• 제목/요약/키워드: Double charge injection

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$WO_{3}$$ MoO_{3}$ 이중층을 가진 전기변색 소자에 관한 연구 (Study of electrochromic cells in $WO_{3}$/$MoO_{3}$ double-layer structure)

  • 임석범;임동규;백희원;김영호;조봉희;유인종;변문기
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.515-518
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    • 2000
  • The electrochromic properties of $WO_{3}$/$MoO_{3}$ and $MoO_{3}$/$WO_{3}$ double-layers have been systemically studied. The double-layers were made by a e-beam evaporation method and investigated by studying optical modulation, transmittance, and cyclic voltammetry. The devices exhibit good optical properties with wavelength range of 400 to 1100 nm(visible and infrared) during coloration as a function of lithium ion charge injection. It has shown that the double-layer electrochromic thin films are improved the electrochromic properties, but the electrochemical properties are less stable.

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STIMULATING NEURAL ELECTRODE-A STUDY ON CHARGE INJECTION PROPERTIES OF IRIDIUM OXIDE FILMS

  • Lee, In-Seop;Ray A. Buchanan;Jim M.Williams
    • 한국진공학회지
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    • 제4권S2호
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    • pp.156-162
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    • 1995
  • For a stimulating neural electrode, the charge density should be as large as possible to provide adequate stimulation of the nervous system while allowing for miniaturization of the electrode. Since iridium oxide is able to produce high charge densities while preventing undesirable reactions due to charge storage, it has become a promising material for neural prostheses. Successful production of stable Ir and Ir oxide films on various substrates now limits the use of this material. Ir was deposited on two differently prepared surface of (mirror finish, passivation) surgical Ti-6AI-4V with several methods. Ion beam mixing of sputter deposited Ir films on passivated Ti-6AI-4V produced stable and good adherent Ir films. It was found that the increase in charge density of pure Ir on continuous cyclingis due to the accumulation of the oxide phase ( associated with a large surface area) in which the valence state of iridium changes and the double-layer capacitance increases. This study also showed that the double layer capacitance is equally or even more responsible for the high charge density of anodically formed Ir oxide.

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단일벽 탄소 나노튜브의 엑츄에이터 응용 (Actuaots based on Single Walled Carbon Nanotube)

  • 오영석;조승범;최재붕;김영진;백승현
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2006년도 춘계학술대회논문집
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    • pp.1387-1390
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    • 2006
  • Several actuation mechanism for carton nanotubes has teen reported recently, including actuation by double-layer charge injection and ac voltages applyied to multiple electrodes. Carbon nanotube actuator based on double layer charge injection work well in electrolyte at low voltage. AC dielectrophoresis based on four electrode geometry demonstrated carton nanotubes in solution phase can be oriently manipulated by dielectrophoresis. From this point of view, and in regard to their performance, bucky paper actuator may alternate natural muscle. also, applied AC signal with appropriate magnitude and frequency together with four electrode arrangement has potential to realize nanotube electrokinetics.

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Yellow Light-Emitting Poly(p-phenylenevinylene) Derivative with Balanced Charge Injection Property

  • Kim, Joo-Hyun;Lee, Hoo-Sung
    • Bulletin of the Korean Chemical Society
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    • 제25권5호
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    • pp.652-656
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    • 2004
  • A new luminescent polymer, poly{1,4-phenylene-1,2-ethenediyl-2'-[2"-(4'"-octyloxyphenyl)-(5"-yl)-1",3",4"-oxadiazole]-1,4-phenylene-1,2-ethenediyl-2,5-bis-dodecyloxy-1,4-phenylene-1,2-ethenediyl} (Oxd-PPV), was synthesized by the Heck coupling reaction. Electron withdrawing pendant, conjugated 1,3,4-oxadiazole (Oxd), is on the vinylene unit. The band gap of the polymer figured out from the UV-visible spectrum was 2.23 eV and the polymer film shows bright yellow emission maximum at 552 nm. The electroluminescence (EL) maximum of double layer structured device (ITO/PEDOT:PSS/Oxd-PPV/Al) appeared at 553 nm. Relative PL quantum yield of Oxd-PPV film is 3.6 times higher than that of MEH-PPV film. The HOMO and LUMO energy levels of Oxd-PPV figured out from the cyclic voltammogram and the UV-visible spectrum are -5.32 and -3.09 eV, respectively, so that more balanced hole and electron injection efficiency can be expected compared to MEH-PPV. A double layer EL of Oxd-PPV has an maximum efficiency of 0.15 cd/A and maximum brightness of 464 cd/$m^2$.

공간전하중첩 모델에 의한 스위칭과도장태 특성해석 (Analysis of Switching Transient State characteristis Based on Space charge Overlapping Model)

  • 정홍배;박창엽
    • 대한전자공학회논문지
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    • 제18권2호
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    • pp.27-35
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    • 1981
  • 본 연구에서는 비정질 갈코게나이트박막의 스위칭과도 특성을 분석하기 위해 공체전하중를 모델에 의한 수식적 이론과 그 이론의 타부성에 따른 실험을 연하였다. 이론과 실험에 대한 분석적인 관찰을 실온에서 비정용 잘코게나이드박막에 전압펄스를 인가할 때 생기는 스위칭과도 특성에 대해 비교하였다. 결과로는 전자스위칭 특성에 대한 단순한 이론적 모델의 형태로 설명할 수 있다. 캐리어의 주입은 스위칭 특성을 유발시키기에 필요하며 주입된 캐리어들은 공간전하제한전류(SCLC)로서 전류 흐름에 기여한다. 그러므로 제안된 전하제어 스위칭 특성은 2중 주입 공간 전하중첩 모델로 해석할 수 있다.

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Size and Crystal Structure Dependence of Photochromism of Nanocrystalline WO3 and MoO3 Prepared by Acid-Precipitation Method

  • Jun Young, Kwak;Young Hee, Jung;Yeong Il, Kim
    • 대한화학회지
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    • 제67권1호
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    • pp.33-41
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    • 2023
  • Nanocrystallne WO3 and MoO3 with several different sizes and crystal structures were prepared by simple acid precipitation and subsequent heat treatment. The photochromic (PC) properties of these samples were comparatively investigated in powder state by monitoring diffuse reflectance spectral changes after bandgap irradiation. The PC effect of hexagonal WO3 and monoclinic WO3 strongly depended upon crystallite size rather than crystal structure. The smaller the crystallite size, the better the PC effect. However, orthorhombic WO·H2O and MoO3 having hexagonal and orthorhombic structures did not follow this trend. One consistent result for all WO3 and MoO3 samples is that the heat treatment in air, which changes crystallinity, whether it changes the crystal structure or only the crystallite size, reduces the PC effect. Since the thermal treatment reduces the surface oxygen defect sites, we believe that the PC effect of WO3 and MoO3 depends critically on the surface oxygen defect sites that serve as deep trap sites for photogenerated electrons and oxygen radical holes. We also found that the proton insertion claimed by double charge injection model is not critical for the PC effect.

직류 전계 인가에 따른 절연유의 전하 축적 및 완화 현상에 관한 연구 (A Study on charge accumulation and relaxation phenomena by D.C energization in insulating oil)

  • 이창완;임헌찬;김용운;신태현;허창수;이덕출
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1996년도 하계학술대회 논문집 C
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    • pp.1633-1635
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    • 1996
  • This phenomena of streaming-electrification is generated between solid and liquid boundary called electric double-layer which is generated by potential difference. A charge separation at interfaces between a moving fluid and a solid boundary can give rise to the generation of substantial electric field and at last these can give rise ta insulating failure. Therefore injection of the adverse-charge in streaming-electrified insulating oil to eliminate the accumulation charge and its related phenomena was investigated.

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Spectroscopic Studies of TP6F PI Switched by Hole-Injection

  • 이경재;임규욱;김동민;이문호;강태희;정석민
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.297-298
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    • 2011
  • Metal/poly (4,4'-aminotriphen-ylene hexafluoroisopropylidenediphthalimide) (TP6F PI)/metal structure exhibited an electrically volatile phase transition with high (OFF) or low (ON) resistive states when voltage between electrodes swept. Here, we demonstrate a noble set-up in which holes are injected by photoelectron emission process during the voltage sweep instead of direct charge carrier injection via metal electrode, which enables direct investigation into changed electronic structures of TP6F PI both in ON and OFF states using photoemission spectroscopy methods. In the I-V measurement, TP6F PI shows a non-volatile behavior. In spectroscopic results, this non-volatile behavior is leaded from the structural modification of the O=C double bond in phthalimide of TP6F PI by hole injection.

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정밀한 완전 차동 Sample-and-Hold 회로 (An Accurate Fully Differential Sample-and-Hold Circuit)

  • 기중식;정덕균;김원찬
    • 전자공학회논문지B
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    • 제31B권3호
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    • pp.53-59
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    • 1994
  • A new fully differential sample-and-hold circuit which can effectively compensate the offset voltage of an operational amplifier and the charge injection of a MOS switch is presented. The proposed circuit shows a true sample-and-hold function without a reset period or an input-track period. The prototype fabricated using a 1.2$\mu$m double-polysilicon CMOS process occupies an area of 550$\mu$m$\times$288$\mu$m and the error of the sampled ouput is 0.056% on average for 3V input at DC.

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바이오 센서 적용을 위한 수직형 이중게이트 InGaAs TFET의 게이트 열화 현상 분석 (Constant Voltage Stress (CVS) and Hot Carrier Injection (HCI) Degradations of Vertical Double-date InGaAs TFETs for Bio Sensor Applications)

  • 백지민;김대현
    • 센서학회지
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    • 제31권1호
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    • pp.41-44
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    • 2022
  • In this study, we have fabricated and characterized vertical double-gate (DG) InGaAs tunnel field-effect-transistors (TFETs) with Al2O3/HfO2 = 1/5 nm bi-layer gate dielectric by employing a top-down approach. The device exhibited excellent characteristics including a minimum subthreshold swing of 60 mV/decade, a maximum transconductance of 141 µS/㎛, and an on/off current ratio of over 103 at 20℃. Although the TFETs were fabricated using a dry etch-based top-down approach, the values of DIBL and hysteresis were as low as 40 mV/V and below 10 mV, respectively. By evaluating the effects of constant voltage and hot carrier injection stress on the vertical DG InGaAs TFET, we have identified the dominant charge trapping mechanism in TFETs.