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하수관거내 오염물질 성상변화 특성 (Characteristics of Transformation Process of Wastewater in Sewer)

  • 이두진;김문일
    • 대한환경공학회지
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    • 제27권9호
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    • pp.911-916
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    • 2005
  • 본 연구에서는 하수가 관거를 유하하면서 물리, 화학, 생물학적 반응을 통하여 오염물질이 제거되는 특성을 평가하기 위하여 실제 관거를 대상으로 상, 하류수질변화를 분석하고 관거 퇴적물의 입경변화와 오염물함유량을 평가하였다. 상류와 하류가 2.4 km 떨어진 두 지점에서 24시간 연속 채취된 시료에 대한 DOC 분석결과 상하류의 농도차이는 $-5.8{\sim}18.6\;mg/L$의 범위를 보였다. 상류측 평균 DOC농도를 기준으로 8.4%가 감소하였으며, 관거길이당 감소율은 2.3 mg/L/km, 평균체류시간에 의한 감소율은 0.093 mg/L/min으로 나타났다. SS의 경우 상류와 하류간의 수질차는 $-10.5{\sim}34.6\;mg/L$, 평균 SS 농도차는 13.3 mg/L, 상류수질을 기준으로 10.4%정도 감소하였으며 관거길이당 감소율은 5.5 mg/L/km, 평균체류시간에 의한 감소율은 0.22 mg/L/min으로 DOC에 비하여 약 2배 정도 높은 감소율을 나타내었다. 침입수/유입수를 고려하여 DOC, SS의 누적오염부하를 비교한 결과, DOC의 경우 일누적오염부하를 기준으로 상류 1,230 kg/d, 하류 1,167 kg/d으로 5.2%가 감소하였고, SS의 경우 상류 2,371kg/d, 하류는 2,186 kg/d로 7.8% 감소하였다. 이러한 결과는 하수를 처리장까지 수송하튼 관거시스템내에서 오염부하의 일부가 제거되고 있음을 보여주는 것이며, 하수처리장의 설계 및 운영시 관거를 통한 감소영향을 고려하는 것이 필요함을 알 수 있다.

북한강수계 호수의 POC와 DOC 분포와 조류밀도의 관계 (The Distribution of POC and DOC in Four Reservoirs on the North Han River and the Relationship with Algal Density)

  • 김기용;김범철;엄재성;최영순;장창원;박혜경
    • 한국물환경학회지
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    • 제25권6호
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    • pp.840-848
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    • 2009
  • Spatial and temporal distributions of POC and DOC were surveyed in the North Han River system, Korea The proportion of algal cells was calculated in four reservoirs (Lakes Soyang, Paro, Chunchon, and Uiam). Monthly average DOC concentrations ranged from 1.5 to 2.3 mg C/L, and POC showed larger variation than DOC (range 0.3 to 1.9 mg C/L). The average proportion of POC in TOC was higher than those of typical natural lakes. Due to the influence of the Asian summer monsoon, the seasonal variation in POC concentration depended on heavy rain events occurring during the summer. POC concentrations increased during the summer monsoon season due to turbid storm runoff laden with debris, while DOC concentrations did not increase. The highest POC concentrations were observed in Lake Soyang in 2006 when a severe rain event occurred. In two deep stratified reservoirs (Lake Soyang and Paro) storm runoffs formed an intermediate turbidity layer with high POC and chlorophyll concentrations which is thought to originate from terrestrial debris and periphyton transported by inflowing streams. The proportion of algal cells in total POC was much lower than for most natural lakes, and it varied with season; low in the monsoon season and high in dry seasons with algal blooms. An analysis of POC concentration and chlorophyll a concentration showed that the ratio of POC/Chl.a varied from 24 to 80.

하수중 용존 유기물의 생분해도 및 분자량 분포에 따른 거동특성에 관한연구 (A Study on the Biodegradability and Characteristics Based on Apparent Molecular Weight Distribution of Dissolved Organic Matter in Sewage)

  • 최정헌;이윤진;명복태;우달식;이운기;남상호
    • 한국환경보건학회지
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    • 제27권2호
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    • pp.92-99
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    • 2001
  • This present study was aimed to investigate the characteristics of dissoloved organic matter (DOC) in sewage. The results are summarized as follows ; The plateaux reached in 3~4 days by the biodegradability test on sewage samples based on DOC. 쏭 rations of BDOC to DOC were 48, 21, 13 and 11% for raw sewage, primary treatment effluent, secondary treatment effluent and final treatment effluent, respectively. As the SUVA values ranged less 3L/m.mg for the effluent of sewage treatment plant, the DOC is composed largely of non-humic materials, hydrophilic, less aromatic as compared to waters with higher SUVA values. Through the biodegradability test, Dissolved organics showed that the quantity of LMW(Low Molecular Weight) less than 1,000 daltons was decreased, HMW(High Molecular Weight) more than 30,000 daltons had a tendency to increase. Large portion of UV$^{254}$ in final treatment effluent was increased of MMW(Medium Molecular Weight). Also, average removal efficiency of DOC was 32% during sewage treatment.

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Comparison of BOD, COD, TOC and DOC as the Indicator of Organic Matter Pollution of Agricultural Surface Water in Gyeongnam Province

  • Lee, Seong-Tae;Lee, Young-Han;Hong, Kwang-Pyo;Lee, Sang-Dae;Kim, Min-Kyeong;Park, Jong-Hwan;Seo, Dong-Cheol
    • 한국토양비료학회지
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    • 제46권5호
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    • pp.327-332
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    • 2013
  • This survey was conducted to obtain basic data about organic matter such as BOD (Biochemical Oxygen Demand), COD (Chemical Oxygen Demand), DOC (Dissolved Organic Carbon) and TOC (Total Organic Carbon) in agricultural water in Gyeongnam province. BOD and COD are currently used for water quality indices, but adoption of TOC is being suggested. The surface water samples were collected at 39 locations in Gyeongnam province in April, July and October. Average concentrations of BOD, COD, DOC and TOC were 1.6, 3.3, 5.3 and $5.7mg\;L^{-1}$, respectively. In July, average concentrations of BOD and COD were 2.4 and $3.9mg\;L^{-1}$, respectively, showing these values were higher than other months. Average concentrations of TOC in April, July and October were 4.8, 7.4 and $4.8mg\;L^{-1}$, respectively. This suggested that the highest value of TOC was in July. Average decomposition efficiencies for BOD-C/TOC and COD-C/TOC were 11.4 and 23.9%, respectively. Correlation coefficient of TOC and DOC was higher by 0.995, whereas that of TOC and COD was lower by 0.763. Especially, TOC and DOC were highly related than others.

집중 강우시 남한강 내 용존 유기물의 성상 변화 (Changes in Dissolved Organic Matter Composition in the Namhan River during a Heavy Rain Event)

  • 오세진;우성호;허진;정명숙;신현상
    • 한국물환경학회지
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    • 제25권5호
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    • pp.697-703
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    • 2009
  • In this study, changes in the composition of dissolved organic carbon (DOC) were investigated using water samples collected at a downstream site of the Namhan River near the Lake Paldang ($N37^{\circ}24^{\prime}05.33^{{\prime}{\prime}}E127^{\circ}32^{\prime}25.01^{{\prime}{\prime}}$) during a heavy rain event from July 23 to July 28, 2008. The DOC concentrations varied from 1.68 to 3.18 mg/L with the maxium value at a peak of the river water level. Each DOC sample was fractionated into three compositions including hydrophilic (Hi), hydrophobic acid (HoA) and hydrophobic neutral (HoN) fractions. The results showed that HoA was most abundant fractions, constituting 47.2~56.5% of DOC. Refractory dissolved organic carbon (R-DOC) contents were also determined by measuring the DOC concentration after 28-day dark incubation of the samples. R-DOC content was in the range from 83 to 99% of DOC and it was significantly correlated with HoA contents (r = 0.91, p<0.005), while it did not exhibit such a good correlation with the fractions of Hi and HoN (p>0.02). Our results suggest that the HoA, which is associated with humic substances, may be a major composition of refractory organic matters in rivers during storm events.

남매지에서 Eubacteria 군집구조의 계절적 변화와 그에 영향을 미치는 환경요인 (Seasonal Variation of Eubacterial Community Structure and Their Structure Affecting Environmental Parameters in Reservoir)

  • 이희순;박정원;김미경;이영옥
    • 미생물학회지
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    • 제38권1호
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    • pp.31-37
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    • 2002
  • 경북 경산시 에 위치한 남매지 에서 세균군집 의 구조를 fluorescent in situ hybridization(FISH) 방법을 이용하여 분석하였고 아울러 세균군집크기에 영향을 주는 환경요인을 측정하여 그 상관성을 파악하고자 하였다. 담수계에 우점하는 것으로 알려진 proteobacteria($\alpha$.$\beta$.$\gamma$-subclasses)와 글Cytophaga-Flavobacterium (CF) group에 속하는 진정세균군의 연중변화를 정점별로 측정하였다. 총세균수에 대한 각 세균군집 비율은 정점간의 큰 차이 없이 $\alpha$-subclass가 4.0~29.2%,$\beta$-subclass가 1.7~25.8%, $\gamma$-subclass가 1.8~12.8%를, 그리고 CF group은 4.9~36.3%의 군집 비율을 나타냈다. 온도,SS, pH, DOC,질산염, 조류 현존량 등 환경요인과 세균군집 간의 상관관계를 분석한 결과, 총세균수는 수온, DOC,55, eubacteria는 DOC, 녹조류 현존량, $\gamma$-subclass 세균군은 DOC, CF group세 균은 녹조류 현존량과 양의 상관성을 나타낸 반면 $\beta$-subclass는 남세균 . 총 조류 현존량과 음의 상관성을 나타냈다.

Effects of Organic Matter Concentration in Soil on Phytoavailability of Cadmium in Medicinal Plants

  • Noh, Yong-dong;Kim, Kwon-Rae;Kim, Won-Il;Jung, Ki-Yuol;Hong, Chang Oh
    • 한국토양비료학회지
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    • 제48권5호
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    • pp.319-325
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    • 2015
  • The safety of plant species used as a source for herbal medicines and dietary supplements has recently been questioned due to poisonings associated with the presence of cadmium (Cd) in these plants. These plants can derive Cd from their presence in the soil. Organic matter (OM) concentrations in soils could affect the availability of Cd for plants. To determine the effect of OM concentration in soil on the concentration of plant available Cd and uptake of this toxic element by medicinal plants, soil and plant samples were collected from 102 fields supporting for 5 species of medicinal plants in 6 province of South Korea. Concentrations of OM and dissolved organic carbon (DOC) in soils affected the phytoavailability of Cd. One M $NH_4OAc$ extractable Cd concentration in soil increased with increasing OM concentrations. There were significantly positive relationships between 1 M $NH_4OAc$ extractable Cd concentration and OM concentration in soil and between 1 M $NH_4OAc$ extractable Cd concentration and DOC concentration. Likewise, OM and DOC concentrations significantly affected Cd concentration in medicinal plant soils. Cadmium concentration in medicinal plants increased with increasing OM concentration in soil [Cd concentration $(mg\;kg^{-1})= 0.179+1.424{\times}10^{-3}$ OM concentrations, $R^2=0.042*$] and with DOC concentration [Cd concentration $(mg\;kg^{-1})= 0.150+5.870{\times}10^{-4}$ DOC concentrations, $R^2=0.124***$]. These results might result from Cd-DOC complex which is easily absorbed Cd form by plant root. Dissolved organic carbon concentration had more positive relationship with Cd concentration in medicinal plants and 1 M $NH_4OAc$ extractable Cd concentration in soils than OM. Cadmium concentration in all 5 species of medicinal plant (Atractylodes macrocephala Koidzumi, Astragalus membranaceus, Codonopsis lanceolata, Platycodon grandiflorum, and Rehmannia glutinosa) significantly increased with increasing DOC concentration in soil. From the above results, formation of Cd-DOC complex caused by OM application might be mainly attributed to increase in Cd concentration in medicinal plants.

CFD에 의한 선박용 DPF/DOC내 배기가스의 유동 균일도 및 특성 연구 (A Study on the Flow Uniformity and Characteristics of Exhaust gas in Diesel Particulate Filter/Diesel Oxidation Catalyst of Ship Diesel Reduction System by Computational Fluid Dynamics)

  • 김윤지;한단비;백영순
    • 청정기술
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    • 제25권2호
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    • pp.153-160
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    • 2019
  • 디젤 선박 운행 횟수의 증가로 인한 대기오염이 심각해짐에 따라 선박의 유해배출가스에 대한 규제가 강화되고 있다. 따라서 선박용 디젤 배기 후처리 장치의 개발이 요구되고 배기 처리 장치는 유동 균일도가 높을수록 처리효율이 증가된다. 본 연구에서는 ANSYS Fluent를 이용하여 기존 저감장치, 저감장치 내부의 Baffle 설치시, 배기가스 유량에 따른 배압과 유동 균일도를 시뮬레이션 하였다. 기존 장치조건에서는 시스템 배압이 38 ~ 40 mbar로 나타났으며, 유동 균일도는 DOC 입구와 출구에서 약 84 ~ 92%로 나타났다. 시스템 내부에 Baffle을 설치한 경우 압력이 상승되고 유속 증가로 인해 유동 균일도가 낮아진다. 배기가스 유량을 $7,548kg\;h^{-1}$에서 $3,772kg\;h^{-1}$로 50% 감소했을 때, 낮은 유속에 의해 DOC 입구와 출구의 유동 균일도는 약 1 ~ 3% 증가했다. DPF의 경우 불균일한 유동이 DOC를 균일하게 거쳐 흐른 후 유입되기 때문에 유동 균일도가 98 ~ 99%로 높게 나타났다.

국내 제작된 대형 디젤산화촉매의 배출가스 성능평가 (Performance Evaluation of Domestic -made DOC for the Heavy-duty Diesel Engine)

  • 정일록;엄명도;김종춘;김태승;류정호;임철수
    • 한국자동차공학회논문집
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    • 제7권7호
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    • pp.15-23
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    • 1999
  • In recent years, environmental damage to urban area becomes serious problem due to the exhaust emissions by increasing the number of vehicle . Especially, diesel particulate matters(DPM) are hazardous air pollutant s to human health and environment. The reduction technologies of exhaust emissions from diesel engines are improvement of engine combustion, fuel quality and development of diesel exhaust aftertreatment. In this study, a diesel oxidation catalyst(DOC) that is one of diesel exhaust aftertreatments was made for performance evaluation . It was tested for NA and turbocharged engine by D-13 mode that currently be used for regulation driving test mode in Korea Scanning mobility particle sizer (SMPS) was used for the analysis of the particle size distribution with and w/o DOC. As the results , for NA and tubochartged engine, CO, THC, DPM was respectively reduced 85.7, 40.7,3.3% and 79.1, 53.1, 11.6% by DOC. Test results of particle size distribution was showed that particle number is 107 ~108per ㎤ , 2 $\times$105 ~5$\times$105$\mu\textrm{g}$/㎥ for weight concentration and 100~200nm for particle mean size in diesel engine and there is no effect to reduce the particle concentration by the DOC.

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Patterns in solute chemistry of six inlet streams to Lake Hövsgöl, Mongolia

  • Puntsag, Tamir;Owen, Jeffrey S.;Mitchell, Myron J.;Goulden, Clyde E.;McHale, Patrick J.
    • Journal of Ecology and Environment
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    • 제33권4호
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    • pp.289-298
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    • 2010
  • A number of characteristics of the Lake H$\ddot{o}$vsg$\ddot{o}$l watershed, such as the lake's location at the edge of the Central Asian continuous permafrost zone, provide a unique opportunity to evaluate possible anthropogenic impacts in this remote area in northern Mongolia. In this study, we compared stream solute concentrations in six sub-watersheds in the Lake H$\ddot{o}$vsg$\ddot{o}$l watershed. Water samples were collected during the summer months between 2003 and 2005. Concentrations of $Cl^-$ ranged from 9.8 to $51.3\;{\mu}mol/L$; average nitrate concentrations were very low and ranged from undetectable to $1.1\;{\mu}mol/L$ and average ${SO_4}^{2-}$ concentration at sampling stations with minimal animal grazing ranged from 66 to $294\;{\mu}mol/L$. Average dissolved organic carbon (DOC) concentrations ranged from 642 to $1,180\;{\mu}mol$ C/L. We did not find statistically significant differences in DOC concentrations among the six streams, although DOC concentrations tended to be higher in the two northernmost streams, possibly related to differences in the active layer above the permafrost. Dissolved organic nitrogen (DON) concentrations were correlated with DOC concentration, and followed the same spatial pattern as those for DOC. In streams in this remote watershed, total dissolved nitrogen was made up of mostly organic N, as has been found for other regions distant from anthropogenic N sources. Overall, these results suggest that future research on the dynamics of DOC and DON in this watershed will be especially insightful in helping to understand how changes in climate and land use patterns will affect transformations, retention, and export of dissolved organic matter within these sub-watersheds in the Lake H$\ddot{o}$vsg$\ddot{o}$l region.