• New Physics: Sae Mulli
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• v.68 no.12
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• pp.1315-1323
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• 2018

We studied the carbonization due to the annealing condition of waste coffee powder for application as an active anode material for lithium-ion batteries (LIBs). The coffee powder used as an active anode material for LIBs was obtained from coffee beans, not from a coffee shells. The waste coffee powder was dried in air and heat-treated in an $Ar/H_2$ atmosphere to obtain a pore-forming activated carbon powder. The specific capacity of the sample annealed at $700^{\circ}C$ was still 303 mAh/g after 1000 cycles at a current density of 1000 mA/g and with a coulombic efficiency of over 99.5%. The number of pores and the pore size of the waste coffee powder were increased due to chemical treatment with KOH, which had the some effect as an increased specific surface area. The waste coffee powder is considered to be a very promising active anode material because of both its excellent electrochemical properties due to enhanced carrier conduction and its being a cost effective resource for use in LIBs.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.20 no.7
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• pp.46-52
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• 2006

The effects of surface treatment on the hydrogen storage properties of a $Mg_2Ni$ alloy particle were investigated by the microvoltammetric technique, in which a carbon-filament microelectrode was manipulated to make electrical contact with the particle in a KOH aqueous solution. It was found that the hydrogen storage properties of $Mg_2Ni$ at room temperature were improved by the surface treatment with a nickel plating solution. The sodium salts(sodium phosphate and sodium dihydrogen citrate) contained in the nickel plating solution made the alloy form an amorphous-like state, resulting in an improved hydrogen charge/discharge capacity at room temperature as high as about 150[mAh/g] from the original value of 17[mAh/g]. Potential-step experiment was carried out to determine the apparent chemical diffusion coefficient of hydrogen atom($D_{app}$) in the alloy. Since the alloy particle we used here was a dense, conductive sphere, the spherical diffusion model was employed for data analysis. $D_{app}$ was found to vary the order between $10^{-8}{\sim}10^{-9}[cm^2/s]$ over the course of hydrogenation and dehydrogenation process.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.10 no.11
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• pp.2091-2098
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• 2006

In this paper, it proposes a protocol of resource adaptive data dissemination for sensor nodes in a wireless sensor network. In general, each sensor node used in a wireless sensor network delivers the required information to the final destination by conducting cooperative works such as sensing, processing, and communicating each other using the battery power of a independent sensor node. So, a protocol used for transferring the acquired information to users through the wireless sensor network can minimize the power consumption of energy resource given to a sensor node. Especially, it is very important to minimize the total amount of power consumption with a method for handling the problems on implosion. data delivery overlapping, and excessive message transfer caused by message broadcasting. In this paper, for the maintaining of the shortest path between sensor nodes, maximizing of the life time of a sensor node and minimizing of communication cost, it presents a method for selecting the representative transfer node for an event arising area based on the negotiation scheme and maintaining optimal transfer path using hop and energy information. Finally, for the performance evaluation, we compare the proposed protocol to existing directed diffusion and SPIN protocol. And, with the simulation results, we show that the proposed protocol enhances the performance on the power consumption rate when the number of overall sensor nodes in a sensor network or neighbor sensor nodes in an event area are increased and on the number of messages disseminated from a sensor node.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2006.05a
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• pp.437-441
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• 2006

Wireless sensor network consists of sensor nodes which are disseminated closely to each other to collect informations for the various requests of a sensor application applied for sensing phenomenons in real world. Each sensor node delivers sensing informations to an end user by conducting cooperative works such as processing and communicating between sensor nodes. In general, the power supply of a sensor node is depends on a battery so that the power consumption of a sensor node decides the entire life time of a sensor network. To resolve the problem, optimal routing algorithm can be used for prolong the entire life time of a sensor network based on the information on the energy level of each sensor node. In this paper, different from the existing Directed Diffusion and SPTN method, we presents a data dissemination protocol based on lower-power consumption that effectively maximizes the whole life time of a sensor network using the informations on the energy level of a sensor node and shortest-path hops. With the proposed method, a data transfer path is established using the informations on the energy levels and hops, and the collected sensing information from neighboring nodes in the event-occurring area is merged with others and delivered to users through the shortest path.

• Applied Chemistry for Engineering
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• v.9 no.5
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• pp.774-780
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• 1998

For the stabilization of the spinel structured $LiMn_2O_4$, a fraction of manganese was substituted with various metals such as Mg, Fe, V, W, Cr, Mo with Mn that had a similar ionic radii ($LiM_xMn_{2-x}O_4(0.05{\leq}x{\leq}0.02)$). The $LiM_xMn_{2-x}O_4$ showed a substantial improvement as lower capacity loss than that of the spinel structured $LiMn_2O_4$ when it was used as a cathode material. And with the partial substitution, the chemical diffusion coefficient for $LiMg_{0.05}Mn_{1.9}O_4$ and $LiCr_{0.1}Mn_{1.9}O_4$ was increased by and order of magnitude compared to that of the $LiMn_2O_4$ with spinel structure. The results showed that significant improvement can be made on the electrochemical characteristics as the structure of the $LiMn_2O_4$ electrode material was stabilized by the partial substitution.

• Journal of Electrochemical Science and Technology
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• v.8 no.4
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• pp.323-330
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• 2017

$M_2GeO_4$ (M = Co, Fe and Ni) was synthesized as an anode material for lithium-ion batteries and its electrochemical characteristics were investigated. The $Fe_2GeO_4$ electrode exhibited an initial discharge capacity of $1127.8mAh\;g^{-1}$ and better capacity retention than $Co_2GeO_4$ and $Ni_2GeO_4$. A diffusion coefficient of lithium ion in the $Fe_2GeO_4$ electrode was measured to be $12.7{\times}10^{-8}cm^2s^{-1}$, which was higher than those of the other two electrodes. The electrochemical performance of the $Fe_2GeO_4$ electrode was improved by coating carbon onto the surface of $Fe_2GeO_4$ particles. The carbon-coated $Fe_2GeO_4$ electrode delivered a high initial discharge capacity of $1144.9mAh\;g^{-1}$ with good capacity retention. The enhanced cycling performance was mainly attributed to the carbon-coated layer that accommodates the volume change of the active materials and improves the electronic conductivity. Our results demonstrate that the carbon-coated $Fe_2GeO_4$ can be a promising anode material for achieving high energy density lithium-ion batteries.

• Applied Chemistry for Engineering
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• v.7 no.2
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• pp.362-370
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• 1996

The performance of The performance of $Li/V_6O_{13}$ cell and the electrochemical properties of polymer electrolyte based on poly(acrylonitrile)[PAN] was investigated. The ionic conductivity of polymer electrolyte showed $2.3{\times}10^{-3}S/cm$ and the compatibility with lithium electrode was excellent. Also, it showed the electrochemical stability up to 4.3V(vs. $Li^+/Li$). The cell reaction of $Li/V_6O_{13}$ was dominated by the interfacial resistance between $V_6O_{13}$ electrode and polymer electrolyte. The diffusion coefficient of lithium ion within $V_6O_{13}$ was $2.7{\times}10^{-9}{\sim}4.2{\times}10^{-8}cm^2/sec$. The utilization of $V_6O_{13}$ active material was 95% at C/8($50{\mu}A/cm^2$) and 82% at C/4($100{\mu}A/cm^2$), respectively.

• The Journal of the Korea Contents Association
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• v.7 no.2
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• pp.92-99
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• 2007

This paper presented a low power design of a 32bit block cypher processor reduced from the original 128bit architecture. The primary purpose of this research is to evaluate physical implementation results rather than theoretical aspects. The data path and diffusion function of the processor were reduced to accommodate the smaller hardware size. As a running example demonstrating the design approach, we employed a modified ARIA algorithm having four S-boxes. The proposed 32bit ARIA processor comprises 13,893 gates which is 68.25% smaller than the original 128bit structure. The design was synthesized and verified based on the standard cell library of the MagnaChip's 0.35um CMOS Process. A transistor level power simulation shows that the power consumption of the proposed processor reduced to 61.4mW, which is 9.7% of the original 128bit design. The low power design of the block cypher Processor would be essential for improving security of battery-less wireless sensor networks or RFID.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.64 no.2
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• pp.228-231
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• 2015

In power system research fields, one of current key issues is the construction and commercialization of micro grid site which is called green island, carbon zero island, energy independent island, building micro grid, etc. and various affiliated technologies have been being vigorously developed to realize. In addition, various researches about electric vehicles (EVs) are in progress and it is expected to penetrate rapidly with the next a few years. Some new load models should be developed integrating with electric vehicle loads because the EVs' deployment could cause the change of load composition rate on power system planning and operations. EVs are also resources for micro grid as well as distributed generation and demand response so that various supply and demand side resources should be considered for micro grid researches. In this paper, the load composition rate of residential sectors is prospected considering the deployment of EVs and the resource configuration of micro grid is optimized based on net present cost. In the optimization, the load patten of case studies includes EV's charging characteristics and various cases are simulated comparing micro grid environment and normal condition. HOMER is used to compare various cases and economic effects.

• Journal of Electrochemical Science and Technology
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• v.4 no.3
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• pp.102-107
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• 2013

The electrochemical properties of Mg-doped $LiFe_{0.48}Mn_{0.48}Mg_{0.04}PO_4$ and pure $LiFe_{0.5}Mn_{0.5}PO_4$ olivine cathodes are examined and the lattice parameters are refined by Rietveld analysis. The calculated atomic parameters from the refinement show that $Mg^{2+}$ doping has a significant effect in the olivine $LiFeMnPO_4$ structure. The unit cell volume is 297.053(2) ${\AA}^3$ for pure $LiFe_{0.5}Mn_{0.5}PO_4$ and is decreased to 296.177(1) ${\AA}^3$ for Mg-doped $LiFe_{0.48}Mn_{0.48}Mg_{0.04}PO_4$ sample. The doping of $Mg^{2+}$ cation with atomic radius smaller than $Mn^{2+}$ and $Fe^{2+}$ ion induces longer Li-O bond length in $LiO_6$ octahedra of the olivine structure. The larger interstitial sites in $LiO_6$ octahedra facilitate the lithium ion migration and also enhance the diffusion kinetics of olivine cathode material. The $LiFe_{0.48}Mn_{0.48}Mg_{0.04}PO_4$ sample with larger Li-O bond length delivers higher discharge capacities and also notably increases the rate capability of the electrode.