• 제목/요약/키워드: Diffusion study

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Ti-6Al-4V 샌드위치 패널제작을 위한 초소성/확산접합 기술개발 (Development of Superplastic Forming/Diffusion Bonding Technology for Ti-6Al-4V Sandwich Panels)

  • 이호성;윤종훈;이승철;박동규;이영무
    • 한국군사과학기술학회지
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    • 제11권3호
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    • pp.123-128
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    • 2008
  • Ti-6Al-4V alloy is a critical strategic metal used in aerospace structure due to the high specific strength, toughness, durability, low density, corrosion resistance. Examples of application of this alloy are airframe structural components, aircraft gas turbine disks and blades. Forming of this alloy is not easy due to its high strength and low formability. However, this alloy shows superplastic properties that allow for large plastic deformation under certain conditions. Combination of superplastic forming and diffusion bonding(SPF/DB) processes of this alloy has been widely used to replace mechanically fastened structures with reduced weight and fabrication costs. In this study, superplastic forming/diffusion bonding technology has been developed for fabricating lightweight sandwich panels with Ti-6Al-4V alloy. The experimental results show the forming of titanium lightweight sandwich structure is successfully performed from 3 and 4 sheets of Ti-6Al-4V.

하천 오염물질의 모의를 위한 프랙탈 이송확산방정식의 해석적 유도 (The Analytical Derivation of the Fractal Advection-Diffusion Equation for Modeling Solute Transport in Rivers)

  • 김상단;송미영
    • 한국수자원학회논문집
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    • 제37권11호
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    • pp.889-896
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    • 2004
  • 프랙탈 이송확산방정식은 정수 차수의 미분연산자로 구성된 고전적인 이송확산방정식과 비교하여 프랙탈 차수의 미분연산자로 구성된 보다 상위개념의 방정식으로써 정의된다. 지금까지의 프랙탈 이송확산방정식은 추계학적인 기법을 동원하여 푸리에-라플라스 공간에서 주로 해석되었으나, 본 연구에서는 실제 공간에서 유한차분개념을 도입하여 보다 직접적으로 하천에서의 오염물 이송확산에 관한 지배방정식을 유도하였다. 이러한 개념의 유도방법은 프랙탈 차수 및 관련 확산계수의 물리적인 추정에 관한 실마리를 제공할 수 있다. 고전적인 이송확산방정식과는 달리 프랙탈 이송확산방정식은 실제 하천에서 관측되는 오염물의 시간-농도 분포곡선의 왜곡현상과 분포곡선의 전후방부 농도를 보다 실제에 가깝게 모의할 수 있을 것으로 기대되어진다.

CCIGC 기법을 사용한 SBS/cyclic solvent 시스템에서의 확산계수 측정 및 해석 (Measurement and Analysis of Diffusivity for SBS/cyclic Solvent Systems Using CCIGC Technique)

  • 김지의;홍성욱
    • 공업화학
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    • 제25권2호
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    • pp.147-151
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    • 2014
  • 많은 고분자 공정에서 고분자에서의 유기 용매와 같은 저분자 물질의 확산은 중요하다. 고분자에서의 저분자 물질의 이동은 중합 반응기의 효율성과 제조된 고분자의 특성을 결정한다. 공정을 설계하고 최적화하는데 중요한 물성값은 고분자/용매 상호확산 계수이다. 용매의 농도가 매우 낮은 무한희석 상태에서의 고분자/용매 계의 무한확산계수를 측정하기 위해서 capillary column inverse gas chromatography (CCIGC) 기법이 흔히 사용된다. 이 기법을 사용하면 비교적 짧은 시간에 확산계수와 분배계수를 측정하는 것이 가능하다. 본 연구에서는 CCIGC 기법을 사용해서 styrene/butadiene/styrene (SBS) 블록 공중합체에서 환형 구조를 가지는 용매의 확산계수와 분배계수를 다양한 온도 범위에서 측정하였다.

이차이온질량분석기의 깊이 분포도를 이용한 동선의 열적 확산에 대한 연구 (Study of Thermal Diffusion in the Copper Wire Using SIMS Depth Profiling)

  • 박종진;홍태은;조영진;서영일;문병선;박종찬;박혁규;이정식
    • 한국화재소방학회논문지
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    • 제22권5호
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    • pp.43-47
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    • 2008
  • 최근에 이차이온질량분석기(Secondary Ion Mass Spectrometry)를 이용한 1 2차 용융흔 구별에 관한 연구가 많은 관심을 끌고 있다. 동선의 깊이 분포에 따른 $^{12}C^-$, $^{63}Cu^-$, $^{18}O^-$, $^{35}Cl^-$ 이차 이온을 검출하기 위해 Cs+ 일차 이온빔을 사용하였고, 본 논문에서는 과전류에 의한 동선의 열적 확산에 대해 분석하였다. 분석결과 PVC 절연피복이 덮인 동선이 보다 더 깊이 탄소와 염소가 확산함을 보였으나, 산소는 절연피복이 덮이지 않은 동선이 더 깊이 확산된 것을 보였다.

Thermal Stability of Self-formed Barrier Stability Using Cu-V Thin Films

  • 한동석;문대용;김웅선;박종완
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.188-188
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    • 2011
  • Recently, scaling down of ULSI (Ultra Large Scale Integration) circuit of CMOS (Complementary Meta Oxide Semiconductor) based electronic devices, the electronic devices, become much faster and smaller size that are promising property of semiconductor market. However, very narrow interconnect line width has some disadvantages. Deposition of conformal and thin barrier is not easy. And metallization process needs deposition of diffusion barrier and glue layer for EP/ELP deposition. Thus, there is not enough space for copper filling process. In order to get over these negative effects, simple process of copper metallization is important. In this study, Cu-V alloy layer was deposited using of DC/RF magnetron sputter deposition system. Cu-V alloy film was deposited on the plane SiO2/Si bi-layer substrate with smooth surface. Cu-V film's thickness was about 50 nm. Cu-V alloy film deposited at $150^{\circ}C$. XRD, AFM, Hall measurement system, and AES were used to analyze this work. For the barrier formation, annealing temperature was 300, 400, $500^{\circ}C$ (1 hour). Barrier thermal stability was tested by I-V(leakage current) and XRD analysis after 300, 500, $700^{\circ}C$ (12 hour) annealing. With this research, over $500^{\circ}C$ annealed barrier has large leakage current. However vanadium-based diffusion barrier annealed at $400^{\circ}C$ has good thermal stability. Therefore thermal stability of vanadium-based diffusion barrier is desirable for copper interconnection.

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Solid-state sintering mechanism of blended elemental Ti-6Al-4V powders

  • Kim, Youngmoo;Song, Young-Beom;Lee, Sung Ho
    • 한국분말재료학회지
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    • 제25권2호
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    • pp.109-119
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    • 2018
  • The objective of this study is to reveal the sintering mechanism of mixed Ti-6Al-4V powders considering the densification and the homogenization between Ti and Al/V particles. It is found that the addition of master alloy particles into Ti enhances densification by the migration of Al into the Ti matrix prior to the self-diffusion of Ti. However, as Ti particles become coarser, sintering of the powders appears to be retarded due to slower inter-diffusion of the particles due to the reduced surface energies of Ti. Such phenomena are confirmed by a series of dilatometry tests and microstructural analyses in respect to the sintering temperature. Furthermore, the results are also consistent with the predicted activation energies for sintering. The energies are found to have decreased from 299.35 to $135.48kJ{\cdot}mol^{-1}$ by adding the Al/V particles because the activation energy for the diffusion of Al in ${\alpha}-Ti$ ($77kJ{\cdot}mol^{-1}$) is much lower than that of the self-diffusion of ${\alpha}-Ti$. The coarser Ti powders increase the energies from 135.48 to $181.16kJ{\cdot}mol^{-1}$ because the specific surface areas of Ti decrease.

미고결 퇴적물의 지질공학적 특성에 대한 수치해석적 연구 (Numerical Analysis for the Geological Engineering Characteristics of Unconsolidated Sediment)

  • 조태진
    • 한국수산과학회지
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    • 제23권3호
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    • pp.215-224
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    • 1990
  • 포화상태인 물질의 역학적, 수리학적 거동을 연구할 수 있는 유한요소법적 수치해석모델을 개발하여 부산 남항 인근해역의 미고결 퇴적물의 거동을 분석하였다. 하중재하에 의한 상부세립 퇴적물의 역학적 변형은 공극수의 확산에 따른 공극수압의 수리학적 변화에 크게 영향을 받는 것으로 나타났다. 하중이 일정지역에 편재되어 있을 경우 포아송효과 및 과잉공극수압의 영향에 의해 하중을 직접 받지 않는 표층부분이 융기되며, 하중경계지역에서 멀어질수록 점근적으로 증가한다. 세립점토층에 비해 높은 투수성을 갖는 하부 모래층은 공극수확산의 통로역할을 하여 과잉공극수압의 소멸을 촉진시키며, 결과적으로 상부점토층 변형의 시간적 변화에도 영향을 끼친다.

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Analysis of radon depth profile in soil air after a rainfall by using diffusion model

  • Maeng, Seongjin;Han, Seung Yeon;Lee, Sang Hoon
    • Nuclear Engineering and Technology
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    • 제51권8호
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    • pp.2013-2017
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    • 2019
  • The radon concentrations in soil air were measured before and after a rainfall. 226Ra concentration, porosity, moisture content and temperature in soil were measured at Kyungpook National University in Daegu. As the results of measurement and analysis, the arithmetic mean of measured 222Rn concentration increased from 12100 ± 500 Bq/㎥ to 16200 ± 600 Bq/㎥ after the rainfall. And the measured 226Ra concentration was 61.4 ± 5.7 Bq/kg and the measured porosity was 0.5 in soil. The estimated values of 226Ra concentration and porosity using diffusion model of 222Rn in soil were 60.3 Bq/kg and 0.509, respectively. The estimated values were similar to the measured values. 222Rn concentration in soil increased with depth and moisture content. The estimations were obtained through fitting based on the diffusion model of 222Rn using the measurement values. The measured depth profiles of 222Rn were similar to the calculated depth profiles of 222Rn in soil. We hope that the results of this study will be useful for environmental radiation analysis.

혁신의 확산 혹은 혼란 - 스마트 의류 잠재적 채택자 관점 - (Diffusion or confusion of innovation - Smart clothing potential adopters' perspectives -)

  • 이규혜;주나안
    • 복식문화연구
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    • 제26권2호
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    • pp.157-171
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    • 2018
  • As the next generation of smartphone and tablet computers, wearable devices are currently being developed and available in market in various forms. Smart clothing is a wearable device that holds the greatest potential for future development but low in market penetration. This study was designed to identify factors that influence adoption and diffusion of smart clothing. In-depth interviews with potential consumers who were knowledgeable about and interested in smart clothing were conducted. A semantic network analysis method was used. The results showed that consumers perceived smart clothing as a garment rather than as a type of wearable device and had a positive perception of smart apparel as more convenient and advanced than functional apparel. At the same time, however, consumers had a negative perception of smart clothing as unnecessary, ugly, and injurious to health. Consumers also worried that wearing smart apparel over long periods of time would negatively impact their health. Factors affecting resistance to smart apparel included low utility, perceived risk, and lack of aesthetic completeness. Usefulness and convenience were factors that affected the acceptance of smart clothing. The innovativeness of the product was more influential than consumer innovativeness in the process of adoption and diffusion of smart clothing.

The Influence of Mechanical Milling on the Structure and Magnetic Properties of Sm-Fe-N Powder Produced by the Reduction-Diffusion Process

  • Lee, Jung-Goo;Kang, Seok-Won;Si, Ping-Zhan;Choi, Chul-Jin
    • Journal of Magnetics
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    • 제16권2호
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    • pp.104-107
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    • 2011
  • In the present study, we systematically investigated the effect of mechanical milling on the magnetic properties of $Sm_2Fe_{17}N_x$ powders produced by the reduction-diffusion process. The Sm-Fe powders obtained by the reduction-diffusion process were composed of an $Sm_2Fe_{17}N_x$ single phase. After nitrogenation, the coercivity and saturation magnetization of the powders were 0.48 kOe and 13.32 kG, respectively. The particle size largely decreased down to less than $2\;{\mu}m$ in diameter after ball milling for 30 hours. However, there is no evidence that the $Sm_2Fe_{17}N_x$ was decomposed to Sm-N and ${\alpha}$-Fe even after ball milling for 30 hours. The coercivity was significantly improved up to 8.82 kOe after milling for 60 hours. However, the magnetization decreased linearly with the ball milling time.