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Determination of Arsenic in Water by ICP-DRC/MS (ICP-DRC/MS를 이용한 수중의 비소 측정)

  • Jeong, Gwan-Jo;Kim, Dok-Chan;Park, Hyeon
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.6
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    • pp.620-625
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    • 2006
  • In this investigation, an ICP-DRC/MS method to measure arsenic with ultra-trace concentration without any interference by the compounds such as $^{40}Ar^{35}Cl^+\;and\;^{40}Ca^{35}Cl^+$, which disturb the precise measurement of arsonic was described. Thus, the oxgen was introduced into the dynamic reaction cell as reaction gas and reacted with arsenic ion created in plasma gas, $AsO^+$ was formed and detected with m/z of 91 by ICP-MS. It resulted in better detection limit than the old method with m/z of 75($As^+$). The optimum condition for oxygen supply as the reaction gas was 0.5 mL/min. The analytical features of the method are as follows: detection limit of $0.02{\mu}g/L$, precision(RSD) of 3.4%, and recovery of 96%. Arsenic in the water samples from the tributary streams to the Han River and the main stream of Paldang were analyzed with this method to identify the characteristics in its distribution. The concentration of As ranged from 0.53 to $1.26{\mu}g/L$. We could measure As with very low concentration, less than $1.0{\mu}g/L$, with excellent reproducibility. The method developed is expected to be applied to analyze As of the samples from sea water, food, and domestic and industrial waste water which have high concentration of Cl and/or Ca.

Distribution of $^{222}Rn$ Concentration in Seoul Subway Stations (서울지역 지하철역의 라돈농도 분포 특성)

  • Jeon, Jae-Sik;Kim, Dok-Chan
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.6
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    • pp.588-595
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    • 2006
  • Indoor radon($^{222}Rn$) concentrations of subway stations in Seoul area were measured to survey the environmental indoor radon levels and to identify sources of radon. The radon concentration of indoor air by method of long-term measuring with a-track detector were surveyed at 232 subway stations from 1998 to 2004. And the radon concentration in ground-water was measured with a method of alpha particle counting. To trace main source of radon, 8 out of 232 stations were selected and their radon concentrations in tunnel and on platform were analyzed. Total geometric mean and arithmetic mean of radon concentrations in all stations from 1998 to 2004 were $1.40{\pm}1.94pCi/L,\;1.65{\pm}1.07$ respectively. Geometric means of radon concentrations on platform and concourse were $1.54{\pm}1.96pCi/L,\;1.23{\pm}1.88pCi/L$ respectively, with higher concentration at the platform than at the concourse. The geological structure was significantly correlated to the indoor radon concentration in subway stations region. Radon concentrations of adjacent tunnel and ground-water of subway station was significantly correlated to the indoor radon concentration in subway stations. And There was a significant difference in radon concentration, depending on the depth levels in platform of subway stations(p<0.05).

Impacts of Combined Hydrogeological and Chemical Heterogeneities on the Transport of Leachate through Landfill Sites (수리지질학적, 화학적 특성의 복합 불균질성이 매립지반 내 침출수 이동에 미치는 영향)

  • Lee, Kun-Sang
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.4
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    • pp.300-307
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    • 2009
  • The transport of landfill leachate in the subsurface formations of unlined landfill sites is considered. The impacts of hydrogeological and chemical heterogeneities on the leachate transport are assessed by examining the results from a series of Monte-Carlo simulations. The landfill system simulated in this study is hypothetically represented with three levels of spatial variability for the hydrogeological and chemical parameter; (1) homogeneous hydraulic conductivity (K) and distribution coefficient ($K_d$), (2) K heterogeneity only, and (3) combined heterogeneities of K and $K_d$. To calculate the transport of leachate through negatively-correlated random hypothetical K-$K_d$ fields generated using geostatistical input parameters, a saturated flow model is linked with a contaminant transport model. Point statistic values such as mean, standard deviation, and coefficient of variation of the concentration were obtained from 100 Monte-Carlo trials. Results of point statistics show that the heterogeneities of K and $K_d$ in the landfill site prove to be an important parameter in controlling leachate concentrations. Consideration of combined K and $K_d$ heterogeneities results in enhancing the variability of contaminant transport. The variability in the leachate concentration for different realizations also increases as the distance between source and monitoring well increase.

Determination of Focused Control Pollutant Source by Analysis of Pollutant Delivery Characteristics in Unit Watershed Upper Paldang Lake (팔당호 상류의 단위유역별 오염물질 유출특성 분석을 통한 중점관리 오염원 선정)

  • Kim, Dong Woo;Jang, Mi Jeong;Han, Ihn Sup
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.5
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    • pp.367-377
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    • 2014
  • Paldang lake which is the most important water resource in Korea is classified as a stream type reservoir and water quality of Paldang lake can be significantly influenced by external pollutant source. So this study was aimed to determine focused control BOD and TP sources of each unit watershed upper Paldang lake through analysis of pollutant source distribution and pollutant runoff characteristics. Generated load, discharge load, delivery load and each load density of 11 unit watersheds upper Paldang lake were calculated using data of water quality and flow rate from pollutant sources and 74 small streams. As a result of generated load, discharge load and delivery load of BOD and TP from pollutant sources, the most BOD generated load was taken by livestock with 66% of total BOD discharge load and domestic had the most BOD discharge load, 42.7%. The ratio of delivery load of livestock and domestic was 36.4% and 34.3%, respectively. Livestock occupied high ratio of TP generated load, discharge load and delivery load with 82.5%, 44.4% and 46.7%, respectively. Gyeongan watershed which had high population density showed the highest BOD delivery load density of $14.6kg/km^2/d$ and the highest TP delivery load density with $1.23kg/km^2/d$ was analyzed in Cheongmi watershed including the biggest number of livestock. From these results, management of domestic sewer and livestock excrement was determined as a focused control pollutant source. And intensive management about domestic sewer in Gyeongan stream and livestock excrement in Cheongmi stream is required for water quality improvement of Paldang lake.

A Simulation Study to Investigate Climatic Controls on Net Primary Production (NPP) of a Rugged Forested Landscape in the Mid-Western Korean Peninsula (기복이 심한 한반도 중서부 산림경관에서 기후가 순일차생산(NPP)에 미치는 영향에 대한 모사연구)

  • Eum Sungwon;Kang Sinkyu;Lee Dowon
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.7 no.1
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    • pp.66-77
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    • 2005
  • We have investigated microclimatic controls on the spatiotemporal variations of net primary production (NPP) of a rugged forested watershed using the process-based biogeochemical model (BIOME-BGC). To validate the model simulation of water and carbon cycles at the plot scale, we have conducted field survey over deciduous broadleaf forest (DBF) and evergreen needleleaf forest (ENF) since 2000. The modeled values of soil temperature, soil moisture and soil respiration showed high correlation with those from the field measurements. The modeled seasonal changes of NPP showed high correlation with air temperature but no significant correlation with water related parameters. The precipitation frequency turned out to be the best climatic factor to explain the annual variation of NPP. Furthermore, NPP of ENF was more sensitive to precipitation frequency than that of DBF. With changes in vegetation cover and topography, the spatial distribution of NPP was of great heterogeneity, which was negatively correlated with the magnitude of NPP. Despite the annual precipitation of 1,400mm, NPP at the study site was constrained by the amount of water available for the vegetation. Such a modeling result should be verified by the field measurements.

Study of Radio Frequency Thawing for Cylindrical Pork Sirloin

  • Kim, Jinse;Park, Jong Woo;Park, Seokho;Choi, Dong Soo;Choi, Seung Ryul;Kim, Yong Hoon;Lee, Soo Jang;Park, Chun Wan;Han, Gui Jeung;Cho, Byoung-Kwan
    • Journal of Biosystems Engineering
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    • v.41 no.2
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    • pp.108-115
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    • 2016
  • Purpose: Radio frequency (RF) heating is a promising thawing method, but it frequently causes undesirable problems such as non-uniform heating. This can occur because of the food shape, component distribution, and initial temperature differences between food parts. In this study, RF heating was applied to the thawing of cylindrically shaped pork sirloin by changing the shape of electrodes and the surrounding temperature. Methods: Curved electrodes were utilized to increase the thawing uniformity of cylindrically shaped frozen meat. Pork sirloin in the shape of a half-circle column was frozen in a deep freezer at $-70^{\circ}C$ and then thawed by RF heating with flat and curved electrodes. In order to prevent fast defrosting of the food surface by heat transfer from air to the food, the temperature of the thawing chamber was varied by -5, -10, and $-20^{\circ}C$. The temperature values of the frozen pork sirloin during RF thawing were measured using fiber-optic thermo sensors. Results: After multiple applications of curved electrodes resembling the food shape, and a cooled chamber at $-20^{\circ}C$ the half-cylindrically shaped meat was thawed without surface burning, and the temperature values of each point were similarly increased. However, with the parallel electrode, the frozen meat was partially burned by RF heating and the temperature values of center were overheated. The uniform heating rate and heat transfer prevention from air to the food were crucial factors for RF thawing. In this study, these crucial factors were accomplished by using a curved electrode and lowering the chamber temperature. Conclusions: The curved shape of the electrode and the equipotential surface calculated from the modeling of the parallel capacitor showed the effect of uniform heating of cylindrically shaped frozen food. Moreover, the low chamber temperature was effective on the prevention of the surface burning during RF thawing.

Distribution of Fish Eggs and Larvae in the Western Waters of Korea (한국 서해안의 어류 난추어 분포)

  • HUR Sung-Bum;YOO Jae-Myung
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.17 no.6
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    • pp.536-542
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    • 1984
  • Fish eggs and larvae in the western waters of Korea are surveyed during the periods from February to August in 1982. Six species of eggs and forty-two species of larvae are occurred in the survey area. The dominant species occurred during the study periods are Ammodytes personatus, Enedrias sp., Engraulis japonica, Callionymus sp., Gobiidae, etc. Major spawning month and ground of each species are estimated from the data, i.e., occurrence month and abundance of eggs and larvae by survey month and area, as well as the optimum water temperature and salinity for spawning.

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Hydraulic Characteristics of Anaerobic Fluidized Bed Bioreactor (혐기성 유동상 반응기의 수리학적 특성)

  • Seok, Jong-Hyuk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.2
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    • pp.90-96
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    • 2018
  • Tracer experiments were carried out on two laboratory modes, "without media mode" and "with media mode", to examine the hydraulic characteristics of the anaerobic fluidized bed bioreactor (AFBR). For both configurations, a formula was derived for the hydraulics and data interpretation to obtain the actual characteristics of the reactor. The dispersion model is based on the assumption that carriers are non-reacting and the dispersion coefficient is constant. The model represents the one-dimensional unsteady-state concentration distribution of the non-reacting tracer in the reactors. The experimental results showed that the media increased the mixing conditions in the reactor considerably. For the reactor without media, in the range tested, the dispersion coefficient was at least an order of magnitude smaller than that of the reactor with media. Advective transport dominates and the flow pattern approaches the plug flow reactor (PFR) regime. The dispersion coefficient increased significantly as us, the superficial liquid velocity, was increased proportionally to 0.82cm/s. On the other hand, for the reactor with media, the flow pattern was in between a PFR and a completely mixed flow reactor (CMFR) regime, and the dispersion coefficient was saturated at us=0.41cm/s, remaining relatively constant, even at us=0.82cm/s. The dispersion coefficient depends strongly on the liquid Reynolds number (Re) or the particle Reynolds number (Rep) over the range tested.

Usefulness of the PRESS Technique using 3.0T Magnetic Resonance Spectroscopy for Evaluation of Non-Alcoholic Fatty Liver Disease Patients (비알콜성 지방간환자 평가를 위한 3.0T 고자기장 자기공명분광법을 이용한 PRESS 기법의 유용성)

  • Goo, Eun-Hoe
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.12
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    • pp.5931-5936
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    • 2012
  • This study was to evaluate the clinical usefulness of the PRESS technique based on the correlation between PRESS technique and biopsy results by applying 3.0T high magnetic field MRS technique for evaluation of non-alcoholic fatty liver disease patients. This experiment were carried out using a 3.0T magnetic resonance imaging equipment. The part data of each spectrum is taken by peak area integration. The part data of resonance peak was used to calculate relative ratio. MR spectral peak in patients with non-alcoholic fatty liver disease is from 0.9 to 1.6 ppm. According to MRS method study result, Patients with NAFLD were obtained with 94% sensitivity and 80% specificity(p=0.000). When compared to normal based on MRS and Biopsy results was valid correlation(r=0.79, p=0.04). Results for NAFLD(r=0.89, p=0.002) also showed a correlation. Therefore, PRESS technique to evaluate patients with non-alcoholic fatty liver disease, the distribution difference between normal liver and fatty liver part is significantly distinguished. Biopsy and MRS fatty liver peak ratio(%) proves high lipid over grade(r = 0.7).

Oral Health Knowledge and Awareness of the Prevention Effects against Dental Caries among Childcare Teachers (보육교사의 구강보건지식수준과 치아우식증 예방인식도 조사)

  • Yoon, Hyun-Seo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.9
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    • pp.5668-5674
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    • 2014
  • This study examined the oral health knowledge of childcare teachers and their awareness of the prevention effects against dental caries. The subjects in this study were 433 childcare teachers in Seoul, Gyeonggi Province, Busan and South Gyeongsang Province, on whom a survey was conducted for five months, beginning in March, 2013. Hospitals (56.6%) were the most common route by which the childcare teachers acquired oral health knowledge. Regarding the distribution of the correct answers on oral health knowledge, every teacher gave the correct answer to the item "When a tooth comes out, it should be kept in milk and then be brought to a dental clinic," and the smallest number of them (35.1%) gave the correct answer to the item "When a tooth comes out, it should be washed with water." Concerning the level of oral health knowledge, the respondents, who worked in Busan and South Gyeongsang Province (p<0.001), who worked in childcare centers with more children (p<0.001), who were younger (p<0.001), and who were junior college graduates (p=0.002) had better oral health knowledge. In regard to the awareness of the prevention effects against dental caries, the respondents who were older (p<0.001) and who were married (p=0.002) were more aware of the prevention effects. According to position and career, teachers who were assistant principals (p=0.023) and had worked for 10 years or more (p=0.009) were more aware of the effects. Therefore, child care teachers should acquire accurate knowledge to improve the oral health of children, and regular training programs for age and education are needed.