• Title/Summary/Keyword: Dielectric $(Pb_{1-x}Sr_x)TiO_3$

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Study on the Preparation and Characteristics of $(Pb_{1-x}Sr_x)TiO_3$ Thin Films by the Sol-gel Process (졸-겔법을 이용한 $(Pb_{1-x}Sr_x)TiO_3$ 박막의 제조 및 특성에 관한 연구)

  • 선계혁;윤희한;황규석;김병훈
    • Journal of the Korean Ceramic Society
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    • v.33 no.11
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    • pp.1195-1202
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    • 1996
  • To prepare the dielectric thin films of (Pb1-xSrx)TiO3 (x=0.1, 0.2, 0.3, 0.35, 0.5) by the sol-gel process titanium (IV) isopropoxide (Ti[OCH(CH3)2]4) and Pb Sr, acetate were used therefore the thin films were fabricated by dip-coating method. Stability of the sol decreased with addition of Sr content thin films could be fabricated up to 35mol% Over this range precipitation of sol occured thin films couldn't be obtained. Transmittance of thin films at visible range decreased with the increase of heat-treatment temperature but exhibited transmit-tance above 60% in all case. Moreover transmittance of thin films at visible range slightly increased with of addition of Sr,. When thin film containing 30 mol% srontium was heated at 600℃ the best perovskite phase was obtained. The dielectric constant (ε) was 280 and dielectric loss factor (tan δ) was 0.021 and curie tempera-ture (Tc) decreased with the increase of addition of Sr.

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The study on Dielectric and Strain Properties of ((1-y-x)Pb(Mg$_{1}$3 Nb$_{2}$3/)O$_3$-yPbTiO$_3$-xSrTiO$_3$Ceramics ((1-y-x)Pb(Mg$_{1}$3 Nb$_{2}$3/)O$_3$-yPbTiO$_3$-xSrTiO$_3$세라믹의 유전 및 변위 특성에 관한 연구)

  • 이해영;이덕출;이능헌;김용혁
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.05a
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    • pp.5-8
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    • 1994
  • In this paper, Dielectric and strain properties of (1-x-y)PMN-yPT-xST Ceramics hale been investigated as a function of the amount of SrTiO$_3$(ST). The SrTiO$_3$ content is ranged from 0.01-0.05(wt%). As the amount of ST is increased, dielectric constant has a maximun value at 0.05 mol% composition. The Curie temperature is decreased linearly with increasing ST composition and Polarization properties have been investigated. Coercive field and remnant polarization has a maximum value at 0.01mo1% composiion.

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Dielectric and strain properties of Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$-PbTiO$_{3}$ Ceramic with Respect to the Variation of SrTiO$_{3}$ Substitution (SrTiO$_{3}$ 고용에 따른 Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$-PbTiO$_{3}$계 세라믹스의 유전 및 전왜특)

  • 지승한;이해영;이덕출;이진걸;이연학
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.45 no.2
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    • pp.235-241
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    • 1996
  • In this paper dielectric and electrostrictive strain properties of (1-y-x)Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$-PbTiO$_{3}$$-yPbTiO_{3}-xSrTiO_{3}[(1-y-x)PMN-yPT-xST]$ ceramics fabricated by using columbite precursor method have been investigated with the substitution of SrTiO$_{3}$(ST). Dielectric constant of the specimens increased with the increase of ST content up to 5[m/o] and decreased with further substitution of ST. And the pyrochlore phase decreased with the increase of ST content up to 5[m/o] in XRD analysis. The elimination of the pyrochlore phase improved dielectric constants. The electrostrictive strains generated by AC electric field have the highest value at 5[m/o] SrTiO$_{3}$ addition and the hysteresis of strain ranged from 12 to 20[%]. The electrostrictive strain at various temperature investigated in the temperature range of $-50[^{\circ}C]~74[^{\circ}C].$ In higher temperature than phase transition region, it showed paraelectric property which shows very small hystersis.

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Electrical Properties of $\{(Sr_xCa_{1-x})_{0.95-y-z}Bi_2Pb_{0.05+y}\}Ti_{1.02}O_3$ for SMD-type Dielectric Trimmer Condenser (SMD-type Trimmer Condenser용 $\{(Sr_xCa_{1-x})_{0.95-y-z}Bi_2Pb_{0.05+y}\}Ti_{1.02}O_3$)

  • Kang, D.H.;Cha, H.J.;Nam, K.C.;Hu, J.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.597-600
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    • 2002
  • Electrical properties of $\{(Sr_xCa_{1-x})_{0.95-y-z}Bi_2Pb_{0.05+y}\})Ti_{1.02}O_3$ ceramic were studied as a function of Sr/Ca ratio and Bi, Pb contents. Dielectric properties of specimens with different x, y, z values were explained in terms of ionic polarizability with Molecular Additionally Rules and Clausius-Mosotti equation. For the composition of $\{(Sr_{0.62}Ca_{0.38})_{0.90}Bi_{0.01}Pb_{0.09}\})Ti_{1.02}O_3$ and $\{(Sr_{0.62}Ca_{0.38})_{0.905}Bi_{0.015}Pb_{0.08}\})Ti_{1.02}O_3$, dielectric constant$({\varepsilon}_r)$, quality factor(Q) and temperature coefficient(TC) were 389, 3048, -1490 and 394, 1869, -1340 at 1MHz, respectively.

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The Dielectrical Properties of $(1-x)(Sr_a.Pb_b.Ca_c)TiO_3-xB_i2O_3.TiO_2$ system affected by $Bi_2O_3.3TiO_2$ amounts and $MnO_2$ ($(1-x)(Sr_a.Pb_b.Ca_c)TiO_3-xB_i2O_3.TiO_2$계에서의 $Bi_2O_3.3TiO_2$$MnO_2$첨가에 따른 유전특성에 관한 연구)

  • 박상도;이응상
    • Journal of the Korean Ceramic Society
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    • v.34 no.2
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    • pp.123-130
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    • 1997
  • In this study, (Sr.Pb.Ca)TiO3-Bi2O3.3TiO2(SPCT) systems were investigated to develop a new material which has a high dielectric constant, a low dielectric loss and a small TCC(Temperature Coefficient of Capa-citance), and are suitable for high voltage applications as a function of the additions of Bi2O3.3TiO2 from 5 mol.% to 9 mol.%. The result obtained from our investigation showed that up to 6 mol.% Bi2O3.3TiO ad-dition the dielectric constant increased and it deteriorated at higher concentrations with increasing amount of the acicular grains. As a result of some dopants (SiO2, Nb2O3, MnO2) addition to SPCT, the specimens with MnO2 showed good dielectric properties. The dielectric constant decreased, but the TCC was improved with the addition of MnO2 from 0.15 wt.% to 0.45 wt. %.

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Structureal and dielectric properties of $(Pb_{x},Sr_{x-1})TiO_{3}$ thin film for tunable device application (Tunable 소자 응용을 위한 $(Pb_{x},Sr_{x-1})TiO_{3}$ 박막의 구조 및 유전특성)

  • Kim, Kyoung-Tae;Kim, Chang-Il;Lee, Sung-Gap
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05b
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    • pp.78-81
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    • 2002
  • Ferroelectric thin film is a very attractive material for the tunable microwave device applications such as electronically tunable mixers, delay lines, filters and phase shifters. Thin films of $Pb_{x}Sr_{1-x}TiO3(PST)$ were fabricated onto Pt/Ti/SiO2/Si substrate by the sol-gel method. We have investigated the structural and dielectric properties of PST(50/50) thin films for tunable microwave device applications. The PST thin films show typical polycrystalline structure with a dense microstructure without secondary phase formation. Dielectric properties of PST films are strongly dependent on annealing temperature. The dielectric constants, loss and tunability of the PST (50/50) thin films were 404, 0.023 and 51.73 %, respectively.

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The study on Dielectric and Strain Properties of $Pb(Mg_{1/3}Nb_{2/3})O_3-PbTiO_3-SrTiO_3$ Ceramics. ($Pb(Mg_{1/3}Nb_{2/3})O_3-PbTiO_3-SrTiO_3$ 세라믹의 유전 및 변위 특성에 관한 연구(II))

  • Lee, H.Y.;Lee, J.;Jung, H.D.;Paek, Y.C.;Lee, H.K.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 1994.07b
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    • pp.1466-1468
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    • 1994
  • In this paper Dielectric and strain properties of (1-x-y)PMN-yPT-xST Ceramics have been investigated as a function of the amount of $SrTiO_3(ST)$. The $SrTiO_3$ content is ranged from 0.01-0.06(wt%). As the amount of ST is increased, dielectric constant has a maximum value at 0.05 mol composition. The Curie temperature is decreased linearly with increasing ST composition and Polarization properties have been investigated. Coercive field and ramnant polarization has a maximum value at 0.01mol composition.

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Sr modified $PbTiO_3$ thin films for tunable microwave device application (MOD법에 의한 Sr modified $PbTiO_3$ 박막 제조 및 Tunable microwave device 응용 특성 연구)

  • Kang, D.H.;Cho, S.C.;Cha, H.J.;Cho, B.H.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.749-751
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    • 2002
  • $(Pb_{1-x}Sr_x)TiO_3$ $(0.6{\leq}x{\leq}0.8)$ thin films were prepared by the MOD method for tunable microwave device application and their characteristics were investigated as a function of Sr content(x) and applied field. Thin films showed a homogeneous microstructure and the tetragonality(c/a) was slightly decreased with increasing Sr content. With increasing Sr content, Curie temperature of the thin films showed a decreasing tendency. For the PST thin films, the dielectric constant at room temperature, Tc, and $tan{\delta}$ were 750~1900, $-70^{\circ}{\sim}-30^{\circ}C$ and 0.025~0.04, respectively.

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Dielectric and Strain Properties of PMN-PT Ceramics Doped with $\textrm{SrTiO}^3$ and excess MgO ($\textrm{SrTiO}^3$ 와 과잉 MgO가 첨가된 $\textrm{Pb(Mg_{1/3}Nb_{2/3})O}_3$ - $\textrm{PbTiO}^3$ 계 세라믹스의 유전 및 변위 특성)

  • 이상훈
    • Journal of the Korean Institute of Telematics and Electronics T
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    • v.36T no.3
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    • pp.7-12
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    • 1999
  • In this paper, dielectric and strain properties of (1-f-y)PMN-yPT-xST ceramics investigated with the amount of $\textrm{SrTiO}^3$(ST). The $\textrm{SrTiO}^3$ content is ranged within 1~6㏖%. Another compositions with excess MgO also investigated. As the amount of ST is increased, dielectric constant has a maximum value at 5㏖% composition. The Curie temperature is decreased linearly with increasing the amount of ST. Coercive field and ramnant polarization has a maximum value at l㏖% composition. As for the effects of excess MgO, the dielectric constant has been increased by the addition of excess MgO up to 3㏖% to a 0.8PMN-0.12PT-0.04ST specimen. But the strain has been decreased by the addition of excess MgO.

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Effects of Bi$_2$O$_3$.3TiO$_2$ on the Dielectric Properties of Ceramics in the system (Sr.Pb)TiO$_3$ ((Sr.Pb)TiO$_3$계 세라믹의 유전특성에 미치는 Bi$_2$O$_3$.3TiO$_2$의 영향)

  • 최운식;김충혁;홍진웅;김재환;이준웅
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1990.10a
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    • pp.68-70
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    • 1990
  • (1-X)(Sr$\_$7/9/Pb$\_$2/9/)$\_$(1-y)/(Ca$\_$1/5/Mg$\_$4/5/)$\_$y/TiO$_3$+X(BiO$_2$O$_3$$.$3TiO$_2$) (y=0.145, 0$\leq$X$\leq$0.08) ceramics were fabricated by the mixed oxide method. The sintering temperature and time were 1180∼1230[$^{\circ}C$], 2[hr], respectly. The grain size were grown with increasing the contents of Bi$_2$O$_3$$.$3TiO$_2$, but decreased more and less in the specimens which had more than 0.04[mol].