• Title/Summary/Keyword: Dispersibility

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Preparation and Characteristics of Fluorinated Carbon Nanotube Applied Capacitive Desalination Electrode with Low Energy Consumption (불소화 탄소나노튜브를 적용한 저에너지 소모형 축전식 탈염전극의 제조 및 특성)

  • Yoo, Hyun-woo;Kang, Ji-hyun;Park, Nam-soo;Kim, Tae-il;Kim, Min-Il;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.27 no.4
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    • pp.386-390
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    • 2016
  • The surface of carbon nanotubes (CNTs) was modified by fluorination and applied to conductive materials to improve the energy efficiency of a capacitive desalination (CDI) electrode. CNTs were fluorinated at room temperature with a mixed gas of fluorine and nitrogen, and activated carbon based CDI electrodes were then prepared by adding 0-0.5 wt% of untreated CNTs or fluorinated CNTs with respect to the activated carbon. Fluorinated CNTs showed improved dispersibility in the electrode and also slurry as compared to untreated CNTs, which was confirmed by the zeta potential and scanning electron microscopy. Fluorinated CNTs added electrodes showed higher desalination efficiency but lower energy consumption than those of using untreated CNTs added electrodes. This was attributed to the decrease in the resistance of CDI electrodes due to the improved dispersibility of CNTs by fluorination.

Optimization of self-dispersible floating granule (UG) of flucetosulfuron and its herbicidal performance (Flucetosulfuron 수면부상형 입제의 최적화 및 제초효과)

  • Kim, Do-Soon;Kim, Tae-Young;Lee, Jong-Nam;Hwang, Ki-Hwan;Lee, Yong-Sang
    • The Korean Journal of Pesticide Science
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    • v.10 no.1
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    • pp.28-35
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    • 2006
  • This study was conducted to optimize formulation factors of a self-dispersible floating granule of flucetoaulfuron that can be used at a low application volume (5 kg $ha^{-1}$). SPA and xanthan gum were selected as a binder because blending of them showed good granulation and floatation. Potassium chloride selected as a filler also showed good granulation, floatation and disintegration properties. Among wetters and dispersants, Surfynol 440 gave the best dispersibility The optimum granule size was determined to be 1.0 mm considering floating time and dispersibility. Flucetosulfuron was mixed with the blend of SPA and xanthan gum, potassium chloride, and Surfynol 440 and formulated as a floating self-dispersible granule at 1.0 mm in diameter. Indoor and outdoor field experiments showed that the floating granule of flucetosulfuron performed well, covering long range from the application spot up to 15 m in weed control. Therefore, this floating technology may be used for laborsaving herbicide formulation development and help to reduce workloads for herbicide application.

Effect of a Compatibilizer on the Microstructure and Properties of Partially Biodegradable LDPE/Aliphatic Polyester/Organoclay Nanocomposites

  • Hwang Kun-Jun;Park Jin-Woo;Kim Il;Ha Chang-Sik;Kim Gue-Hyun
    • Macromolecular Research
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    • v.14 no.2
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    • pp.179-186
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    • 2006
  • In the present work, low density polyethylene (LDPE)/aliphatic polyester (APES)/organoclay ternary nanocomposites were prepared. In particular, the effect of a compatibilizer, polyethylene-graft-maleic anhydride (PE-g-MAH), on the morphology and properties of the ternary nanocomposites was investigated. LDPE/APES/organoclay nanocomposites were prepared through melt intercalation method using two different kinds of organoclay. The dispersibility of silicate clays in the nanocomposites was investigated by X-ray diffraction and atomic force microscopy. The ternary nanocomposites showed higher tensile properties than the LDPE/APES blend did. The dispersibility and properties of nanocomposites containing Cloisite 30B were better than those of the nanocomposites containing Cloisite 20A. Unlike Cloisite 20A, hydroxyl groups in the intercalants in Cloisite 30B interlayer underwent a certain polar interaction with the carboxyl group of APES, favoring the intercalation of APES chains and the formation of LDPE/APES/Closite 30B nanocomposites. However, the introduction of the polar hydroxyl groups also enhanced the interaction with the silicate surface at the same time, thereby rendering somewhat difficult the replacement of the surface contacts by LDPE chains, and impeding the extensive intercalation and further exfoliation of Cloisite 30B in the LDPE/APES matrix. The compatibilizer enhanced the intercalation of the polymer chain inside the clay gallery and thus improved the mechanical properties of the ternary nanocomposites. Rheological measurements of the nanocomposites via frequency sweep experiment indicated a certain interaction between the clay platelet and the polymer molecules in the melted state.

Characteristics of Lecithin-adsorbed Magnetic Nanoparticle and Biocompatibility of Its Fluid (Lecithin이 흡착된 나노 자성입자의 특성과 그 자성유체의 생체 친화성)

  • Park, Sang-Im;Kim, Chong-Oh;Kim, Jong-Hee;Kim, Seong-Min;Kim, Keun-Ho
    • Journal of the Korean Magnetics Society
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    • v.16 no.6
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    • pp.293-299
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    • 2006
  • Magnetic nanoparticles were prepared by thermal decomposition and adsorbed with lecithin by applying ultrasonic. The size and saturation magnetization of magnetic nanoparticles were observed with different lecithin concentration, and the maximum tolerated dose (HTD) and toxicity of magnetic fluid was investigated through a biological test. The thickness of lecithin-adsorption layer increased non-linearly with increasing amounts of added lecithin, and the desirable adsorption amount was observed in the lecithin concentration of 20%(w/v). The dispersibility and magnetic properties of lecithin-adsorbed magnetic nanoparticles were most excellent when the ultrasonic exposure time was 1.5h. Also, the maximum tolerated concentration with best cell viability was $32{\mu}g/ml$ in vitro test, and lecithin-adsorbed magnetic fluids improved the biocompatibility by 1.2 times compared with bare magnetite fluids in vivo.

Study on Synthesis of Honeycomb-patterned Resin Dispersed Silver Nanoparticles (은 나노입자가 분산된 Honeycomb-patterned 수지 합성에 대한 연구)

  • Lee, Dong Chang;Lee, Jong Jib
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.2
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    • pp.711-718
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    • 2017
  • Silver nanoparticles were attached by chemical reduction after synthesizing a porous PVK-CTA complex. The PVK-CTA complex was synthesized by polymerizing N-vinylcarbazole in a CTA-chloroform solution using iron(III) chloride as an oxidizing agent and a honeycomb-pattern with uniformly formed macropores was formed by applying steam to the complex surface soaked with a volatile solvent under humid conditions. Using TTF as a reducing agent and PVP as a dispersant, silver nanoparticles were attached on the Honeycomb-pattern complex surface through chemical reduction. The formation of the complex was confirmed by FT-IR and UV-Vis spectrometry, and the degree of thermal decomposition of the complexes was analyzed after N-vinylcarbazole was polymerized by varying its concentration. The uniformity of the pores on the composite surface and the dispersibility of the attached silver nanoparticles were investigated by SEM. The dispersibility of the silver nanoparticles was also analyzed by varying the concentrations of reducing agent and dispersant and precursor.

Synthesis and Dispersion of Ceria(CeO2) Nanoparticles by Solvothermal Process (용매열 공정을 이용한 세리아(CeO2) 나노분말의 합성 및 분산거동)

  • Lim, Tae Seop;Ock, Ji Young;Choi, Yeon Bin;Kim, Bong Gu;Son, Jeong Hun;Jung, Yeon Gil
    • Korean Journal of Materials Research
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    • v.30 no.7
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    • pp.376-382
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    • 2020
  • CeO2 nanoparticles, employed in a lot of fields due to their excellent oxidation and reduction properties, are synthesized through a solvothermal process, and a high specific surface area is shown by controlling, among various process parameters in the solvothermal process, the type of solvent. The synthesized CeO2 nanoparticles are about 11~13 nm in the crystallite size and their specific surface area is about 65.38~84.65 ㎡/g, depending on the amount of ethanol contained in the solvent for the solvothermal process; all synthesized CeO2 nanoparticles shows a fluorite structure. The dispersibility and microstructure of the synthesized CeO2 nanoparticles are investigated according to the species of dispersant and the pH value of the solution; an improvement in dispersibility is shown with the addition of dispersants and control of the pH. Various dispersing properties appear according to the dispersant species and pH in the solution with the synthesized CeO2 nanoparticles, indicating that improved dispersing properties in the synthesized CeO2 nanoparticles can be secured by applying dispersant and pH control simultaneously.

Water-dispersible Clay Content in Summer Rainy Season for Korean Irrigated Rice Paddy Fields as Affected by Cultivated Years Using Heavy Agro-machinery and Soil Properties (우리나라 관개논에서 토양특성과 대형농기계를 사용한 경작년수에 따른 여름 강우기 분산성 점토의 함량)

  • Han, Kyung Hwa
    • Korean Journal of Environmental Agriculture
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    • v.37 no.4
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    • pp.317-323
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    • 2018
  • BACKGROUND: This study was conducted to evaluate the water-dispersible clay content of paddy soils over the country in the summer rainy season as affected by cultivated years using heavy agro-machinery and soil properties such as texture and exchangeable sodium percentage. METHODS AND RESULTS: Water-dispersible clay content of 16 soil series of Korean paddy soils over the country were investigated in summer rainy season from July to August, 2006 by Middleton's method. Water-dispersible clay content ranged from non-detected to 4.8%, showing maximum value from the fine textured soils and high clay dispersibility in average from the coarse textured soils. Longer cultivated years using agro-machinery more than 40 hp result in higer water-dispersible clay content for 60% of studied paddy soils with less than 5% of exchangeable sodium percentage (ESP). Exceptionally, soils with relatively big difference of ESP at about 10 percent showed higher water-dispersible clay content with higher ESP. CONCLUSION: Long years of cultivation using agro-machinery with more than 40 hp enhanced water-dispersiblility of clay in approximately 60% of the studied paddy fields except for salt-affected soils.

Effect of Dispersant and Silane on Dispersion of Magnetic Powder Paste (연자성 금속 분말의 분산에 분산제와 실란이 미치는 영향)

  • Lee, Chang Hyun;Shin, Hyo Soon;Yeo, Dong Hun;Nahm, Sahn
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.1
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    • pp.25-29
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    • 2019
  • Various process technologies for manufacturing power inductors are under development. The core goal is to increase the mixing ratio of the soft magnetic powder in the epoxy, and to uniformly disperse it in a molding-type power inductor, manufactured by the injection molding method. In this study, we investigated the effect of dispersant and silane on the dispersion of soft magnetic metal powders in epoxy. We added 0.6 wt% of dispersant and 2.0 wt% of silane, and an excellent dispersibility resulted. Under the conditions of 0.3 wt% of dispersant and 0.5 wt% of silane, we added both dispersant and silane together to observe the effect of their interaction on dispersibility. Similarly, the addition of 0.3 wt% of dispersant and 0.1 wt% of silane resulted in a sharp increase in viscosity, considered to be due to the interaction of the dispersant and silane. The addition of 0.1 wt% of dispersant with 0.5 wt% of silane resulted in a sharp rise in viscosity, and sedimentation-height decreased sharply due to the dispersion optimization.

Evaluation of Structural Changes and Dispersibility of Boron Nitride Nanotubes under Different Ultrasonication Conditions (초음파 처리 조건에 따른 질화붕소나노튜브 구조 변화 및 분산성 평가)

  • Da Bin Cheon;Won Jung Choi;Seung Hwa Yoo
    • Composites Research
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    • v.37 no.4
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    • pp.350-355
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    • 2024
  • Boron nitride nanotubes (BNNT) are materials of significant interest in next-generation technological fields due to their outstanding physicochemical properties, including excellent chemical and thermal stability. However, for effective utilization, dispersion of BNNT is essential. Unfortunately, BNNT exhibit hydrophobic surfaces and strong van der Waals forces, making their dispersion challenging. Current dispersion methods include the addition of surfactants and surface functionalization, but these chemical treatments often damage BNNT and involve cumbersome processes. In this study, we dispersed BNNT in water under various tip ultrasonication conditions and identified conditions that do not affect BNNT using FT-IR spectroscopy, Raman spectroscopy, and X-ray diffraction analysis. Subsequently, enhanced dispersibility was confirmed through turbidity measurements, and the solubility range in 15 different solvents was evaluated using the Hansen solubility parameter.