• Title/Summary/Keyword: Diffusion Length

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Biophysical Feature, Crystallization and X-ray Crystallographic Studies of Toxascaris leonina Galectin

  • Sung, Min-Kyung;Jeong, Mi-Suk;Lee, Woo-Chul;Song, Jeong-Hyun;Kim, Hye-Yeon;Cho, Min-Kyoung;Yu, Hak-Sun;Jang, Se-Bok
    • Bulletin of the Korean Chemical Society
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    • v.33 no.1
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    • pp.227-232
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    • 2012
  • Galectins are generally believed to be potential candidates for use in the development of novel antiinflammatory agents or as selective modulators of the immune response. In particular, galectin-9 exhibits some of the extracellular functions, including cell aggregation, adhesion, chemoattraction, activation, and apoptosis. Tl-galectin (Tl-gal, galectin-9 homologue gene) was isolated from an adult worm of the Toxascaris leonina. The full-length Tl-gal gene, which was incorporated into pET-28a, was overexpressed in E. coli and purified by nickel affinity and gel filtration chromatographies. The purified Tl-gal was crystallized using the hangingdrop vapor-diffusion method. The crystal belonged to the tetragonal space group $P4_1$, with unit-cell parameters of a = b = $75.7\AA$ and c = $248.4\AA$. The crystals were obtained at $20^{\circ}C$ and diffracted to a resolution of $3.0\AA$. The asymmetric unit contained four molecules of Tl-gal, which gave a crystal volume per protein mass (Vm) of $2.8\AA^3Da^{-1}$ and a solvent content of 54.1%.

Adsorption Characteristics of Malachite Green on Zeolite (제올라이트에 의한 말라카이트 그린의 흡착특성)

  • Lee, Jong-Jib;Um, Myeong-Heon
    • Clean Technology
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    • v.18 no.3
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    • pp.312-319
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    • 2012
  • Malachite green is used a dye but malachite green is harmful toxic substance. In this study, the adsorption characteristics of zeolite has been investigated for the adsorption of malachite green dissolved in water. The effects of initial dye concentration, contact time, pH and temperature on adsorption of malachite green by a fixed amount of zeolite have been studied in batch adsorber and fixed bed. The adsorption equilibrium data are successfully fitted to the Freundlich isotherm equation in the temperature range from 25 to $45^{\circ}C$. The estimated values of k and ${\beta}$ are 23.60-46.88, 0.225-0.347, respectively. The mechanism of the adsorption process was determined from the intraparticle diffusion model. The effects of the operation conditions of the fixed bed on the breakthrough curve were investigated. When the inlet concentration and initial flow rate of malachite green are increased, the corresponding adsorption breaktime appears to decrease. Breaktime increased with increasing bed height and length of adsorption zone showed similar patterns.

Size-controlled Chevrel Mo6S8 as Cathode Material for Mg Rechargeable Battery

  • Ryu, Anna;Park, Min-Sik;Cho, Woosuk;Kim, Jeom-Soo;Kim, Young-Jun
    • Bulletin of the Korean Chemical Society
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    • v.34 no.10
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    • pp.3033-3038
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    • 2013
  • Nanoscale Chevrel $Mo_6S_8$ powders are synthesized by molten salt synthesis. Synthesized $Mo_6S_8$ powders have different mean particle sizes which are dependent on a ratio of salt to precursor. The particle sizes of $Mo_6S_8$ powders changes along with the ratio increase. $Mo_6S_8$ (6:1) demonstrates the best electrochemical characteristics among the synthesized $Mo_6S_8$ powders although the $Mo_6S_8$ (4:1) has the smallest particle size. $Mo_6S_8$ (6:1) shows a reversible capacity of 83.9 $mAhg^{-1}$, which is 27.5% and 33% improved value over $Mo_6S_8$ (2:1) and $Mo_6S_8$ (4:1) at a current density of 0.2C, respectively. The superior electrochemical properties of $Mo_6S_8$ (6:1) are attributed to the balanced particle size which provides proper contact area with electrolyte and the shortened $Mg^{2+}$ diffusion length. The $Mo_6S_8$ (4:1) has the smallest particle size but further reduction of particle size from $Mo_6S_8$ (6:1) is not advantageous.

Fabrication of Wavelength Division Demultiplexing Photodetectors Using Quantum Well Intermixing (다중양자우물의 상호 섞임 현상을 이용한 다중파장검출기의 제작)

  • Yeo, Deok-Ho;Yoon, Kyung-Hun;Kim Sung-June
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.37 no.9
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    • pp.1-6
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    • 2000
  • Utilizing impurity free vacancy diffusion (IFVD) method, area selective intermixing of InGaAs/InGaAsP multi-quantum well (MQW) structure was done. After this, wavelength division demultiplexing waveguide type photodetectoers was integrated and measured. It showed large blue shift in bandgap due to intermixing of MQW. Photodetectors are based on typical p-i-n structure and devices having large and small bandgap areas line up linearly. Width of waveguide and length of each photodetector are 20 and 250 ${\mu}m$, respectively, TE/TM polarized light from tunable laser was butt-coupled to the photodetector and spectral response was measured. Photodetectors can demultiplexing 1480 and 1550 nm wavelength.

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A Simple Model for Dispersion in the Stable Boundary Layer

  • Kang Sung-Dae;Kimura Fujio;Lee Hwa-Woon;Kim Yoo-Keun
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.1 no.1
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    • pp.35-43
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    • 1997
  • Handling the emergency problems such as Chemobyl accident require real time prediction of pollutants dispersion. One-point real time sounding at pollutant source and simple model including turbulent-radiation process are very important to predict dispersion at real time. The stability categories obtained by one-dimensional numerical model (including PBL dynamics and radiative process) are good agreement with observational data (Golder, 1972). Therefore, the meteorological parameters (thermal, moisture and momentum fluxes; sensible and latent heat; Monin-Obukhov length and bulk Richardson number; vertical diffusion coefficient and TKE; mixing height) calculated by this model will be useful to understand the structure of stable boundary layer and to handling the emergency problems such as dangerous gasses accident. Especially, this simple model has strong merit for practical dispersion models which require turbulence process but does not takes long time to real predictions. According to the results of this model, the urban area has stronger vertical dispersion and weaker horizontal dispersion than rural area during daytime in summer season. The maximum stability class of urban area and rural area are 'A' and 'B' at 14 LST, respectively. After 20 LST, both urban and rural area have weak vertical dispersion, but they have strong horizontal dispersion. Generally, the urban area have larger radius of horizontal dispersion than rural area. Considering the resolution and time consuming problems of three dimensional grid model, one-dimensional model with one-point real sounding have strong merit for practical dispersion model.

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Shape Optimization of an Active Micro-Mixer for Improving Mixing Efficiency (혼합 효율 향상을 위한 마이크로 동적 믹서의 형상최적화)

  • Park, Jae-Yong;Kim, Sang-Rak;Lee, Won-Gu;Yoo, Jin-Sik;Kim, Young-Dae;Maeng, Joo-Seung;Han, Seog-Young
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.16 no.6
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    • pp.146-152
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    • 2007
  • An active micro-mixer, which was composed of an oscillating micro-stirrer in the microchannel to provide rapid, effective mixing at high flow, rates was analyzed. The effects of molecular diffusion and disturbance by the stirrer were considered with regard to two types of mixer models: the simple straight microchannel and microchannel with an oscillating stirrer. Two types of mixer models were studied by analyzing mixing behaviors such as their interaction after the stirrer. The mixing was calculated by Lattice Boltzmann methods using the D2Q9 model. In this study, the time-averaged mixing index formula was used to estimate the mixing performance of time-dependent flow. The mixing indices of the two models compared. From the results, it was found that the mixer with an oscillating stirrer was much more enhanced and stabilized. Therefore, an optimum design for a dynamic micro-mixer with an oscillating stirrer was performed using Taguchi method in order to obtain a robust solution. The design parameters were established as the frequency, the length and the angle of the stirrer and the optimal values were determined to be 2, 0.8D and ${\pm}75^{\circ}$, respectively. It was found that the mixing index of the optimal design increased 80.72% compared with that of the original design.

Approximate Optimization of an Active Micro-Mixer (능동형 미소혼합기의 근사최적화)

  • Park, Jae-Yong;Kim, Sang-Rak;Yoo, Jin-Sik;Lim, Min-Gyu;Kim, Young-Dae;Han, Seog-Young;Maeng, Joo-Seung
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.17 no.5
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    • pp.95-100
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    • 2008
  • An active micro-mixer, which is composed of an oscillating micro-stirrer in the micro-channel to provide effective mixing was optimized. The effects of molecular diffusion and disturbance by the stirrer were considered with regard to two types of mixer models: the simple straight micro-channel and micro-channel with an oscillating stirrer. Two types of mixer models were studied by analyzing mixing behaviors such as their interaction after the stirrer. The mixing was calculated by Lattice Boltzmann methods using the D2Q9 model. In this study, the time-averaged mixing index formula was used to estimate the mixing performance of time-dependent flow. The mixing indices of the two models were compared. From the results, it was found that the mixer with an oscillating stirrer was much more enhanced and stabilized. Therefore, an approximate optimization of an active micro-mixer with an oscillating stirrer was performed using Kriging method with OLHD(Optimal Latin Hypercube Design) in order to determine the optimal design variables. The design parameters were established as the frequency, the length and the angle of the stirrer. The optimal values were obtained as 1.0346, 0.66D and $\pm45^{\circ}$, respectively. It was found that the mixing index of the optimal design increased by 88.72% compared with that of the original design.

Electrical Characteristics of Ni/Ti/Al Ohmic Contacts to Al-implanted p-type 4H-SiC (Al 이온 주입된 p-type 4H-SiC에 형성된 Ni/Ti/Al Ohmic Contact의 전기적 특성)

  • Joo, Sung-Jae;Song, Jae-Yeol;Kang, In-Ho;Bahng, Wook;Kim, Sang-Cheol;Kim, Nam-Kyun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.11
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    • pp.968-972
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    • 2008
  • Ni/Ti/Al multilayer system ('/'denotes the deposition sequence) was tested for low-resistance ohmic contact formation to Al-implanted p-type 4H-SiC. Ni 30 nm / Ti 50 nm / Al 300 nm layers were sequentially deposited by e-beam evaporation on the 4H-SiC samples which were implanted with Al (norminal doping concentration = $4\times10^{19}cm^{-3}$) and then annealed at $1700^{\circ}C$ for dopant activation. Rapid thermal anneal (RTA) temperature for ohmic contact formation was varied in the range of $840\sim930^{\circ}C$. Specific contact resistances were extracted from the measured current vs. voltage (I-V) data of linear- and circular transfer length method (TLM) patterns. In constrast to Ni contact, Ni/Ti/Al contact shows perfectly linear I-V characteristics, and possesses much lower contact resistance of about $2\sim3\times10^{-4}\Omega{\cdot}cm^2$ even after low-temperature RTA at $840^{\circ}C$, which is about 2 orders of magnitude smaller than that of Ni contact. Therefore, it was shown that RTA temperature for ohmic contact formation can be lowered to at least $840^{\circ}C$ without significant compromise of contact resistance. X-ray diffraction (XRD) analysis indicated the existence of intermetallic compounds of Ni and Al as well as $NiSi_{1-x}$, but characteristic peaks of $Ti_{3}SiC_2$, a probable narrow-gap interfacial alloy responsible for low-resistance Ti/Al ohmic contact formation, were not detected. Therefore, Al in-diffusion into SiC surface region is considered to be the dominant mechanism of improvement in conduction behavior of Ni/Ti/Al contact.

Defect Detection of the Wall Thinning Pipe of the Nuclear Power Plant Using Infrared Thermography (적외선열화상을 이용한 원자력발전소 감육 배관의 결함 검출)

  • Kim, Kyeong-Suk;Chang, Ho-Sub;Hong, Dong-Pyo;Park, Chan-Joo;Na, Sung-Won;Kim, Kyung-Su;Jung, Hyun-Chul
    • Journal of the Korean Society for Nondestructive Testing
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    • v.30 no.2
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    • pp.85-90
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    • 2010
  • The infrared energy is emitted in the infrared wavelength range that corresponds to the surface temperature of a object which has temperature that is over the absolute the temperature(OK). The infrared thermography (IRT) is a non-destrnctive testing method that provides thermal video for the user in real-time by converting the infrared quantity that is detected by the infrared detector into temperature. The pipes of nuclear power plant(NPP) could be thinned by the corrosion and fatigue and the defect could lead to a big accident. For this reason, the effective non-destructive testing method is necessary. In this study, the relationship between the measured temperature and the defect depth or size of NPP pipes were recognized and that was applied to detect the wall thinning defects of NPP pipes.

Combustion Characteristics and the Modeling of Ionized Methane for Battery Fires (배터리화재를 모사한 이온화 메탄의 연소특성 및 모델링)

  • Ko, Hyuk-Ju;Lee, Eui-Ju
    • Fire Science and Engineering
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    • v.33 no.1
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    • pp.23-29
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    • 2019
  • Rechargeable battery such as lithium-ion battery has been noticed as a kinds of the energy storage system in the recent energy utilization and widely used actually in various small electronic equipment and electric vehicles. However, many thermal runaway caused battery accidents occurred recently, which still is obstacle for advanced application of lithium ion battery. One of the main differences to general fires is the existence of ionized electrolyte with electron during combustion. Therefore, we simply simulated the ion addition effects of battery fires by introducing an ionized fuel in jet diffusion flames. When the ionized methane through a corona discharge was used as fuel, the overall flame stability and shape such as flame length showed no significant difference from normal methane flame, but NOx and CO emissions measured at the post flame region decreased. The ion addition effect of methane oxidation was also numerically simulated with the modeling of hydrogen addition in the mixture. It was confirmed that the hydrogen addition at a fixed temperature had a similar effects on ionization of methane and hence could be modeled successfully.