• Title/Summary/Keyword: Disperse dyeing

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Organic Solvent Dyeing(II) -The Dyeing of PET by C. I. Disperse Violet 1 in Alkanes as Dyeing Media- (유기용매염색(II) -Alkane류를 염색매체로 한 C. I. Disperse Violet 1에 의한 PET 염색-)

  • 김태경;허재원;김병인;임용진
    • Textile Coloration and Finishing
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    • v.10 no.1
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    • pp.25-32
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    • 1998
  • In the prior study, we found that the dye uptakes of C. I. Disperse Violet 1 on PET in hexane and cyclohexane were higher than those in the other solvents. Therefore, in this study, the dye uptakes and the partition coefficients in alkanes having different number of carbon atoms were obtained and their relationship to the solubilities of the dye in alkanes was also investigated. As the number of carbon atoms of alkanes increases, solubility of the dye increases but the dye uptake decreases. This is due to the fact that the hydrophobicity of alkanes become relatively strong as increasing the number of carbon atoms. It was also found that the dye uptakes in iso-alkanes were larger than those in normal alkanes. This is because that the branched alkanes(iso-alkanes), judging from the tendency of lowering solubility and increasing dye uptake as decreasing the number of carbon atoms of alkanes, behave like the alkanes with less number of carbon atoms rather than the alkanes with the same number of carbon atoms. The logarithmic plot of the dye uptakes vs. the solubilities of the dye showed that the dye uptakes are linearly and inversely proportional to the solubilities. This is in good accordance with the results of the prior study. The heat of dyeing was also calculated from the equilibrium adsorptions at various temperatures. It seemed that the dyeings of PET by C. I. Disperse Violet 1 in nonane, decane, iso-pentane and iso-octane were rather endothermic processes. Dyeing rates in alkanes were somewhat delayed unlike general appearances in solvent dyeing.

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A Study on the Dyeing of Polyester Fiber in Alkaline Dyebath ―Dyeing Properties of Disperse dyes According to variation of pH values― (폴리에스테르섬유의 알칼리욕염색에 관한 연구 -pH변화에 따른 분산염료의 염색성을 중심으로-)

  • Sung, Woo Kyung;Ryu, Ki Hyo;Park, Soo Min;Kim, Kyung Hwan
    • Textile Coloration and Finishing
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    • v.8 no.1
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    • pp.34-42
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    • 1996
  • This Study was made to investigate alkaline dyeing systems for a new dyeing applicable polyester fibers. Disperse dyes for dyeing of polyester fibers were C.I. Red 60, Blue 56 and Yellow 54 as three primary colors of E type which used widely on the scene. Dyeing properties of dispers dyes on the polyester fibers are discussed according to variation of pH values for application of alkaline dyeing method compared with to ordinary acidic dyebath. Alkaline pH of the dyebath was controlled to pH 9 and 10.5 with buffer solutions using each hydrochloride and disodiumtetraborate, disodiumtetraborate and sodium hydroxide to promote the reproducibility of dyeing. Dyeing properties of dispers dyes on the polyester fibers by alkaline dyeing method compared with to ordinary acidic dyebath were discussed by estimation of color, wash-fastness, bleeding and migration of dyed polyester fabric.

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Dyeing Performance of Disperse Dyes Based on 2-aminothiazole for Cellulose Triacetate and Nylon Fibers

  • Maradiya, Hari-Raghav;Patel, Vithal-Soma
    • Fibers and Polymers
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    • v.3 no.1
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    • pp.43-48
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    • 2002
  • A series of monoazo disperse dyes based on 2-amino-4-phenylthiazole was prepared using various N,N-dialkvlaniline derivatives as the coupling component. The dyes were characterized by IR spectral studies, visible absorption spectroscopy and elemental analysis. The dyeing performance of these dyes was assessed on cellulose triacetate and nylon fibers. These dyes were found to give a wide range of colour shades varying from bright red to royal blue with very good depth, brightness and levelness on fibers. The dyed fibers showed good to very good light fastness and very good to excellent fastness to washing, perspiration, rubbing and sublimation. The dyebath exhaustion and fixation on the fibers were found to be very good.

Preparation and Characterization of Microcapsule for non-aqueous dyeing (비수계 염색용 마이크로캡슐의 제조 및 성질)

  • 최창남;박원규;변수진;이기영
    • Textile Coloration and Finishing
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    • v.15 no.5
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    • pp.327-332
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    • 2003
  • In this study, the polyurethane microcapsules for non-aqueous dyeing containing iron oxide and disperse dyes were prepared by in-situ polymerization method using hexamethylene diisocyanate(HDI) with ethylene glycol(EG). And the size, shape, and particle size distribution of microcapsules prepared were investigated. The size and shape of microcapsule were observed by optical microscope and scanning elecron microscope. The particle size distribution was analyzed by particle size analyzer. The microcapsule size and its distribution were largely effected by the existance of surface active agent in the system. When a surfactant did not exist in the system, the size distribution of microcapsules prepared was much uneven. By adding a surfactant, this phenomenon was disappeared. And the size of microcapsule was also effeced by the hydrophobicity of core material(disperse dye). It was considered due to the difference of dispersity of core materials. And the size of microcapsule prepared was inversely proportional to the stirring speed.

Dyeing Properties of Polyurethane Fiber by Novel Phthalimidyl Azo Disperse Dyes (Phthalimide계 신규 Azo dye의 Polyurethane계 섬유 염색 특성)

  • Choi, Jong-Yun;Choi, Jae-Hong
    • Textile Coloration and Finishing
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    • v.21 no.6
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    • pp.46-55
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    • 2009
  • Some phthalimidyl azo dyes containing N,N-diethyl or N,N-di($\beta$-methoxycarbonylethyl) group have been attempted to apply onto two kinds of polyurethane based materials and rationalize their dyeability and fastness comparing with those of some commercial disperse dyes. Phthalimidyl azo dye showed 66~98% of exhaustion yield at $120^{\circ}C$ by a conventional exhaust dyeing method. The dyeings were found to have a higher wash fastness with both fabrics in comparison with those of commercial dyes which indicates lower thermomigration and efficient alkali clearable properties of phthalimidyl ring and/or diester group during post-dyeing process.

Reduction Cleaning and Thermomigration Effects on Micro Polyester SUEDE (극세 폴리에스테르 스웨드의 환원세정과 열이행의 영향)

  • Choi, Kyung-Yeon;Han, Sam-Sook;Lee, Mun-Cheul
    • Textile Coloration and Finishing
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    • v.21 no.6
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    • pp.12-21
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    • 2009
  • The dyeing property of direct-spinning type and seaisland type 0.2D micro polyester nonwoven fabrics was characterized by three disperse dyes (Dorosperse Red KFFB, Blue KGBR, Yellow KRL) at $120^{\circ}C$ and $130^{\circ}C$. Before and after reduction cleaning, dyeing fastness was evaluated and the thermomigaration after heat setting at $180^{\circ}C$ for 60 min were also evaluated. Direct-spinning type fabric showed better dyeing property, wash fastness, and light fastness, but worse rub fastness than seaisland type fabric. The dyeing property and fastness of direct-spinning type fabric increased at higher dyeing temperature, whereas seaisland type fabric exhibited lower dyeing fastness and the increase of thermomigration at higher dyeing temperature. Non-fixed dye in fiber surface was removed by reduction cleaning process, then dyeing fastness was improved and thermomigration decreased. The higher dye uptake of direct-spinning type non-woven fabric caused the increase of dye molecule migration from fiber internal to fiber surface, so this fabric showed larger thermomigration than seaisland type non-woven fabric.

Dyeing Properties on Jacquard Fabric for Blind Using Low-melting Flame Retardant Polyester (저융점 난연 폴리에스터를 이용한 블라인드용 자카드 직물의 염색성)

  • Kim, Jeong-Hwa;Lee, Jung Soon;Lee, Sung-Young;Lee, Seung-Gu
    • Journal of the Korean Society of Clothing and Textiles
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    • v.38 no.3
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    • pp.404-414
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    • 2014
  • This study investigates the dyeability and fastness of jacquard fabric for blind using low-melting flame retardant polyester. Two types of jacquard fabric were prepared with a low-melting flame retardant polyester and regular polyester. The low-melting flame retardant polyester has a sheath and a core. The core consists of flame retardant polyester and the sheath consists of low-melting polyester. Disperse red 50 (DR 50), disperse blue 56 (DB 56), disperse yellow (DY 54) of E-type dyes and disperse 92 (DR 92), disperse blue 60 (DB 60), disperse yellow (DY 79) of S-type dyes were used and dyed on jacquard fabrics dependent of dyeing temperature and time. The fastness, dye exhaustion, color strength (K/S value), and colorimetric properties of jacquard fabrics were evaluated. The dyeability of S-type dyes were higher than E-type dyes. The experiments indicated optimum dyeability that the dyeing temperature was $110^{\circ}C$ for E-type dyes and $120^{\circ}C$ for S-type dyes for 40 minutes. The fastness to washing and light were excellent at a 4-5 grade.

Dyeing Properties of Nylon 6 Ultramicrofiber (나일론 6 초극세 섬유의 염색성)

  • ;;;Tomiji Wakida
    • Textile Coloration and Finishing
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    • v.14 no.6
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    • pp.319-327
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    • 2002
  • Nylon 6 ultramicrofiber(UMF, monodenier 0.074d) and regular staple fiber(monodenier 2.05d) were dyed with acid and disperse dyes to investigate the effect of the difference of the fiber fineness. Also X-ray diffraction pattern, birefringence, DSC thermogram, moisture regain and water absorption of these fibers are measured. The dyeing rate of nylon UMF with acid dyes is increased compared with that of regular fiber, but not increased for disperse dyes. Also the saturation dye uptake of UMF with acid dyes is higher than that of regular fiber, while it is unchanged for disperse dyes. The moisture regain of UMF is similar to the regular fiber, whereas the water absorption of UMF is two times th그n that of the regular fiber. The crystallinity percentage of UMF is higher than that of regular fiber.

Relationship between Substituents of Aminoazobenzene Disperse Dyes and Dyeing Properties (아미노아조벤젠계 분산염료의 치환기와 염색성과의 관계)

  • Kim, Sung Dong;Kwak, Tae Soo;Lee, In Yeol
    • Textile Coloration and Finishing
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    • v.9 no.6
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    • pp.1-9
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    • 1997
  • Four aminoazobenzene disperse dyes derived from different N-ethyl-N-substitutedalkylanilines and 2-chloro-4-nitroaniline, were synthesized and their chemical structure were analyzed by 500 MHz NMR spectroscopy. The wavelength of maximum absorption of the synthesized dyes, which was dependent on the electron withdrawing ability of the substituent, was in the range of 499.5~526.0nm. As terminal substituent became polar, the dyeing rate of disperse dye increased, and the exhaustion rate of dyes having cyano or hydroxy group became lower, that of the dye having acetoxy group higher. The wash fastness of polyester fabric dyed with disperse dyes possessing the polar group improved probably due to the increased dye-fiber interaction.

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