• Title/Summary/Keyword: Disperse dyes

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Dyeing of Ultra High Molecular Weight Polyethylene Fibers with Diamino-anthraquinoid Blue Disperse Dyes Having Linear Long Alkyl Substituents (선형의 장쇄 알킬치환기를 가지는 디아미노안트라퀴논계 청색 분산염료에 의한 초고분자량 폴리에틸렌 섬유의 염색)

  • Kwak, Dong-Sup;Kim, Tae-Kyeong
    • Textile Coloration and Finishing
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    • v.24 no.3
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    • pp.180-188
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    • 2012
  • Following the reported study that showed the dyeability of diamino-anthraquinoid blue dyes substituted with relatively shorter alkyl groups, the longer aliphatic substituents than pentyl group were examined in terms of the color strength and fastness properties toward UHMWPE fibers. The color strength was increased up to pentyl group and then gradually decreased. However, the fastness properties were improved continuously to octyl group which was the longest alkyl substituent in this study. The most effective maximum color strength was obtained at $130^{\circ}C$ for 2 hours with 3% owf of dyes. The overall fastnesses to washing, rubbing, and light were good enough for practical uses.

The Application of Non-ionic Vat dye to Polyester Fiber : Practical Aspects and Preliminary Studies (비이온성 배트염료의 폴리에스터 섬유에의 응용)

  • 손영아;김태경
    • Textile Coloration and Finishing
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    • v.15 no.1
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    • pp.23-29
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    • 2003
  • Dyeings of the most widely used to the synthetic fibers, namely polyamide and polyester, have been carried out using acid dyes and disperse dyes. The above mentioned dye types, and indeed all dyes onto substrates, rely on the reaction properties between the substrates and dye molecules. In terms of fastness properties, however, especially to washings, the satisfactory levels are not present in the results from acid and disperse dyeings. Thus, vat dyeings leaves a feasibility and are an alternative way to overcome the problem. Although attempts and works have been reported in early years, with little if any commercial achievement and success. In this context, to meet increased demands towards a high level of wash fastness from consumers and retailers, an attempt using vat dyes has been carried out in this work.

A Study on the Dyeing Method of Silk/Polyester Blend Fabrics (견/Polyester 혼방직물의 염색에 관한 연구)

  • Park, Hyun-Tea;Song, Mi-Kyoung;Kim, Gong-Ju
    • Textile Coloration and Finishing
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    • v.3 no.2
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    • pp.16-24
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    • 1991
  • The textile fabric have the functions of sanitation, decoration, wearing style and washing in the practical use. Among various texitle fiber, silk has less utilities than synthetic fiber in practical use although silk has good benefits of the high quality. Thus no textile fiber, neither natural nor synthetic, has all the functions. In this sence, many blend yarns have been improved various functions of fabric. However, this has been disturbed with the problem of dyeing, especially in the case of blend fabric of silk. In this study, we dyed silk/PET blend fabric in one step useing one bath dyeing method by acid dyes/disperse dyes. The results of the experiments can be summarized as follows; 1) Yellow index of silk fabric treated at $130^{\circ}C$ increased about 7.8 (color difference 4.5 NBS) and whiteness decrease about 5%. 2) Both elongation and tensile strength of silk fabric treated at $130^{\circ}C$ of pH 5-6 decreased about 10% and tensile strength of silk spun yarn treated at $60^{\circ}C$ of pH 10 have little changed. 3) While silk/PET blend frbric dyeing, silk soiling of disperse dyes causes from difference of dyeing rate and degree of silk soiling with dyes. 4) Fastness and soiling of silk/PET blend fabric dyed by one bath dyeing method of acid dyes/disperse dyes was same as two bath dyeing method.

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Dyeing Properties of Nylon 6 and Polyester Fabrics with Vat Dyes - Effect of Composition of Reducing Agent and Alkali on Color Change - (배트염료에 의한 나일론과 폴리에스테르 섬유의 염색성 - 색상 변화에 미치는 하이드로슬파이트와 NaOH의 영향 -)

  • ;;;Tomiji Wakida
    • Textile Coloration and Finishing
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    • v.14 no.5
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    • pp.284-293
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    • 2002
  • Nylon 6 and polyester taffeta fabrics are dyed in aqueous medium with vat dyes such as Indanthren Red FBB, Mikethren Blue ACE and Mikethren Blue HR varying the compositions of sodium hydrosulfite and NaOH. Also nylon UMF nonwoven and polyester UMF knitted fabrics are dyed with metal complex and disperse dyes as a reference, and the wash and rubbing fastnesses for these dyes are investigated. In vat dyeing of polyester and nylon taffeta, an optimum composition of sodium hydrosulfite/NaOH is existed at a range of 1∼2wt%/0.2wt%. A good build-up property for Mikethren Blue ACE on nylon 6 UMF nonwoven fabric is shown at high temperature. Vat dyeing of polyester with Mikethren Blue Ace shows a good color shade in a higher temperature, while dyeing with Mitsui Blue HR shows low temperatures. Vat dyes In dyeing of both nylon 6 UMF nonwoven and polyester UMF knitted fabrics have a better wash fastnesses compared with metal complex or disperse dyes.

Synthesis of Azo based Disperse Dyes for Dyeing Polyester Fiber in Supercritical Carbon Dioxide (초임계 유체 염색용 아조계 분산염료 합성 및 PET 섬유에 대한 염색 특성 연구)

  • Shin, Seung-Rim;An, Kyoung-Lyong;Lee, Sunhye;Lee, Seung Eun;Ko, Eunhee;Kim, Changil;Jun, Kun
    • Textile Coloration and Finishing
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    • v.31 no.3
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    • pp.135-146
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    • 2019
  • A series of azo based disperse dyes were synthesized and applied to polyester(PET) fiber in supercritical carbon dioxide($ScCO_2$). Various aniline derivatives were used as diazo component and coupled with glycine ethylester or carbonic acid ethylester derivatives to give azo based disperse dyes. Depending on the various diazo substituents, absorption maxima varied from 415 to 529nm in acetone. Dyeing in $ScCO_2$ was carried out at $120^{\circ}C$ and 250bar pressure for 2hrs with 0.5% o.w.f. of dye concentration. Dyed PET fiber had excellent brightness and good light, washing and perspiration(acid/alkali) fastness properties.

The dyeability and light fastness of amino azobenzene derivatives disperse dye( I ) (아미노 아조벤젠계 분산염료의 염색성 및 내광성(I))

  • Choi, Chang Nam;Lim, Seung Hee;Ryu, Hee Seok;Park, Hyung In;Hong, Sung Hak
    • Textile Coloration and Finishing
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    • v.8 no.3
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    • pp.24-30
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    • 1996
  • In order to investigate the light fastness of amino azo disperse dyes, some kinds of disperse dyes were prepared and dyed to polyester fabric under the different conditions, such as single or mixture state. After the dyed fabric was irradiated with carbon arc light for several hours, the color differences and K/S values of fabric were measured. The light fastness of amino azo disperse dye was decreased by the introduction of OH group to the dye molecule. But when the amino azo dye was mixed with the anthraquinone disperse dye, the light fastness was increased. It was considered that the dye molecules were aggregated on account of hydrogen bonding via OH groups, resulting the decrease of surface area of dye molecule which might be irradiated by the light.

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Dyeing of Cotton/Polyester Blends with Disperse Dyes and Crosslinking Agent - The Changes of Physical Properties and Colorfastness - (가교제와 분산염료를 이용한 면/폴리에스테르 혼방직물의 염색 - 그에 따른 물성 변화 및 염색견뢰도 -)

  • 김은아;유효선
    • Journal of the Korean Society of Clothing and Textiles
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    • v.26 no.10
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    • pp.1401-1411
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    • 2002
  • To Save energy and cost one bath/one step dyeing and finishing on cotton/polyester blends is carried out with disperse dyes in the presence of crosslinking agent. Cotton 100 %, cotton/polyester 70/30, 50/50, 35/65, polyester 100 % fabrics were used. wrinkle recovery angle, tensile strength retention and tearing strength retention were determined in according to the dyebath composition, and also determined while the concentration of DMDHEU, molecular weight and concentration of PEG were varied. Colorfastness to abrasion, washing and light were tested. For cotton and cotton/polyester blends dyed in the presence of DMDHEU/PEG, wrinkle recovery was improved. Tensile strength retention and tearing strength retention were decreased, in compared with dyed fabrics without DMDHEU. Colorfastness to abrasion was good but colorfastness to washing and to light were poor for the fabrics dyed in the presence of DMDHEU/PEG.

Dyeing Study on DMF-Modified Polyesters for Morphology Characterization

  • Park, Myung-Ja
    • The International Journal of Costume Culture
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    • v.5 no.2
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    • pp.53-65
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    • 2002
  • Morphology of polyester fiber was physically modified by solvent treatment. PET fiber was treated with N,N-dimethylformamide (DMF) at 100, 120, $140^{circ}C$ for 10 minutes without tension. The structural changes in the morphology of DMF-induced modified PET fiber were FTIR and SEM analysis. Also dyeing behavior of DMF-treated polyester fibers with various disperse dyes was studied to detect changes of amorphous area in fine structure. DMF treatment resulted in increases in total void content, degree of crystallinity, trans isomer content, chain folding, segmental mobility and molecular packing, but it resulted in decreases in amorphous orientation, intermolecular forces and individual void size through longitudinal shrinkage, lateral welling and removal of oligomers. Void-size distribution could be estimated from the dye uptake with various sizes of disperse dyes. In contrast to the large increases in dye uptake with small dye molecules, there is no and little dye uptake with the bulkiest dye, which means that void size is bigger or smaller than the volume of each dye. Diffusion rates of dye molecules showed increases. This dyeing study revealed that the disperse dyeing is very effective method for characterizing the internal morphology of polyester fiber.

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A Study on Dyeing Ability of Aramid(Nomex) Spun Yarn in Supercritical Carbon Dioxide using Disperse dyes (초임계 이산화탄소에 의한 아라미드(Nomex) 방적사의 분산염료에 대한 염색성에 관한 연구)

  • 용관중;박영환;김한석;유기풍;김인회;남성우
    • Textile Coloration and Finishing
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    • v.15 no.2
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    • pp.93-101
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    • 2003
  • To acquire dyeing ability on aramid(Nomex) spun yarn in supercritical fluid dyeing, supercritical fluid dying(SFD) machine of 3L scale was designed. C. I. Disperse Red 60 and Red 360 were used in this work. It was possible to increase dyeing ability and to get level dyeing of fiber by attaching assistance devices(controlling device of supercritical fluid, nozzle, cover of carrier, etc.) to SFD machine. Physical properties(tensile strength, elongation, shrinkage) of Nomex spun yam treated by SFD were not changed. K/S values of dyed Nomex spun yam with Red 360 were higher than that with Red 60 and color fastness of dyed Nomex spun yam by SFD was similar to that by conventional dyeing method.

Washing Fastness of Polyester Artificial Suede Fabric According to Reduction Clearing Method (환원세정방법에 따른 스웨드 직물의 세탁견뢰도)

  • 강연희;백진주;서말용;김삼수;허만우;이난형
    • Textile Coloration and Finishing
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    • v.13 no.4
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    • pp.234-240
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    • 2001
  • In order to improve the washing fastness of dyed polyester artificial suede fabric, it was dyed by using auto and anthraguinone type disperse dyes and treated with 3 different reduction clearing methods. The reduction clearing methods used in this study were normal alkaline reduction clearing, $N_2$ gas replacement method, and ultrasonic treatment during normal reduction clearing. The results were as followings ; The washing fastness property of dyed polyester artificial suede fabric was slightly improved by reduction clearing with $N_2$ gas replacement or with ultrasonic treatment comparing with normal alkaline reduction clearing. It was found that the use of $N_2$ gas replacement or ultrasonic treatment during reduction clearing eave effective removal of unfixed dyes on the fiber surface. We also obtained that the azo type disperse dye on polyester artificial fabric suede fabric showed higher wash fastness than anthraquinone type disperse dye.

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