• Title/Summary/Keyword: Diffusion loss

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Mass Transfer Characteristics in the Osmotic Dehydration Process of Carrots (당근의 삼투건조시 물질이동 특성)

  • Youn, Kwang-Sup;Choi, Yong-Hee
    • Korean Journal of Food Science and Technology
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    • v.27 no.3
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    • pp.387-393
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    • 1995
  • Diffusion coefficients of moisture and solid, reaction rate constants of carotene destruction, and the fitness of drying models for moisture transfer were determined to study the characteristics of mass transfer during osmotic dehydration. Moisture loss and solid gain were increased with increase of temperature and concentration; temperature had higher osmotic effect than concentration. Diffusion coefficient showed similar trend with osmotic effect. Diffusion coefficients of solids were larger than those of moisture because the movement of solid was faster than that of moisture at the high temperature. Reaction rate constants were affected to the greater extent by concentration changes than by temperature changes. Arrhenius equation was applied to determine the effect of temperature on diffusion coefficients and reaction rate constants. Moisture diffusion required high activation energy in $20^{\circ}Brix$, while relatively low in $60^{\circ}Brix$. To predict the diffusion coefficients and reaction rate constants, a model was established by using the optimum functions of temperature and concentration. The model had high $R^2$ value when applied to diffusion coefficients, but low when applied to reaction rate constants. Quadratic drying model was most fittable to express moisture transfer during drying. In conclusion, moisture content of carrots could be predictable during the osmotic dehydration process, and thereby mass transfer characteristics could be determined by predicted moisture content and diffusion coefficient.

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Study on Transient Response of a Unit Proton Exchange Membrane Fuel Cell with an Aged Gas Diffusion Layer (내구성능저하된 기체확산층이 고분자전해질 연료전지의 과도응답성능에 미치는 영향 연구)

  • Cho, Junhyun;Ha, Tahun;Park, Jaeman;Oh, Hwanyeong;Min, Kyoungdoug;Jyoung, Jy-Young;Lee, Eunsook
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.76.2-76.2
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    • 2010
  • The gas diffusion layer is the key component of the proton exchange membrane fuel cell because it directly affect to the mass transport mechanism and dynamic behavior of the cell. In this study, the effects of GDL aging on the transient response of the PEM fuel cell is systematically investigated using current step transient response analysis under different stoichiometric ratios and humidity conditions. With GDLs aged by the accelerated stress test, the effects of hydrophobicity and structural changes due to carbon loss in the GDL on the transient response of PEM fuel cells are determined. The degraded GDLs that had uneven hydrophobicity distributions cause local water flooding inside the GDL and induce lower and unstable voltage responses after load changes.

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Experimental Study on Carbon Corrosion of Gas Diffusion Layer in PEM Fuel Cell (고분자전해질형 연료전지 가스확산층의 탄소 부식에 관한 실험적 분석)

  • Ha, Taehun;Cho, Junhyun;Park, Jaeman;Min, Kyoungdoug;Lee, Eunsook;Jyoung, Jy-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.76.1-76.1
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    • 2010
  • Recently, many efforts to solve the durability problem of PEM fuel cell are carried on constantly. However, despite this attention, durability researches of gas diffusion layer (GDL) are not much reported yet. Generally, GDL of PEM fuel cell experiences three external attacks, which are dissolution of water, erosion of gas flow, corrosion of electric potential. In this study, among these degradation factors, carbon corrosion of electric potential was focused and investigated with accelerated carbon corrosion test. Through the test, it is confirmed that carbon corrosion occurred at GDL, and corroded GDL decreased a performance of operating fuel cell. The property changes of GDL were measured with various methods such as air permeability meter, pore distribution analyzer, thermo gravimetric analyzer, and tensile stress test to discover the effects of carbon corrosion. Carbon corrosion caused not only loss of weight and thickness, but also degradation of mechanical strength of GDL. In addition, to analysis the reason of GDL property changes, a surface and a cross section of GDL were observed with scanning electron microscope. After 100 hours test, the GDL showed serious damage in center of layer.

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Study on the Optimization of Superhydrophobic Coating for the Durability of Gas Diffusion Layer in Alkaline Fuel Cells (알카라인 연료전지 가스확산층 내구성 향상을 위한 초발수 코팅 최적화 연구)

  • Kim, Soong Yeon;Seo, Minhye;Uhm, Sunghyun
    • Applied Chemistry for Engineering
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    • v.28 no.6
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    • pp.691-695
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    • 2017
  • Optimization study was carried out to improve the durability of the gas diffusion layer (GDL) in alkaline fuel cell cathode by the use of highly stable PDMS superhydrophobic coating. Two different commercial GDLs were selected as substrates. Coating temperature and viscosity of PDMS were controlled for the stability of structure in microporous layer of GDL as well as uniform coating according to thermal characteristics of GDL. Regardless of PDMS viscosity, highly stable superhydrophobicities were obtained with both GDLs at $200^{\circ}C$. After the accelerated test, however, 28BC GDL coated with 1000 CS PDMS showed the best durability with the lowest loss of superhydrophobicity.

Synthesis of 58Ni Target and Co Diffused Rh Composite for Application of Mössbauer Source (뫼스바우어선원 적용을 위한 58Ni 표적체 및 Co가 확산된 Rh복합재 제조)

  • Uhm, Young Rang;Choi, Sang Mu;Kim, Jong-bum;Son, Kwang Jae
    • Journal of Powder Materials
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    • v.22 no.6
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    • pp.432-437
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    • 2015
  • The en-riched $^{58}Ni$ powders are dissolved in acid solution and coated on a Cu target for proton irradiation at cyclotron to produce $^{57}Co$ radioisotope. The condition of the plating bath and the coating process are determined using the en-riched powders. To establish the coating conditions for $^{57}Co$, non-radioactive Co ions are dissolved in an acid solution and electroplated on to a rhodium plate. The thermal diffusion of electroplated Co into a rhodium matrix was studied to apply a $^{57}Co$ Mssbauer source. The diffusion depth from surface to matrix of Co is depended on the annealing temperature and time. The deposited Co atoms diffuse completely into a rhodium (Rh) matrix without substantial loss at an annealing temperature of 1200 for 4 hours.

A study on wear damage of SKD11 steel material for a cutting mold jig (SKD11 절단금형치구용 소재의 마모손상에 관한 연구)

  • Nam, Ki-Woo;Kim, Cheol-Su;Ahn, Seok-Hwan
    • Journal of Power System Engineering
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    • v.20 no.5
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    • pp.5-13
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    • 2016
  • This study is on wear damage of the material for a molding machine that be used at finally cutting of metal beam made in roll forming process of vehicle bump beam process line. SKD11 steel was used with the material for cutting mold jig. In the cutting mold jig, Ti diffusion heat treatment after vacuum heat treatment was carried out for upgrade of surface hardness and anti-wear. Also, the heat treatments by various methods were performed to compare the wear damage degree against above the existing heat treatment. Wear loss and friction coefficient were obtained from wear test. And, micro Vickers hardness values were compared with damaged parts or not of cutting mold jig. Micro Vickers hardness value appeared higher at the undamaged part by Ti diffusion heat treatment. The micro Vickers hardness well followed a two-parameter Weibull probability distribution.

Microstructures and Dielectric Properties of SrTiO$_3$-Based BL Capacitor with Content of Ca

  • 김충혁;최운식;이준웅
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.12 no.1
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    • pp.35-43
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    • 1999
  • Microstructures and dielectric properties of (Sr$\_$1-x/Ca$\_$x/) TiO$_3$-0.006Nb$_2$O$\_$5/ (0.05$\leq$x$\leq$0.2) boundary layer ceramics were investigated. The samples fired in a reducing atmosphere(N$_2$) were painted on the surface with CuO paste for the subsequent grain boundary diffusion, and then annealed at 1100$^{\circ}C$ for 2 hrs. The metal oxide of CuO infiltrated by thermal diffusion from surface of sample presents continuously in not grain but only grain boundary, and makes up thin boundary phase. The SEM photo, and EDAX revealed that CuO was penetrated rapidly into the bulk along the grain boundaries during the annealing. The average grain sizes is continuously increased as the content of substitutional Ca is increased from 5[mol%] to 15[mol%], but the average grain size of the sample with content of 20[mol%] Ca is slightly decreased. In the samples with content of 10∼15[mol%] Ca, excellent dielectric properties were obtained as follows; dielectric constant <25000, dielectric loss <0.3[%], and capacitance change rate as a function of temperature <${\pm}$10[%], respectively. All samples in this study exhibited dielectric relaxation with frequency as a functior of the temperature.

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Numerical analysis of concrete degradation due to chloride-induced steel corrosion

  • Ayinde, Olawale O.;Zuo, Xiao-Bao;Yin, Guang-Ji
    • Advances in concrete construction
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    • v.7 no.4
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    • pp.203-210
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    • 2019
  • Concrete structures in marine environment are susceptible to chloride attack, where chloride diffusion results in the corrosion of steel bar and further lead to the cracking of concrete cover. This process causes structural deterioration and affects the response of concrete structures to different forms of loading. This paper presents the use of ABAQUS Finite Element Software in simulating the processes involved in concrete's structural degradation from chloride diffusion to steel corrosion and concrete cover cracking. Fick's law was used for the chloride diffusion, while the mass loss from steel corrosion was obtained using Faraday's law. Pressure generated by steel corrosion product at the concrete-steel interface was modeled by applying uniform radial displacements, while concrete smeared cracking alongside the Extended Finite Element Method (XFEM) was used for concrete cover cracking simulation. Results show that, chloride concentration decreases with penetration depth, but increases with exposure time at the concrete-steel interface. Cracks initiate and propagate in the concrete cover as pressure caused by the steel corrosion product increases. Furthermore, the crack width increases with the exposure time on the surface of the concrete.

Denoising Diffusion Null-space Model and Colorization based Image Compression

  • Indra Imanuel;Dae-Ki Kang;Suk-Ho Lee
    • International Journal of Internet, Broadcasting and Communication
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    • v.16 no.2
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    • pp.22-30
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    • 2024
  • Image compression-decompression methods have become increasingly crucial in modern times, facilitating the transfer of high-quality images while minimizing file size and internet traffic. Historically, early image compression relied on rudimentary codecs, aiming to compress and decompress data with minimal loss of image quality. Recently, a novel compression framework leveraging colorization techniques has emerged. These methods, originally developed for infusing grayscale images with color, have found application in image compression, leading to colorization-based coding. Within this framework, the encoder plays a crucial role in automatically extracting representative pixels-referred to as color seeds-and transmitting them to the decoder. The decoder, utilizing colorization methods, reconstructs color information for the remaining pixels based on the transmitted data. In this paper, we propose a novel approach to image compression, wherein we decompose the compression task into grayscale image compression and colorization tasks. Unlike conventional colorization-based coding, our method focuses on the colorization process rather than the extraction of color seeds. Moreover, we employ the Denoising Diffusion Null-Space Model (DDNM) for colorization, ensuring high-quality color restoration and contributing to superior compression rates. Experimental results demonstrate that our method achieves higher-quality decompressed images compared to standard JPEG and JPEG2000 compression schemes, particularly in high compression rate scenarios.

Two Models to Assess Fuzzy Risk of Natural Disaster in China

  • Chongfu, Huang
    • Journal of the Korean Institute of Intelligent Systems
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    • v.7 no.1
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    • pp.16-26
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    • 1997
  • China is one of the few countries where natural disaster strike frequently and cause heavy damage. In this paper, we mathematically develop two models to assess fuzzy risk of natural disaster in China. One is to assess the risk based on database of historical disaster effects by using information diffusion method relevant in fuzzy information analysis. In another model, we give an overview over advanced method to calculate the risk of release, exposure and consequence assessent, where information distribution technique is used to calculate basic fuzzy relationships showing historical experience of natural disasters, and fuzzy approximate inference is employed to study loss risk based on these basic relationships. We also present an examples to show how to use the first model. Result show that the model is effective for natural disaster risk assessment.

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