• Title/Summary/Keyword: Double charge injection

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Study of electrochromic cells in $WO_{3}$/$MoO_{3}$ double-layer structure ($WO_{3}$$ MoO_{3}$ 이중층을 가진 전기변색 소자에 관한 연구)

  • 임석범;임동규;백희원;김영호;조봉희;유인종;변문기
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.515-518
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    • 2000
  • The electrochromic properties of $WO_{3}$/$MoO_{3}$ and $MoO_{3}$/$WO_{3}$ double-layers have been systemically studied. The double-layers were made by a e-beam evaporation method and investigated by studying optical modulation, transmittance, and cyclic voltammetry. The devices exhibit good optical properties with wavelength range of 400 to 1100 nm(visible and infrared) during coloration as a function of lithium ion charge injection. It has shown that the double-layer electrochromic thin films are improved the electrochromic properties, but the electrochemical properties are less stable.

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STIMULATING NEURAL ELECTRODE-A STUDY ON CHARGE INJECTION PROPERTIES OF IRIDIUM OXIDE FILMS

  • Lee, In-Seop;Ray A. Buchanan;Jim M.Williams
    • Journal of the Korean Vacuum Society
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    • v.4 no.S2
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    • pp.156-162
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    • 1995
  • For a stimulating neural electrode, the charge density should be as large as possible to provide adequate stimulation of the nervous system while allowing for miniaturization of the electrode. Since iridium oxide is able to produce high charge densities while preventing undesirable reactions due to charge storage, it has become a promising material for neural prostheses. Successful production of stable Ir and Ir oxide films on various substrates now limits the use of this material. Ir was deposited on two differently prepared surface of (mirror finish, passivation) surgical Ti-6AI-4V with several methods. Ion beam mixing of sputter deposited Ir films on passivated Ti-6AI-4V produced stable and good adherent Ir films. It was found that the increase in charge density of pure Ir on continuous cyclingis due to the accumulation of the oxide phase ( associated with a large surface area) in which the valence state of iridium changes and the double-layer capacitance increases. This study also showed that the double layer capacitance is equally or even more responsible for the high charge density of anodically formed Ir oxide.

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Actuaots based on Single Walled Carbon Nanotube (단일벽 탄소 나노튜브의 엑츄에이터 응용)

  • Oh, Young-Seok;Cao, Cheng-Fan;Choi, Jae-Boong;Kim, Young-Jin;Baik, Seung-Hyun
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2006.05a
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    • pp.1387-1390
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    • 2006
  • Several actuation mechanism for carton nanotubes has teen reported recently, including actuation by double-layer charge injection and ac voltages applyied to multiple electrodes. Carbon nanotube actuator based on double layer charge injection work well in electrolyte at low voltage. AC dielectrophoresis based on four electrode geometry demonstrated carton nanotubes in solution phase can be oriently manipulated by dielectrophoresis. From this point of view, and in regard to their performance, bucky paper actuator may alternate natural muscle. also, applied AC signal with appropriate magnitude and frequency together with four electrode arrangement has potential to realize nanotube electrokinetics.

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Yellow Light-Emitting Poly(p-phenylenevinylene) Derivative with Balanced Charge Injection Property

  • Kim, Joo-Hyun;Lee, Hoo-Sung
    • Bulletin of the Korean Chemical Society
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    • v.25 no.5
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    • pp.652-656
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    • 2004
  • A new luminescent polymer, poly{1,4-phenylene-1,2-ethenediyl-2'-[2"-(4'"-octyloxyphenyl)-(5"-yl)-1",3",4"-oxadiazole]-1,4-phenylene-1,2-ethenediyl-2,5-bis-dodecyloxy-1,4-phenylene-1,2-ethenediyl} (Oxd-PPV), was synthesized by the Heck coupling reaction. Electron withdrawing pendant, conjugated 1,3,4-oxadiazole (Oxd), is on the vinylene unit. The band gap of the polymer figured out from the UV-visible spectrum was 2.23 eV and the polymer film shows bright yellow emission maximum at 552 nm. The electroluminescence (EL) maximum of double layer structured device (ITO/PEDOT:PSS/Oxd-PPV/Al) appeared at 553 nm. Relative PL quantum yield of Oxd-PPV film is 3.6 times higher than that of MEH-PPV film. The HOMO and LUMO energy levels of Oxd-PPV figured out from the cyclic voltammogram and the UV-visible spectrum are -5.32 and -3.09 eV, respectively, so that more balanced hole and electron injection efficiency can be expected compared to MEH-PPV. A double layer EL of Oxd-PPV has an maximum efficiency of 0.15 cd/A and maximum brightness of 464 cd/$m^2$.

Analysis of Switching Transient State characteristis Based on Space charge Overlapping Model (공간전하중첩 모델에 의한 스위칭과도장태 특성해석)

  • 정홍배;박창엽
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.18 no.2
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    • pp.27-35
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    • 1981
  • In this study, a numerical theory based on space charge overlapping model and experiments on the propriety of its theory were carried out to analyze the switching transient characteristic in amorphous coalcogenide thin film. Theoretical and experimental as well as analytical investigations were carried out on the switching behaviour in a transient state arising from a voltage pulse applied to amorphous chalcogenide thin films at room temperature. The results can be explained in terms ot a simple theoretical model of the electronic characteristics of switching. The injection of carriers are necessary to initiate the switching action and injected carriers contribute to the current flow as a space-charge limited current(SCLC) The proposed charge controlled switching characteristics can be explained by double injection space charge overlapping model.

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Size and Crystal Structure Dependence of Photochromism of Nanocrystalline WO3 and MoO3 Prepared by Acid-Precipitation Method

  • Jun Young, Kwak;Young Hee, Jung;Yeong Il, Kim
    • Journal of the Korean Chemical Society
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    • v.67 no.1
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    • pp.33-41
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    • 2023
  • Nanocrystallne WO3 and MoO3 with several different sizes and crystal structures were prepared by simple acid precipitation and subsequent heat treatment. The photochromic (PC) properties of these samples were comparatively investigated in powder state by monitoring diffuse reflectance spectral changes after bandgap irradiation. The PC effect of hexagonal WO3 and monoclinic WO3 strongly depended upon crystallite size rather than crystal structure. The smaller the crystallite size, the better the PC effect. However, orthorhombic WO·H2O and MoO3 having hexagonal and orthorhombic structures did not follow this trend. One consistent result for all WO3 and MoO3 samples is that the heat treatment in air, which changes crystallinity, whether it changes the crystal structure or only the crystallite size, reduces the PC effect. Since the thermal treatment reduces the surface oxygen defect sites, we believe that the PC effect of WO3 and MoO3 depends critically on the surface oxygen defect sites that serve as deep trap sites for photogenerated electrons and oxygen radical holes. We also found that the proton insertion claimed by double charge injection model is not critical for the PC effect.

A Study on charge accumulation and relaxation phenomena by D.C energization in insulating oil (직류 전계 인가에 따른 절연유의 전하 축적 및 완화 현상에 관한 연구)

  • Kim, C.W.;Lim, H.C.;Kim, Y.W.;Shin, T.H.;Huh, C.S.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1633-1635
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    • 1996
  • This phenomena of streaming-electrification is generated between solid and liquid boundary called electric double-layer which is generated by potential difference. A charge separation at interfaces between a moving fluid and a solid boundary can give rise to the generation of substantial electric field and at last these can give rise ta insulating failure. Therefore injection of the adverse-charge in streaming-electrified insulating oil to eliminate the accumulation charge and its related phenomena was investigated.

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Spectroscopic Studies of TP6F PI Switched by Hole-Injection

  • Lee, Gyeong-Jae;Im, Gyu-Uk;Kim, Dong-Min;Lee, Mun-Ho;Gang, Tae-Hui;Jeong, Seok-Min
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.297-298
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    • 2011
  • Metal/poly (4,4'-aminotriphen-ylene hexafluoroisopropylidenediphthalimide) (TP6F PI)/metal structure exhibited an electrically volatile phase transition with high (OFF) or low (ON) resistive states when voltage between electrodes swept. Here, we demonstrate a noble set-up in which holes are injected by photoelectron emission process during the voltage sweep instead of direct charge carrier injection via metal electrode, which enables direct investigation into changed electronic structures of TP6F PI both in ON and OFF states using photoemission spectroscopy methods. In the I-V measurement, TP6F PI shows a non-volatile behavior. In spectroscopic results, this non-volatile behavior is leaded from the structural modification of the O=C double bond in phthalimide of TP6F PI by hole injection.

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An Accurate Fully Differential Sample-and-Hold Circuit (정밀한 완전 차동 Sample-and-Hold 회로)

  • 기중식;정덕균;김원찬
    • Journal of the Korean Institute of Telematics and Electronics B
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    • v.31B no.3
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    • pp.53-59
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    • 1994
  • A new fully differential sample-and-hold circuit which can effectively compensate the offset voltage of an operational amplifier and the charge injection of a MOS switch is presented. The proposed circuit shows a true sample-and-hold function without a reset period or an input-track period. The prototype fabricated using a 1.2$\mu$m double-polysilicon CMOS process occupies an area of 550$\mu$m$\times$288$\mu$m and the error of the sampled ouput is 0.056% on average for 3V input at DC.

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Constant Voltage Stress (CVS) and Hot Carrier Injection (HCI) Degradations of Vertical Double-date InGaAs TFETs for Bio Sensor Applications (바이오 센서 적용을 위한 수직형 이중게이트 InGaAs TFET의 게이트 열화 현상 분석)

  • Baek, Ji-Min;Kim, Dae-Hyun
    • Journal of Sensor Science and Technology
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    • v.31 no.1
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    • pp.41-44
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    • 2022
  • In this study, we have fabricated and characterized vertical double-gate (DG) InGaAs tunnel field-effect-transistors (TFETs) with Al2O3/HfO2 = 1/5 nm bi-layer gate dielectric by employing a top-down approach. The device exhibited excellent characteristics including a minimum subthreshold swing of 60 mV/decade, a maximum transconductance of 141 µS/㎛, and an on/off current ratio of over 103 at 20℃. Although the TFETs were fabricated using a dry etch-based top-down approach, the values of DIBL and hysteresis were as low as 40 mV/V and below 10 mV, respectively. By evaluating the effects of constant voltage and hot carrier injection stress on the vertical DG InGaAs TFET, we have identified the dominant charge trapping mechanism in TFETs.