• Journal of the Korean Electrochemical Society
• /
• v.11 no.2
• /
• pp.120-124
• /
• 2008

Carbon-coated $LiFePO_4$ and $LiMn_{0.4}Fe_{0.6}PO_4$ cathode materials for lithium batteries were synthesized by a sol-gel method. X-ray diffraction and scanning electron microscopy data showed that the cathode materials are pure crystalline and are surrounded by porous carbon. The initial discharge capacities of $LiFePO_4$ and $LiMn_{0.4}Fe_{0.6}PO_4$ with the liquid electrolyte of 1M $LiPF_6$ in EC/DMC are 132 mAh/g and 145 mAh/g, respectively, at current density of 0.1 C-rate. $LiFePO_4$ and $LiMn_{0.4}Fe_{0.6}PO_4$ with an electrospun polymer-based electrolyte exhibit initial discharge capacities of 114 and 130 mAh/g at 0.1 C-rate at room temperature, respectively.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.32 no.4B
• /
• pp.221-232
• /
• 2012

In this study, the model enhancing the safety of reservoirs and reducing the downstream flood damage by reservoirs system operation during abnormal flood was developed. Linear programming was used for the optimal reservoirs system operation during an abnormal flood and fuzzy inference system was introduced to solve the uncertainty problem which is included in hydrological factors like inflow, water level and inflow variation of reservoir operation. The linear programming model determined the optimal reservoir system operation rules and could be used in situation where water demands varies rapidly during the abnormal flood events using fuzzy control technique. In this study, the optimal reservoirs system operation for Andong and Imha reservoirs located in the upper basin of Nakdong river was performed in order that the design flood discharge at Andong city would not be exceeded for the design flood of 100 year and PMF(Probable Maximum Flood). And the model that determines the release according to the downstream flow discharge, the reservoir storage, the inflow and the inflow variation of each reservoir was developed using the optimal system operation result and fuzzy control technique. The developed model consisted of 224 fuzzy rules according to the conditions of Andong reservoir, Imha reservoir and Andong city. And the release from each reservoir could be determined when the current data are used as input data through the developed GUI.

• Journal of Wetlands Research
• /
• v.14 no.1
• /
• pp.89-99
• /
• 2012

This study aims to develop the Masan bay special management system of the point and nonpoint sources of pollution using GIS as part of the Integrated Management System of the Masan Bay Special Management Area and utilize Total Pollution Loads Management System in Masan Bay more systematically and scientifically. The result of the pollution sources management at the Masan bay in conjunction with GIS was made possible the comparison of the source of pollution and the pollutant load among each administration area. It also developed Arc-GIS watershed management program which enables to estimate the population for discharge facilities, the water use of domestic population and commercial population, and pollutant load and discharge load of COD, TN and TP by the administration areas, years, and usages. In addition, this study anticipated minimizing temporal, economical efforts in utilizing large amounts of property and space utilization data and expediting the decision making process of policies in relation to the systematic and effective management system of pollutant loads at the Masan bay area. Further studies are required to plan the systematic management of the point and nonpoint sources of pollution and complement the watershed management system using GIS program for pollutant load which enables to predict the current and future state of point and nonpoint sources.

• Journal of Korea Water Resources Association
• /
• v.42 no.8
• /
• pp.643-657
• /
• 2009

The major reason to construct large dams is to store surplus water during rainy seasons and utilize it for water supply in dry seasons. Reservoir storage has to meet a pre-defined target to satisfy water demands and cope with a dry season when the availability of water resources are limited temporally as well as spatially. In this study, a Hedging rule that reduces total reservoir outflow as drought starts is applied to alleviate severe water shortages. Five stages for reducing outflow based on the current reservoir storage are proposed as the Hedging rule. The objective function is to minimize the total discrepancies between the target and actual reservoir storage, water supply and demand, and required minimum river discharge and actual river flow. Mixed Integer Linear Programming (MILP) is used to develop a multi-reservoir operation system with the Hedging rule. The developed system is applied for the Han River basin that includes four multi-purpose dams and one water supplying reservoir. One of the fours dams is primarily for power generation. Ten-day-based runoff from subbasins and water demand in 2003 and water supply plan to water users from the reservoirs are used from "Long Term Comprehensive Plan for Water Resources in Korea" and "Practical Handbook of Dam Operation in Korea", respectively. The model was optimized by GAMS/CPLEX which is LP/MIP solver using a branch-and-cut algorithm. As results, 99.99% of municipal demand, 99.91% of agricultural demand and 100.00% of minimum river discharge were satisfied and, at the same time, dam storage compared to the storage efficiency increased 10.04% which is a real operation data in 2003.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.4 no.1
• /
• pp.87-93
• /
• 2006

Inventories, and characteristics such as dimension, fuel rod array, weight, $^{235}U$ enrichment, and discharge burnup of spent nuclear fuel (SNF) generated from existing and planed nuclear power plants based on National 2nd Basic Plan for Electric Power Demand and Supply were investigated and projected to support geological disposal system design. The historical and projected inventory by the end 2057 is expected to be 20,500 and 14,800MTU for PWR and CANDU spent nuclear fuel, respectively. The quantity of SNF with initial $^{235}U$ enrichment of 4.5 wt.% and below was shown to be 96.5% in total. Average burnup of SNF revealed $\sim36$ GWD/MTU and $\sim40$ GWD/MTU for the period of 1994-1999 and 2000-2003, respectively. It is expected that the average burnup of SNF will be $\sim45$ GWD/MTU at the end of 2000's. From the comprehensive study, it was concluded that the imaginary SNF with $16\times16$ Korean Standard Fuel Assembly, cross section of $21.4cm\times21.4cm$, length of 453cm, mass of 672 kg, initial $^{235}U$ enrichment of 4.5 wt.%, discharge burnup of 55 GWD/MTU could cover almost all SNFs to be produced by 2057.

• Carbon letters
• /
• v.28
• /
• pp.31-37
• /
• 2018

This paper examines a simple one-step and catalyst-free method for synthesizing carbon nanoparticles from aliphatic alcohols and n-hexane with linear molecule formations by using a stable solution plasma process with a bipolar pulse and an external resistor. When the external resistor is adopted, it is observed that the current spikes are dramatically decreased, which induced production of a more stable discharge. Six aliphatic linear alcohols (methanol-hexanol) containing carbon with oxygen sources are studied as possible precursors for the massive production of carbon nanoparticles. Additional study is also carried out with the use of n-hexane containing many carbons without an oxygen source in order to enhance the formation of carbon nanoparticles and to eliminate unwanted oxygen effects. The obtained carbon nanoparticles are characterized with field emission-scanning electron microscopy, energy dispersive X-ray spectroscopy, and Raman spectroscopy. The results show that with increasing carbon ratios in alcohol content, the synthesis rate of carbon nanoparticles is increased, whereas the size of the carbon nanoparticles is decreased. Moreover, the degree of graphitization of the carbon nanoparticles synthesized from 1-hexanol and n-hexane with a high carbon (C)/oxygen (O) ratio and low or no oxygen is observed to be greater than that of the carbon nanoparticles synthesized from the corresponding materials with a low C/O ratio.

• Journal of the Korean Electrochemical Society
• /
• v.15 no.1
• /
• pp.19-26
• /
• 2012

SEI (solid electrolyte interphase) layers are generated on a graphite negative electrode from three different electrolytes and low-temperature ($-30^{\circ}C$) charge/discharge performance of the graphite electrode is examined. The electrolytes are prepared by adding 2 wt% of vinylene carbonate (VC) and fluoroethylene carbonate (FEC) into a standard electrolyte solution. The charge-discharge capacity of graphite electrode shows the following decreasing order; FEC-added one>standard>VC-added one. The polarization during a constant-current charging shows the reverse order. These observations illustrate that the SEI film resistance and charge transfer resistance differ according to the used additives. This feature has been confirmed by analyzing the chemical composition and thickness of three SEI layers. The SEI layer generated from the standard electrolyte is composed of polymeric carbon-oxygen species and the decomposition products ($Li_xPF_yO_z$) of lithium salt. The VC-derived surface film shows the largest resistance value even if the salt decomposition is not severe due to the presence of dense film comprising C-O species. The FEC-derived SEI layer shows the lowest resistance value as the C-O species are less populated and salt decomposition is not serious. In short, the FEC-added electrolyte generates the SEI layer of the smallest resistance to give the best low-temperature performance for the graphite negative electrode.

• Journal of radiological science and technology
• /
• v.33 no.3
• /
• pp.269-276
• /
• 2010

This study attempts to propose ways to optimize and improve the period of hospitalization for the radioiodine treatment by calculating the dose rate of patients treated with high-dose radioiodine by distance and time slot. As a result, 24 hours after the patient was treated with 100 mCi high-dose iodine, the dose rate was attenuated to $1,035{\mu}Sv/hr$ at the navel, to $109{\mu}Sv/hr$ at 50 cm, and to $33{\mu}Sv/hr$ at 100 cm. 24 hours after the patient was treated with 150 mCi high-dose iodine, the dose rate was attenuated to $637{\mu}Sv/hr$ at the navel, to $100{\mu}Sv/hr$ at 50 cm, and to $40{\mu}Sv/hr$ at 100 cm. 24 hours after the patient was treated with 180 mCi high-dose iodine, the dose rate was attenuated to $1,251{\mu}Sv/hr$ at the navel, $140{\mu}Sv/hr$ at 50 cm, and to $56{\mu}Sv/hr$ at 100 cm. In light of the current criterion for discharge recommended by the US Nuclear Regulatory Commission being $70.4{\mu}Sv/hr$, the present study indicates earlier discharge is feasible by applying a new scheme. This suggests that the proposed scheme in this study will help to solve the problem of shortage of treatment beds with the increasing trend of patients with thyroid cancer taken into consideration.

• Membrane Journal
• /
• v.30 no.5
• /
• pp.307-318
• /
• 2020

Conventional perfluorinated sulfonic acid membrane, Nafion is widely used for vanadium redox flow battery (VRFB). It is desired to prevent vanadium ion permeation through a membrane to retain the capacity, and to keep the cell efficiency of a VRFB. Highly proton conductive and chemically stable Nafion membranes, however, suffer from high vanadium permeation, which induce the reduction in charge and discharge capacity by side reactions of vanadium ions. In this study, to resolve the issue, silica nanoparticles, which are functionalized with 3-aminopropyl group (fS) are introduced to enhance the long-term performance of a VRFB by lowering vanadium permeation. It is expected that amine groups on silica nanoparticles are converted to positive ammonium ion, which could deteriorate positively charged vanadium ions' crossover by Gibbs-Donnan effect. There is reduction in proton conductivity may due to acid-base complexation between fS and Nafion side chains, but ion selectivity of proton to vanadium ion is enhanced by introducing fS to Nafion membranes. With the composite membranes of Nafion and fS, VRFBs maintain their discharge capacity up to 80% at a high current density of 150 mA/㎠ during 200 cycles.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.16 no.10
• /
• pp.6466-6474
• /
• 2015

The purpose of this study is to indicate the problem and its improvement plan derived from pollution discharge industries inspection, implementation process on overall instruction including record management, and utilization of information about emission. This focuses on analyzing the inspection system of pollution discharge industries and the actual condition of management system with survey and interview from the managers. As a result of examining the administration information system from each of structural and practical perspectives, the users were not able to receive support for inspection through the system because it was designed based on licensing. Also according to results of survey and interview, it was difficult to input checkup data and to maintain the information of emission in a sustainable manner. This problem occurs since the current system is not utilized properly. Thus, this study examines similar systems operated in Korea and suggests measure to make improvements. The measures are considered as constructing simple user interface for systematizing of administrative works, simplifying the input matters, linking systems of inspection and emission information, establishing statistical function of emission information, and managing inspection functions through the mobile system.