• Title/Summary/Keyword: Diffusion constant

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A Study on Diffusion Constant Measurement Using Light Reflectance within Biological Tissue (생체조직내에서 반사광을 이용한 확산 상수의 측정에 관한 연구)

  • 임현수
    • Journal of Biomedical Engineering Research
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    • v.17 no.2
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    • pp.227-234
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    • 1996
  • This paper is the study of the diffusion constant in order to calculate the percent oxygenation and percent blood volume using reflectance light within biological tissue. The diffusion constant play major role in percent oxygenation and percent blood volume and varies with the biological material such as hemolyzed blood, whole blood, dermis and epidermis in vivo tissue. The diffusion constant can be modeled to consist of a contribution from bloodless tissue and blood present in tissue. The reflectance light for experimental are red light of 660nm, infrared light of 880nm, green light of 569nm. The correlation between the diffusion constant and biological tissue was analyzed by the intensity of reflectance light at different depth within human limb. The reflectance light was changed in response to physiological changes within biological tissue. The data for diffusion constant were obtained at different depth beneath the surface of the skin and will be utilized to amen the percent oxygenation and percent blood volume.

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Estimating Diffusion-Controlled Reaction Parameters in Photoinitiated Polymerization of Dimethacrylate Macromonomers

  • Choe, Youngson
    • Macromolecular Research
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    • v.11 no.5
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    • pp.311-316
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    • 2003
  • The kinetics of photoinitiated polymerization of dimethacrylate macromonomers have been studied to determine the diffusion-controlled reaction parameters using attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR). A predicted kinetic rate expression with a diffusion control factor was employed to estimate an effective rate constant and to define the reaction-controlled and diffusion-controlled regimes in the photopolymerization. An effective rate constant, k$_{e}$, can be obtained from the predicted kinetic rate expression. At the earlier stages of polymerization, the average values of kinetic rate constants do not vary during the reaction time. As the reaction conversion, $\alpha$, reaches the critical conversion, $\alpha$$_{c}$, in the predicted kinetic expression, the reaction becomes to be controlled by diffusion due to the restricted mobility of dimethacrylate macromonomers. A drop in value of effective rate constant causes a drastic decrease of reaction rate at the later stages of polymerization. By determining the effective rate constants, the reaction-controlled and diffusion-controlled regimes were properly defined even in the photopolymerization reaction system.m.m.

Fluorescence Quenching of Coumarin Laser Dyes by N,N-dimethylaniline (N,N-dimethylaniline에 의한 Coumarin 색소분자의 형광 소광)

  • Park, Guk Hee;Kang, Tai Jong
    • Journal of the Korean Chemical Society
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    • v.42 no.1
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    • pp.22-27
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    • 1998
  • Fluorescence quenching of coumarin 153 and coumarin 481 with N,N-dimethylaniline in various solvents was investigated. Quenching rate constants are related to diffusion-limited rate constants to some extent. It is noted that smaller discrepancy was observed between the diffusion-limited rate constant and the experimental quenching rate constant when the stick boundary condition rather than the slip boundary condition was applied for estimating the diffusion coefficients. In nonpolar solvent like cyclohexane fluorescence quenching is adequately explained by the diffusion controlled process within the experimental error, but in acetonitrile the quenching rate constant was estimated to be consistently smaller than the diffusion limited rate constant. This may suggest that fluorescence quenching of coumarin dyes be affected not only by the molecular diffusion but also by the intramoleccular process such as charge separation.

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Theoretical Calculation of Parabolic Rate Constant for High-Temperature Oxidation of Metals (금속의 고온 산화동안 포물선 속도상수의 이론적 계산)

  • Kim, Insoo;Cho, Weol Dong
    • Journal of the Korean Society for Heat Treatment
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    • v.14 no.5
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    • pp.282-285
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    • 2001
  • Based on the mass balance of anion and cation fluxes, the parabolic rate constant ($K_p$) of oxide grown during the high-temperature oxidation of metal is theoretically calculated. It is assumed that the diffusion of oxygen anion and metal cation through oxide scale obeys the Fick's 1st law, the growth of oxide is controlled by the diffusion of ions, electrical potential gradient as driving force for diffusion of ions is ignored, and oxidation occurs within an existing oxide layer. Then, the parabolic rate constant can be expressed by $K_p=[2{\rho}_{MmOn}{M^2}_{MmOn}(mD_oC_o{^e}+nD_MC_M{^e})/nm]$.

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REFLECTED DIFFUSION WITH JUMP AND OBLIQUE REFLECTION

  • Kwon, Young-Mee
    • Bulletin of the Korean Mathematical Society
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    • v.35 no.2
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    • pp.269-278
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    • 1998
  • Let ($G,\;{\upsilon}$) be a bounded smooth domain and reflection vector field on $\partial$G, which points uniformly into G. Under the condition that locally for some coordinate system, ${\mid}{\upsilon^i}{\mid}\;i\;=\;1,{\cdot},{\cdot}$,d - 1, where is constant depending on the Lipschitz constant of G, we have tightness for reflected diffusion with jump on G with reflection $\upsilon$ depending only on c. From this, we obtain some properties of L-harmonic function where L is a sum of Laplacian and integro one.

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ASYMPTOTIC RUIN PROBABILITIES IN A GENERALIZED JUMP-DIFFUSION RISK MODEL WITH CONSTANT FORCE OF INTEREST

  • Gao, Qingwu;Bao, Di
    • Journal of the Korean Mathematical Society
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    • v.51 no.4
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    • pp.735-749
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    • 2014
  • This paper studies the asymptotic behavior of the finite-time ruin probability in a jump-diffusion risk model with constant force of interest, upper tail asymptotically independent claims and a general counting arrival process. Particularly, if the claim inter-arrival times follow a certain dependence structure, the obtained result also covers the case of the infinite-time ruin probability.

Validity of Inter-Particle Models for the Mass-Transfer Kinetics of a Fin-Tube-Type Adsorption Bed (핀-튜브형 흡착탑 해석시 입자간 물질전달 모델의 타당성 검증)

  • Ahn, Sang Hyeok;Hong, Sang Woo;Kwon, Oh Kyung;Chung, Jae Dong
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.25 no.12
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    • pp.660-667
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    • 2013
  • This study presents a numerical investigation of the heat and mass transfer kinetics of a fin-tube-type adsorption bed using a two-dimensional numerical model with silica-gel and water as the adsorbent and refrigerant pair. The performance is strongly affected by the heat and mass transfer in the adsorption bed, but the details of the mass transfer kinetics remain unclear. The validity of inter-particle models used to simulate mass-transfer kinetics were examined, such as a constant pressure model and non-constant pressure model, and the valid ranges of the diffusion ratio for each model are proposed. The COP and SCP have been numerically calculated as the performance indexes according to the diffusion ratio. The constant pressure model, which is commonly used in previous research, was found to be valid only in a limited range of diffusion ratio.

Pseudo-Binary Diffusion Coefficients of Organic Aroma Component - I. The Diffusion Coefficient of Benzaldehyde in Aqueous Sugar Solution - (유기방향물질의 의사 2성분계 확산계수 - 제1보 : 설탕수용액중 Benzaldehyde의 확산계수 -)

  • Kang, An-Soo;Lee, Tae-Hee
    • Korean Journal of Food Science and Technology
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    • v.14 no.4
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    • pp.315-323
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    • 1982
  • The measurement of cell constant in a diaphragm-cell method is the most important factor. In order to get the correct cell constant, the diffusion coefficients of potassium chloride were measured, at various concentration and temperature of potassium chloride solution, and at the stirring rate in the cell. The pseudo-binary diffusion coefficients of organic aroma component (benzaldehyde) in sugar solution has been measured at various concentration and temperature with the cell constant obtained above. Experimental results were compared and discussed with the semi-empirical epuations from literatures. And, especially, the diffusion coefficient of benzaldehyde, $D_{ba}$ for a small solute diffusing in a viscous solvent of larger molecules is proportional to the -0.82 power of the viscosity of aqueous sugar solution, ${\mu}$ at constant temperature, $D_{ba}{\mu}^{0.82}=constant$.

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A Study on the Soot Measurement in Laminar and Turbulent Diffusion Flame Using the Laser Diagnostics (광계측 기법을 이용한 층류 및 난류 확산 화염에서의 매연 측정에 관한 연구)

  • Lee, Jun-Yong;Han, Yong-Taik;Lim, Jun-Won;Min, Kyoung-Doug
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.3073-3078
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    • 2008
  • In this study to find out the amount of soot, LII method, which utilizes a laser, was used in laminar diffusion flame and based upon the temperature and soot measured from the turbulent Diesel diffusion flame in the constant-volume chamber using the two-color method. Through these experiments, we could know that the LII signal is generally proportional to the soot amount in a laminar diffusion flame. And we could acquire the temperature and soot using the two-color method in a turbulent Diesel diffusion flame effectively. In addition to, this experiment revealed that the KL factor was high on parts of the chamber where the temperature dropped. On the other hand, the KL factor was low where the temperature increased rapidly. Also, it was possible to measure the highest temperature of a turbulent Diesel diffusion flame is approximately 2300K.

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EXISTENCE OF NON-CONSTANT POSITIVE SOLUTION OF A DIFFUSIVE MODIFIED LESLIE-GOWER PREY-PREDATOR SYSTEM WITH PREY INFECTION AND BEDDINGTON DEANGELIS FUNCTIONAL RESPONSE

  • MELESE, DAWIT
    • Journal of applied mathematics & informatics
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    • v.40 no.3_4
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    • pp.393-407
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    • 2022
  • In this paper, a diffusive predator-prey system with Beddington DeAngelis functional response and the modified Leslie-Gower type predator dynamics when a prey population is infected is considered. The predator is assumed to predate both the susceptible prey and infected prey following the Beddington-DeAngelis functional response and Holling type II functional response, respectively. The predator follows the modified Leslie-Gower predator dynamics. Both the prey, susceptible and infected, and predator are assumed to be distributed in-homogeneous in space. A reaction-diffusion equation with Neumann boundary conditions is considered to capture the dynamics of the prey and predator population. The global attractor and persistence properties of the system are studied. The priori estimates of the non-constant positive steady state of the system are obtained. The existence of non-constant positive steady state of the system is investigated by the use of Leray-Schauder Theorem. The existence of non-constant positive steady state of the system, with large diffusivity, guarantees for the occurrence of interesting Turing patterns.