• Title/Summary/Keyword: Dispersion force

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Effect of Temperature on the Surface Tensions in the Detergency System(I) -Change of Surface Tension Components of Washing Liquids- (온도가 세척계의 표면장력에 미치는 영향(제1보) -세액의 표면장력 성분변화를 중심으로-)

  • Chae, Chung-Hee;Kim, Sung-Reon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.17 no.4
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    • pp.511-517
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    • 1993
  • Changes of the surface and interface tension with temperature for washing liquids and alkanes were measured by FACE surface tensiometer. Using the extended Fowkes' equation, the dispersion and polar force components of the surface tension were estimated. The results were as follows : 1. The surface tensions of washing liquids and alkanes decreased almost linearly with the increase of temperature. 2. The interface tensions of 0.25% DBS/alkane increased slowly with the increase of temperature. In the case of nonionic surfactant solutions, however, the interface tensions with alkanes varied with the number of hydrophilic ethylene oxide(EO) groups. 3. Of the surface tension of water at $20^{\circ}C$, the dispersion force component was 25.3 dyn/cm and the polar force component was 47.8 dyn/cm. As the temperature increased, both the polar and dispersion force components decreased in a similar fashion. 4. The dispersion force component of surface tension of 0.25% DBS solution was 30.0 dyn/cm, and the polar force component was 2.2 dyn/cm at $20^{\circ}C$. The two components decreased with the increase of temperature. 5. As the temperature increased, the dispersion force component of surface tension decreased and the polar force component increased significantly for 0.25% NPPG-7.5EO solution. In the case of 025% NPPG-10EO, both the dispersion and polar force components decreased slowly, but the polar force component is expected to increase from $60^{\circ}C$. However, the polar force component of surface tension decreased with the increase of temperature for 025% NPPG-15EO solution, and at the temperature higher than $60^{\circ}C$ the surface tension is expected to be composed of only dispersion force component.

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An Experimental Study of Vibrator Amplitude Change for a Clamping Force Dispersion and Friction Coefficient Decrease (체결력 산포와 마찰계수의 감소를 위한 가진기의 진동량 변화 실험)

  • Lee, Geum-Gang;Moon, Seok-Man;Cho, Yong-Joo
    • Tribology and Lubricants
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    • v.27 no.6
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    • pp.332-337
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    • 2011
  • The object of this experimental study is to investigate influences of vibrator amplitude on clamping force in vibration for bolted joint. The experiment is that change the vibrator amplitude to check clamping force. also the friction coefficient calculated by equation to use an obtained in experiments. The main purpose of generation vibrations is decreasing the clamping force dispersion. also If vibration occurs while tightening the bolt is reduced coefficient of friction. In this paper, In experiments to measure the clamping force before vibrator's amplitude changing. Vibrator's amplitude changes to 5.5mm from 4.4mm. As a result, under various vibration condition, relationship of clamping force and Vibrator amplitude.

Deaggregation and Ultradispersion of Detonation Nanodiamonds in Polar Solvent Using Physicochemical Treatments (물리화학적 처리를 통한 극성 용매 내 나노다이아몬드의 탈응집 및 분산성 향상 연구)

  • Kim, Changkyu;Lee, Gyoung-Ja;Rhee, Changkyu
    • Journal of Powder Materials
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    • v.20 no.6
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    • pp.479-486
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    • 2013
  • In the present work, physicochemical treatments were introduced for de-aggregation and stable dispersion of detonation nanodiamonds (DND) in polar solvents. The DNDs in water exhibited a particle size of 138 nm and high dispersion stability without particular treatment. However, the DNDs in ethanol were severely aggregated to several micrometers in size and showed poor dispersion stability with time. To break down aggregates of DNDs and enhance the dispersion stability of them in ethanol, mechanical force and chemical surfactant were introduced as functions of zirconia ball size, kind of surfactant and amount of surfactant added. From the analyses of average particle size and Turbiscan results, it was suggested that the size of DNDs in ethanol can be reduced by only mechanical force; however, the DNDs were re-aggregated due to high surface activity. The long-term dispersion stability can be achieved by applying mechanical force to break down the aggregates of DNDs and by preventing re-aggregation of them using proper surfactant.

Phonon Dispersion and Specific Heat in FCC Structure (FCC구조에서 포논분산과 비열)

  • Chung, Jae-Dong;Lee, Kyung-Tae
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.1207-1212
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    • 2004
  • A model for the phonon dispersion relationship for cubic zinc sulfide structure, for example SiC, is developed in terms of two unknown force constants. Born model that incorporates bond bending and bond stretching, is used for the force constants. The force constants are determined by fitting to experimental data. Using only the nearest-neighbor coupling results in $6{\times}6$ sized dynamic matrix. The eigenvalues of dynamics matrix for each wavenumber in 3-D ${\kappa}$ space correspond to frequencies, 3 for optical phonon and 3 for acoustic phonon, which is so-called dispersion relation (${\kappa}$-${\omega}$). The density of state is determined by counting the states for each frequency bin, and the properties such as specific heat and thermal conductivity can be obtained. The specific heat is estimated on this model and compared with experiment and other models, i.e. Debye model, Einstein model and combined Debye-Einstein model. In spite of the simple bond potential model, reasonable agreements are found.

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VERIFICATION OF TURBULENCE AND NON-DRAG INTERFACIAL FORCE MODELS OF A COMPUTATIONAL MULTI-FLUID DYNAMICS CODE (CMFD 코드의 난류 모델 및 비견인력 모델의 검증 계산)

  • Park, Ik Kyu;Chun, Kun Ho
    • Journal of computational fluids engineering
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    • v.18 no.2
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    • pp.99-108
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    • 2013
  • The standard drag force and virtual mass force, which exert to the primary flow direction, are generally considered in two-phase analysis computational codes. In this paper, the lift force, wall lubrication force, and turbulent dispersion force including turbulence models, which are essential for a computational multi-fluid dynamics model and play an important role in motion perpendicular to the primary flow direction, were introduced and verified with conceptual problems.

A Research on Powder Dispersion Ability Using Several Content, Variety of Powder and Additive in Aqueous System (파우더, 첨가제의 종류와 함량에 따른 수상 내에서의 파우더 분산에 관한 연구)

  • Kim, Sun-Young;Kim, Il-Gu;Choi, Seung-Man;Lee, Sang-Min
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.38 no.4
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    • pp.271-276
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    • 2012
  • In this study, the dispersion ability of powder in low viscosity solubilization system that depends on variety and amount of additives and powders was investigated. A PMMA powder shows outstanding dispersion ability because of its repulsive force of partially charged chain and low density of porous structure. A sample, which contains salts, showed better dispersion tendency than a sample without any additives. The dispersion ability was quantity of salts dependent. Furthermore, a sample with divalent ion salts, like $MgSO_4$, showed better dispersion tendency than that of monovalent ion salts, like NaCl or KCl. The reason for the better dispersion tendency was due to the existence of ionized salts around the powders which significantly improves repulsive force between powders and consequently reduces powder aggregation. The sample with chelating agent, like EDTA as an additive, had improved dispersion ability. EDTA chelates and blocks metal cation therefore anion's character is maximized and repulsive force between powders is improved. As a result, salts and EDTA help to improve the powder dispersion ability and the stability of product.

The Surface Tension Components of Mixed Surfactant Solutions (혼합계면활성제 용액의 표면장력 성분)

  • 정혜원;윤혜신
    • Journal of the Korean Society of Clothing and Textiles
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    • v.20 no.4
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    • pp.690-696
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    • 1996
  • In order to study the affect of surfactants on the soil removal, the dispersion and polar force components of surface tension for surfactant solutions (such as LAS, AS, AOS, AES, AE) were calculated using extended Fowkes equation. The contact angles on paraffin and surface tension of surfactant solutions were measured. Cmcs of LAS, AS, AES and AE were below the concentration of 0.05%, but the cmc of AOS was between 0.05% and 0.1%. The surface tension of AE was lowest but the dispersion force component was greastest. Total surface tension of every mixed anionic surfactant was lower than that of single surfactants, and the dispersion force components were almost decreased. The addition of sodium carbonate to the sufactant solutions decreased the surface tension, and the surface tensions of surfactant solutions were lowered after washing.

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Anisotropic Dispersion Force Effects for Surface Liquid Crystal Alignment on Rubbed Polystyrene Surfaces (러빙처리된 폴리스타이렌막 표면에있어서의 표면 액정 배향에관한 이방성 분산력의 효과)

  • 서대식
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.05a
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    • pp.105-108
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    • 1996
  • We have studied the anisotropic dispersion force effects for surfaces alignment of liquid crystals (LCs) on rubbed polystyrene (PS) surfaces by unidirection. In microphotographs of the textures, we obtained the nematic (N) LCs are shown to align in both direction parallel and Perpendicular to the rubbing for region up to medium rubbing, however to align in the direction perpendicular to the rubbing for strong rubbing legion. We suggest that the anisotropic dispersion force is very important rather than macro-surface groove effect to uniform alignment of LCs. We also measured the temperature dependence of extrapolation length of 5CB on rubbed PS surfaces for strong rubbing. It is shown that the polar anchoring strength of 5CB is very weak on rubbed PS surface compared to the rubbed polyimide (Pl) surface.

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A research about micro size polymer bead injecting process based on electrostatic force (정전기력 기반의 마이크로 사이즈 폴리머 비드 주입 공정 연구)

  • Yang, Bong-Su;Yang, Sung-Wook;Ko, Jung-Bum;Choi, Kyung-Hyun;Doh, Yang-Hoi
    • Journal of Power System Engineering
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    • v.20 no.2
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    • pp.43-50
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    • 2016
  • This research proposal is based on a novel non-contact technique of micro-sized bead injection process for fabrication of electronic paper display. This non-contact injection process is based on the principle of electrostatic force and uses micro-sized metal-coated beads dispersed in a solution. The dispersion retention times of three different solutions with viscosities of 10 cps, 100 cps, and 1000 cps were measured by optical equipment showing the retention times of 5 mins, 10 mins, and 30 mins respectively. The dispersion retention rate dropped as the time passed. The dispersion retention characteristic of 1000 cps solution was more stable as compared to those of 10 cps and 100 cps meaning that higher viscosity has better retention properties. The experimental results of bead injection at different viscosity levels of the solution were also measured and a stable injection result was achieved by using 1000 cps solution. This results show that stable injection is dependent on solution viscosity and dispersion.

Molecular Interactions of Soaked Nonionic Dye in Ionomer Films (아이오노머 필름에 흡수된 비이온계 염료의 분자간 상호작용에 관한 연구)

  • ;;;;;;Forrest A. Landis;Robert B. Moore
    • Polymer(Korea)
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    • v.25 no.5
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    • pp.671-678
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    • 2001
  • Sodium and zinc salts of poly(ethyaene-co-methacrylic acid) ionomers consist of three phases, i.e. ionic aggregates, amorphous, and crystalline phases. Dye molecules after soaked from the methanol solution are located near the amorphous phase or ionic aggregates within ionomer films. Depending on the location of the molecules in the ionomer film, they are under influence of dispersion forces (ethylene parts), polar forces (acid parts). and ionic dipole (ionic aggregates) interactions. The UV/Vis absorption peak of Nile Red under the dispersion force is found at near 500 nm, for the dye under the polar force effect 525 nm, and 550 and 610 nm for the dyes under $Na^+$ and $Zn^{2+}$ ionization effects, respectively. Since the divalent $Zn^{2+}$ ion has larger ionic dipole than the monovalent $Na^+$ ion, the larger red-shift of the absorption band due to the ionic dipole interaction is observed for $Zn^{2+}$ counter ion.

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