• Korean Chemical Engineering Research
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• v.61 no.4
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• pp.517-522
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• 2023

A chemical/mechanical durability test of polymer membrane evaluation method is used in which air and hydrogen are supplied to the proton exchange membrane fuel cell (PEMFC) and wet/dry is repeated in the open circuit voltage (OCV) state. In this protocol, when wet/dry is repeated, voltage increase/decrease is repeated, resulting in electrode degradation. When the membrane durability is excellent, the number of voltage changes increases and the evaluation is terminated due to electrode degradation, which may cause a problem that the original purpose of membrane durability evaluation cannot be performed. In this study, the same protocol as the department of energy (DOE) was used, but oxygen was used instead of air as the cathode gas, and the wet/dry time and flow rate were also increased to increase the chemical/mechanical degradation rate of the membrane, thereby shortening the durability evaluation time of the membrane to improve these problems. The durability test of the Nafion 211 membrane electrode assembly (MEA) was completed after 2,300 cycles by increasing the acceleration by 2.6 times using oxygen instead of air. This protocol also accelerated degradation of the membrane and accelerated degradation of the electrode catalyst, which also had the advantage of simultaneously evaluating the durability of the membrane and the electrode.

• Korean Chemical Engineering Research
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• v.61 no.1
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• pp.45-51
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• 2023

In order to improve the durability of the PEMFC(Proton Exchange Membrane Fuel Cells) polymer membrane, a radical scavenger and a support are used. In this study, the durability of membranes containing fucoidan extracted from seaweeds and tannic acid serving as a crosslinking agent is evaluated to improve chemical and physical durability. Physical durability is evaluated by measuring tensile strength, and chemical durability is measured by Fenton experiment. Membrane and electrode assembly (MEA) is prepared and mechanical and chemical durability are measured through accelerated durability evaluation in the cell. The tensile strength measurement showed that fucoidan and tannic acid can improve the mechanical durability of the membrane by improving the strain rate and yield strength. It is shown in Fenton experiment that fucoidan acts as a radical scavenger. As a result of the accelerated durability test in the unit cell, fucoidan improved both chemical and mechanical durability, increasing the accelerated durability evaluation time by 38.1% compared to the additive-free membrane. When tannic acid is added, the durability of the polymer membrane is improved by 13.9% by improving the mechanical durability.

• Current Photovoltaic Research
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• v.12 no.1
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• pp.17-23
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• 2024

Photovoltaic (PV) power generation is the world's best and largest renewable energy that generates electricity with infinite sunlight. Solar cell modules are a component of photovoltaic power generation and must have a long-term durability of at least 25 years. The development of processes and equipment that can be recovered through the recycling of metals and valuable metals when the solar module's lifespan is over has been completed to the level of commercialization, but few processes have been developed that require repair due to initial defects. This is mainly due to the economic problems caused by remaking. However, if manufacturing processes such as repairing solar cell modules that have been proven to be early defects are established and the technical review of long-term reliability and durability reaches a certain level, it is considered that it will be a recommended process technology for environmental economics. In this paper, assuming that a defective solar cell module occurs artificially, a manufacturing process for replacement of solar cells was developed, and a technical verification of the manufacturing technology was conducted through long-term durability evaluation in accordance with KS C 8561. Through this, it was determined that remanufacturing technology for solar cell replacement of solar cell modules that occurred in a short period of time after installation was possible, and the research results were announced through a journal to commercialize solar modules using manufacturing technology in the solar market in the future.

• Journal of the Korean Institute of Gas
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• v.21 no.3
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• pp.39-45
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• 2017

The LNG storage tank as core facility of LNG industry is mainly composed of the inner tank of nikel 9% steel and the outer tank of prestressed concrete. To respond proactively increased risk of structure performance deterioration due to fatigue of the inner tank and durability reduction of the outer tank, life evaluation program for LNG storage tank is needed. In this study, life evaluation program for LNG storage tank was developed to assess fatigue of the inner tank and durability(carbonation and chloride attack) of the outer tank. By defining the main three scenarios in the inner tank, the fatigue life analysis is conducted from structural analysis and Miner's damage rule. Carbonation progress of the outer tank is predicted according to thickness of cover concrete by using carbon dioxide contents and data of penetration depth. To consider a variety of input conditions and a reliability in results of chloride attack, the evaluation of choride attack for the outer tank is constructed through Life-365 program of open source.

• Proceedings of the KSR Conference
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• 2003.05a
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• pp.597-603
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• 2003

Air spring system in railway vehicles primarily ensure the air suspension of the vehicle body. The low natural frequency ensures a comfortable ride and an invariably good stiffness. In this paper, the characteristics and durability test was conducted in laboratory by using servo-hydraulic fatigue testing system to reliability evaluation of air spring for electric railway vehicle. The experimental results show that the characteristics and durability of domestic development productions are obtained the good results.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.5
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• pp.66-72
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• 2019

To improve ride quality and running stability of high speed train(HST), it is important that connection between coaches adopts the articulated bogies by using a gangway ring, unlike the conventional independent bogies assembled with car bodies. Although the gangway ring should be ensured absolute safety against passenger movement between coaches during train operation, there is still a lack of quantitative durability criteria of that. Therefore, in order to improve the passenger safety of HST, it is important to study the test requirements on durability evaluation for the ring. In this study, seven mixed loading cases were derived from the triaxial loading(vertical/lateral/longitudinal) modes. The safety factor of each component is at least 2.4 or more from the results of the finite element analysis. In addition, fatigue safety was evaluated through durability analysis from the viewpoint of strain-life design. Durability tests for the gangway ring carried out a total of 10 million cycles in 4 phases load conditions. After the durability test, the defect of each component was investigated using nondestructive testing techniques.

• Korean Chemical Engineering Research
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• v.60 no.1
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• pp.7-11
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• 2022

In the membrane forming process of a proton exchange membrane fuel cell (PEMFC), drying and annealing heat treatment processes are required for performance and durability. In this study, the optimal annealing temperature for improving the durability of the polymer membrane was studied. It was annealed in the temperature range of 125~175 ℃, and thermal stability and hydrogen permeability were measured as basic data of durability at each annealing temperature. The electrochemical durability was analyzed by Fenton reaction and open circuit voltage (OCV) holding. The annealing temperature of 165 ℃ was the optimal temperature in terms of thermal stability and hydrogen permeability. In the Fenton reaction, the fluorine emission rate of the membrane annealed at 165 ℃ was the lowest, and the lifespan of the membrane annealed at 165 ℃ was the longest in the OCV holding experiment, confirming that 165 ℃ was the optimal temperature for the durability of the polymer membrane.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.38 no.12
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• pp.1431-1434
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• 2014

The thermal barrier coating (TBC) applied to a gas turbine can be damaged by repeated thermal fatigue during operation, so an evaluation of its durability is needed. Thermally grown oxide (TGO) is generated inside the TBC in a high-temperature environment. The growth of TGO is known to be the main cause of damage to the TBC. Therefore, the durability of TBC should be evaluated according to the growth of TGO. In this research, Kim et al.'s work on the growth of TGO with aging was used as a basis for finite element analysis. The relationship between stress and aging was derived from the finite element analysis results. The durability of the TBC with aging was evaluated through a comparison between the results of the finite element analysis and a bond strength test.

• Journal of the Korea institute for structural maintenance and inspection
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• v.22 no.5
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• pp.47-54
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• 2018

Concrete undergoes various deterioration on surface. Impregnant with silicate is usually applied to concrete surface and forms insoluble hydrates, which can provide many engineering advantages. In the work, concrete impregnated with colloidal silicate is used for durability enhancement in surface and self-clearing performance is evaluated with photocatalyst-$TiO_2$ spraying. For the work, various tests are performed both for strength evaluation and durability evaluation such as absorption ratio, drying shrinkage, chloride penetration, sulfate resistance, and freezing/ thawing action. Furthermore, removal and self-clearing performance are evaluated with Acetaldehyde decomposition and Methylene blue decolorization. Through silicate impregnation and photocatalyst spraying, the impregnated concrete can have not only durability enhance but also self-clearing performance.

• Korean Chemical Engineering Research
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• v.59 no.1
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• pp.11-15
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• 2021

In this study, we tried to develop a method of accelerated degradation of the electrode by simply using a electronic loader without using a potentiostat to evaluate the durability of the electrode catalyst. To this end, the durability of the electrode was evaluated by repeating the stepwise voltage change using the self-generated voltage by introducing oxygen without introducing nitrogen into the cathode. For accurate electrode durability evaluation, that is, in order not to deteriorate the polymer membrane, the high voltage was lowered to 0.9 V in stepwise voltage change and the relative humidity was 100% to suppress degradation of the polymer membrane due to radicals. After 30,000 cycles (50 hours) of voltage change, the electrode active area decreased by 41.4%. It was confirmed that the electrode was deteriorated, but the polymer membrane was not deteriorated, that there was no increase in hydrogen permeability, no decrease in membrane thickness, and no increase in HFR(High Frequency Resistance).