• Title/Summary/Keyword: Dispersion force

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The Properties of Cement Paste Mixed with Carbon Nanotubes Dispersion Solution (탄소나노튜브 분산용액을 혼입한 시멘트 페이스트의 특성 변화)

  • Park, Sung-Hwan;Kim, Ji-Hyun;Chung, Chul-Woo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.05a
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    • pp.201-202
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    • 2021
  • Currently, the domestic construction industry is trying to expand the range of building materials due to overload of growth. In particular, several studies are being conducted to make up for the weakness of building materials by solving problems such as reduction of tensile strength and brittle behavior of concrete. Among them, efforts to maximize the use of carbon nanotubes (CNT) that has excellent mechanical and electrical conductivity properties are continuing. However, CNT is hydrophobic and have a strong Van der Waals force between particles, making it difficult to obtain an effective dispersion state. Therefore, in this study, various kinds of surfactants like DOC (Sodium Deoxycholate), PVP (Polyvinylpyrrolidone), and PCE (Polycarboxylate ester) were added to improve the dispersibility of CNT, and analyzed the changes in the properties of the cement paste mixed with them.

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Effect of Electrolyte on the Adhesion of Particulate Soil to Fabric in the Surfactant Solution-Adhesion of -$\alpha$-$Fe_2O_3$Particles to PET Fabric- (계면활성제 용액네에서 고형오구의 직물에서의 부착에 영향을 주는 전해질 효과-$\alpha$-$Fe_2O_3$입자의 PET 섬유직물에의 부착-)

  • 강인숙;김병주
    • Journal of the Korean Society of Clothing and Textiles
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    • v.25 no.8
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    • pp.1465-1474
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    • 2001
  • The dispersion stability of particles and the adsorption of surfactant were examined as a fundamental environment to adhesion of particulate soil to fabric. The adsorption of surfactant on the PEF fabrics decreased with the addition of electrolytes and decreased with increasing the ionic strengths showed similar tendency to PET fabric. And the dispersion force of $\alpha$-Fe$_2$O$_3$particles decreased with the addition of electrolyte. The adhesion of particulate soil to fabric, increased with decreasing the adsorption of surfactant the correlation between the two was high at low ionic strength. The correlation between the adsorption of surfactants on $\alpha$-Fe$_2$O$_3$ particles and the adhesion of particles to fabric was smaller as shown in the correlation between the adsorption of surfactants on fiber substrate and the adhesion of particles on fabric. However, the correlation between the adhesion of particles to fabric and the stability of particle dispersion was relatively more significant.

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Size Control and Dispersion Properties of Illite Clay by Physicochemical Treatment (물리화학적 처리에 의한 일라이트 점토광물의 입도조절 및 분산특성)

  • Lim, Jae Won;Jeong, Euigyung;Seo, Kyeong-won;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.22 no.2
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    • pp.133-137
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    • 2011
  • In this study, illite was size-reduced using a wet-ball-milling treatment to improve its dispersion. Changes in illite particle size, size distribution, and dispersion characteristics after varying the treatment period were investigated. And the dispersion and dispersion stability of illite solution after 2 h wet ball milling treatment with different pH conditions were also evaluated. The illite particle size significantly decreased as the treatment time increased and the size reduction effect of wet ball milling deteriorated above 2 h treatment time. In addition, illite particle size was more evenly distributed as the treatment time increased. X-ray diffraction (XRD) analysis showed that no crystal structural changes of illite were induced, but the characteristic peak of illite the weaker due to the size reduction and exfoliation, as the treatment time increased. Zeta potential analysis showed that the illite dispersion improved, as the treatment time increased. The illite wet-ball-mill treated at pH 2 had the lowest dispersion stability. Illite dispersion and dispersion stability increased as pH increased, due to the increase in surface ionization. Hence, the results showed that as the treatment time increased, the illite particle size decreased, and dispersion and dispersion stability improved due to the increase in surface energy and repulsion force between particles.

ON SMALL PERTURBATION DUE TO COLLISION OF PARTICLES IN AXISYMMETRIC ACCRETION DISK (축대칭 강착원반에서 충돌에 의한 소 섭동에 관하여)

  • YOO KYE WHA
    • Journal of The Korean Astronomical Society
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    • v.34 no.1
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    • pp.31-33
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    • 2001
  • The collision effects in particles of the accretion disk are examined by the use of small perturbation. The collision force is assumed to be equal to 2 vV. From the equations governing collisions of such particles the local dispersion relation is obtained.

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Electrical Characteristics and Fabrication of CNT/Cu Nanocomposite (CNT/Cu 나노복합체의 제조 및 전기적 특성평가)

  • Hong, Youn-Jeong;Kim, Hye-Jin;Lee, Kyu-Mann;Kim, In-Woo
    • Journal of the Semiconductor & Display Technology
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    • v.6 no.4
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    • pp.59-63
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    • 2007
  • The CNTs are the most extensively studied material which are characterized by the complete property of matter, structure, and the large thermal conductivity (thermal conductivity of CNTs ~>2000W/mK vs. thermal conductivity of Aluminum ~> 204W/mK). Thus, they are successfully applied to the various fields. However, due to the strong agglomeration caused by the van der waal's force, their applications are limited. In the present study, a new method for CNTs dispersion was developed by using the mechanical dispersion, acid treatment, and then Cu was coated. This process produces CNTs/Cu nanocomposite powders, whereby the CNTs are homogeneously located within the Cu powders. The electrical properties of the CNTs/Cu nanocomposite were investigated.

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Analysis of Hybrid Emulsion Surfaces by the Phase Lag Mapping Atomic Force Microscopy (위상지연 원자간력 현미경법에 의한 혼성 에멀젼 표면의 분석)

  • Han, Sang-Hoon;Kim, Jong-Min;Park, Dong-Won
    • Applied Chemistry for Engineering
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    • v.17 no.4
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    • pp.381-385
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    • 2006
  • We applied a new analyzing technique for the polyurethane acrylate hybrid emulsion sample composed of polyurethane resin and acrylate resin using the phase-lag mapping techniques of atomic force microscopy. For the analysis, we synthesized similarly sized pure polyurethane dispersion and acrylate emulsion particles, which were used for measuring the standard phase-lag intensities for each material. Based on these signal intensity, we could discriminate acryl particle in the polyurethane dispersion matrix with the resolution of a few tens of nanometers. Thus, the techniques show a new possibility in the analysis of the organic two-phase particles, and we believe the techniques are helpful to design organic particles.

Research on Wave Kinematics and Wave Loads in Breaking Wave (쇄파의 유동구조 및 쇄파력에 관한 연구)

  • Lee, Soo-Lyong;Kang, Byung-Yoon;Lee, Byeong-Seong
    • Journal of Ocean Engineering and Technology
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    • v.21 no.1 s.74
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    • pp.18-24
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    • 2007
  • When the wind blows strong, most waves are breaking at sea. Breaking waves occur by exceeding the limitation of wave steepness (wave height/wave length = 1/7). Because a wave of single angular frequency couldn't generate the breaking phenomena at a two-dimensional ocean engineering basin, the breaking wave can be generated by the superposition of waves with various angular frequencies based on dispersion relation. This study investigates the particle kinematics in the breaking wave and the magnitude of the breaking wave exciting force at the breaking point and breaking region. We compare the regular wave load in a regular wave, which has same specifications (wave height, period and length), with the breaking waveload. Also, the experimental results of wave exciting force and particle velocity are investigated, by comparison with the analytic results using the potential theory.

In-plane varying bending force effects on wave dispersion characteristics of single-layered graphene sheets

  • Cao, Yan;Selmi, Abdellatif;Tohfenamarvar, Rasoul;Zandi, Yousef;Kasehchi, Ehsan;Assilzahed, Hamid
    • Advances in nano research
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    • v.10 no.2
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    • pp.101-114
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    • 2021
  • An analytical investigation has been performed on the mechanical performance of waves propagated in a Single-Layered Graphene Sheet (SLGS) when an In-plane Varying Bending (IVB) load is interacted. It has been supposed that the Graphene Sheet (GS) is located on an elastic medium. Employing a two-parameter elastic foundation, the effects of elastic substrate on the GS behavior are modeled. Besides, the kinematic equations are derived by the means of a trigonometric two-variable refined plate theory. Moreover, in order to indicate the size-dependency of the SLGS, a Nonlocal Strain Gradient Theory (NSGT) was considered. The nonlocal governing differential equations are achieved in the framework of Hamilton's Principle (HP). Also, an analytical approach was used to detect the unknowns of the final eigenvalue equation. Finally, the effects of each parameters using some dispersion charts were determined.

Carbon Nano Tube Dispersion Evaluation in B-stage Resin Films (B-stage 레진 필름의 카본나노튜브 분산도 평가 및 제조공정 최적화)

  • Oh, Young-Seok;Park, Tea-Hoon;Byun, Joon-Hyung;Yi, Jin-Woo;Kim, Byung-Sun;Joe, Chee-Ryong
    • Composites Research
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    • v.29 no.6
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    • pp.353-357
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    • 2016
  • An appropriate way to fabricate a hybrid composite containing evenly dispersed carbon nano tubes(CNTs) is to stacking B-stage resin films that contain evenly dispersed CNTs and various reinforcing fiber layers alternatively. In the present study, B-stage resin films are manufactured via shear mixing and three-roll milling. CNT dispersion in resin via these two processes are evaluated by SEM on their fracture surfaces. For more efficient process, the dispersivities are evaluated according to the number of calendering passes. Samples are made for different number of passes during calendering, and their dispersions are evaluated via SEM fractographs as well as by measuring their electrical conductivities. Additionally, the optimal process conditions are obtained by measuring the electrical conductivity and evaluating their dispersivity of the samples prepared by gap mode and force mode.

Molecular Dynamics Simulation of Contact Process in AFM/FFM Surface Observation

  • Shimizu, J.;Zhou, L.;Eda, H.
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.61-62
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    • 2002
  • In order to clarify the contact mechanism between specimen surface and probe tip in the surface observation by the AFM (atomic force microscope) or the FFM (friction force microscope), several molecular dynamics simulations have been performed. In the simulation, a 3-dimensional simulation model is proposed where the specimen and the probe are assumed to consist of mono-crystal line copper and a carbon atom respectively and the effect of cantilever stiffness is also taken into considered. The surface observation process on a well-defined Cu{100} is simulated. The influences of cantilever stiffness on the reactive force images and the behavior of probe tip were evaluated. As a resuIt, several phenomena similar to those observed by the actual surface observation experiment, such as double-slip behavior and dispersion in the stick-slip wave period were observed.

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