxidation (전기화학적 산화를 이용한 염료 처리에 중심합성설계와 반응표면분석법의 적용)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Science International
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    • v.18 no.11
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    • pp.1225-1234
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    • 2009
  • The aim of this research was to apply experimental design methodology in the optimization condition of electrochemical oxidation of Rhodamine B(RhB). The reactions of electrochemical oxidation were mathematically described as a function of parameters amounts of current, NaCl dosage, pH and time being modeled by the use of the central composite design, which was used for fitting quadratic response surface model. The application of response surface methodology using central composite design(CCD) technique yielded the following regression equation, which is an empirical relationship between the removal efficiency of RhB and test variable in actual variables: RhB removal (%) = 3.977 + 23.279$\cdot$Current + 49.124$\cdot$NaCI - 5.539$\cdot$pH - 8.863$\cdot$time - 22.710$\cdot$Current$\cdot$NaCl + 5.409$\cdot$Current$\cdot$time + 2.390$\cdot$NaCl$\cdot$time + 1.061$\cdot$pH$\cdot$time - $0.570{\cdot}time^2$. The model predicted also agree with the experimentally observed result($R^2$ = 91.9%).

Structural Changes and Histochemical Study of Endosperm on Panax ginseng C.A. Meyer during Embryo Development (인삼(Panax ginseng C.A. Meyer) 종자의 배발달에 따른 배유의 구조변화 및 조직화학적 연구)

  • 유성철;김유갑
    • Journal of Ginseng Research
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    • v.16 no.1
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    • pp.37-43
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    • 1992
  • Structural changes of the endosperm of Panax ginseng C.A. Meyer from fertilization to germination were investigated by light microscope. The endosperm of the ginseng seed is cellular type. Since endosperm cells adjacent embryo continuously breakdown and disappear with the elongation of embryo, the real of endosperm is gradually decreased. As the anatropous ovules of immature seed with green seed coat developes more and more, ovary cells adjacent ovary cavity become abundant by the periclinal division, their size is decreased, hypotrophy of cell wall discern, and they are gradually differentiated in seed coat. Though embryo responds strongly to basic dye at the stage of completion of endosperm formation, tissue of endosperm responds to acidic dye positively Cell wall of embryo and endosperm are composed of primary cell wall not lignified. Endosperm cells adjacent embryo begin to breakdown in the endosperm tissue of indehiscent seed before the beginning of the after-ripening. Dehiscent seed of which seed coat is opened through after-ripening represent the form as a seedling in the result of embryo developments with the formation of organs; radicle, cotyledon, plumule. Umbilifom layer represents strong positive response to the toluidine blue and the basic function. Umbiliform layer that endosperm cells breakdown and disappear is observed clearly at the periphery of the embryo cotylemon, while slightly at the periphery of the radicle.

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Photo Catalytic Activity of CNT-TiO2 Nano Composite in Degrading Anionic and Cationic Dyes

  • Kim, Sang-Jin;Im, Ji-Sun;Kang, Phil-Hyun;Kim, Tae-Jin;Lee, Young-Seak
    • Carbon letters
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    • v.9 no.4
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    • pp.294-297
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    • 2008
  • A CNT-$TiO_2$ nano composite was prepared from titanium chloride ($TiCl_4$) via sol-gel process using multi walled carbon nano tube (MWCNT) followed by calcination at $450^{\circ}C$. Spectral analysis revealed that the formed $TiO_2$ resided on the carbon in anatase form. The effect of adsorption was investigated using aqueous solution of methylene blue and procion blue dye. The photochemical reaction of CNT-$TiO_2$ composite in aqueous suspensions was studied under UV illumination in batch process. The reaction was investigated by monitoring the discoloration of the dyes employing UV-Visible spectro-photometeric technique as a function of irradiation time. The catalyst composites were found to be efficient for the photodegradation of the dye.

A Diagnostic Model for Dye Plume Meandering in Oceanic Waters (해양에서의 염료 플럼의 사행에 대한 모델)

  • Ro, Young-Jae
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.2 no.4
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    • pp.200-207
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    • 1990
  • This study is concerned with the meandering of plume axis in oceanic waters. The process is understood that it is a consequence of the differential contribution by the multiple harmonics of local velocity field to variances of center of mass of crossplume as a function of distance from the source point. A diagnostic model is proposed which is aimed to delineate the eddying motions and furthermore the amplified meandering of plumeaxis. From the data base of dye plumes, wave lengths of meandering eddies are estimated to range between 5.5 to 60.3 (m) in coastal surface waters. A numerical simulation is conducted to predict the concentration field of meandering plume.

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Studies on the interaction of Azo dyes with cationic surfactant(1)

  • Cho, Yung-Mee;Lee, Wang-Kyu;Kim, Bak-Kwang
    • Archives of Pharmacal Research
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    • v.4 no.2
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    • pp.75-84
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    • 1981
  • As the cetyltrimenthy ammonium bromide (CTAB) concentration increases to $2{\times}10^{-4}$/M the absorption maximum of ethyl orange (EO) makes a blue shift from 475 mm to 395 mm. At higher concentration of CTAB than $2{\times}10^{-4}$ / M the absorption maximum shifts to higher wavelength than 395 nm. A new peak at 395 nm is shown to result from the mixed micelle due to dye stacking interaction rather than from a change in dye geometry. Because Raman spectra of EO on interaction with varying amount of CTAB are similar to that of EO in water. EO retains trans azo type on interaction with CTAB. There is a change of c.m.c.s. of CTAB for the mixed micelle in the presence of salt. The effect of added salt on C. M. C. of CTAB for the mixed micelle is given that the logarithm of the c. m. c. is a linear function of the logarithm of the sum of the c. m. c. and the concentration of added salt.

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