Two pyridinecarboxamide dicyanidecobalt(III) building blocks and two mononuclear seven-coordinated macrocycle manganese(II) compounds have been rationally selected to assemble cyanide-bridged heterobimetallic complexes, resulting in three cyanide-bridged $Co^{III}-Mn^{II}$ complexes. Single X-ray diffraction analysis show that these complexes $\{[Mn(L^1)][Co(bpb)]\}ClO_4{\cdot}CH_3OH{\cdot}0.5H_2O$ ($\mathbf{1}$), $\{[Mn(L^2)][Co(bpb)]\}ClO_4{\cdot}0.5CH_3OH$ ($\mathbf{2}$) and ${[Mn(L^1)][Co(bpb)]\}ClO_4{\cdot}H_2O$ ($\mathbf{3}$) ($L^1$ = 3,6-diazaoctane-1,8-diamine, $L^2$ = 3,6-dioxaoctano-1,8-diamine; $bpb2^{2-}$ = 1,2-bis(pyridine-2-carboxamido)benzenate, $bpmb2^{2-}$ = 1,2-bis(pyridine-2-carboxamido)-4-methyl-benzenate) all present predictable one-dimensional single chain structures. The molecular structures of these one-dimensional complexes consists of alternating units of $[Mn(L)]^{2+}$ ($L=L^1$ or $L^2$) and $[Co(L^{\prime})(CN)2]^-$ ($L^{\prime}=bpb2^{2-}$, or $bpmb2^{2-}$), forming a cyanide-bridged cationic polymeric chain with free $ClO_4{^-}$ as the balance anion. The coordination geometry of manganese(II) ion in the three one-dimensional complexes is a slightly distorted pentagonal-bipyrimidal with two cyanide nitrogen atoms at the trans positions and $N_5$ or $N_3O_2$ coordinating mode at the equatorial plane from ligand $L^1$ or $L^2$. Investigation over magnetic properties of these complexes reveals that the very weak magnetic coupling between neighboring Mn(II) ions connected by the diamagnetic dicyanidecobalt(III) building block. A best-fit to the magnetic susceptibility of complex ${\mathbf}{1}$ leads to the magnetic coupling constants $J=-0.084(3)cm^{-1}$.
Japanese red pines growing along the Taebaek mountains have been called "Kangsong" and considered to be superior in growth and wood quality. An attempt was made to determine whether their boundaries for planting may be expanded by testing their early growth at eight experimental plantations of the Republic of Korea. Seeds were collected from the six different natural populations including Uljin in Kyongbuk province. For the provenance test, they were planted in eight different regions including Taean in the spring of 1987. Experimental planting was a randomized complete block design with 3 replications. Height growth was measured at the ages of 2, 4, and 6 after planting, and the diameter at root collar at the age of 6 after planting. Significant variation in height growth was observed among the plantations. The height growth measured at the age of 6 after planting showed a positive correlation with the latitude of the test plantation, and the contents of phosphate, potassium and calcium in the soil. A negative correlation, however, was observed between the longitude of the test plantation and height growth. Ponghwa provenance appeared to be the best among the provenances in that the trees from the area grew 16% better in volume growth than the average of all the trees tested in the study, while the worst one was Kyongju from which trees grew 11% less than the average.
This study has been conducted to estimate the proper amount of phosphatic fertilizer required to increase-yield in growing soybeans on newly reclaimed-sterile land which is short of phosphatic fertilizer. IKSAN, the variety chosen for this study, was planted, using the plant spacing $60cm{\times}30cm$. Phosphatic fertilizer was applied in 4 levels in none, standard, double, and triple amount. and at the same time, nitrogen and postassium were applied only in standard amount. Randomized block design was applied in arranging the experimental plots. A series of results acquired are summarized as follows. 1. The fact was recognized that only the standard amount of phosphatic fertilizer is effective for increasing the pod numbers and the soybean yield per l0a. 2. The difference in stem length and stem diameter was very remarkable even among individual plants in the same plot, Throughout all four of the plots there were difference in stem length and stem diameter. That is to say, any invariable tendency on them due to the amount of phosphatic fertilizer applied could not be observed at all. 3. It was recognized that amount of phosphatic fertilizer applied did not have a considerable influence upon the weight of the seeds and the number of seeds contained in 0.l8ι. 4. It was observed that the weight of 1000 seeds was strikingly increased as far as double the amount phosphatic fertilizer.
Mavis, Brempong Badu;Hwang, Hyun Young;Lee, Sang Min;Lee, Cho Rong;An, Nan Hee
Journal of the Korea Organic Resources Recycling Association
/
v.30
no.4
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pp.151-163
/
2022
This study was conducted to promote organic fertilizer(s) that sustain soil productivity for corn production and protect the environment as required by the Act on the promotion of eco-friendly agriculture. It was conducted at the research station of the Organic Agriculture Division of the National Institute of Agricultural. The treatments consisted of Compost (Com), Bokashi as fermented organic fertilizer (FOF), and mixed expeller pressed cake (PC). They were applied at 174 kg N /ha to field corn, together with a 'no fertilizer' check in Randomized Complete Block Design. At eight weeks after transplanting (WAT) corn, compost increased soil carbon (C) and nitrogen (N) to 7.48 and 0.76 g/kg respectively, while other fertilizers maintained the initial levels (before treatment application). At corn harvest (13 WAT), soil chemical properties (total C, total N, pH, electrical conductivity, P2O5, Ca, K, and Mg) were similar among all organic fertilizer treatments. For soil respiration, FOF increased soil CO2 respiration by 31-76% above other fertilizer treatments. However, there were no prominent changes in the trends of CH4 fluxes following the two mechanical weeding operations. Fermented organic fertilizer affected N2O emissions between 87-96% lower than other fertilizer treatments. Compared to the initial microbial densities, FOF increased fungi and actinomycete colony foming unit by 25 and 16% at harvest. Therefore, the additional potential of improving soil biological fertility and local availability of raw materials make FOF a better option to sustain soil productivity while protecting the environment.
Jun Sik Woo;Gyeong Rim Ryu;Jeong Hoon Kim;Sun Sik Jang;Hong Gu Lee;Keun Kyu Park
Animal Bioscience
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v.37
no.7
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pp.1303-1315
/
2024
Objective: This study aimed to determine the effects of increasing energy and protein levels in diets by including protected fat (PF), glycerol (GL), and soybean meal (SBM) on growth performance, physiological parameters, carcass characteristics, and behavioral measurements of late-fattening Hanwoo steers under heat stress conditions. Methods: Thirty-six steers (initial body weight, 724.9±58.3 kg; age, 25.5±0.4 month) were assigned into control (total digestible nutrient [TDN] 76%, crude protein [CP] 15%), PF (TDN 83.6%, CP 15%), PF+GL (TDN 83.6%, CP 15%) and PF+GL+SBM (TDN 83.6%, CP 16.5%) by randomized complete block design for a total of 16 weeks with division of 4-week periods. The average temperature-humidity index was 87.0 (1st period; severe), 82.8 (2nd; moderate), 71.4 (3rd; comfort), and 68.1 (4th; comfort). Results: The dry matter intake (DMI) showed no treatments differences during the whole experiment. However, DMI in 1st and 2nd period decreased by approximately 30% and 10% compared to 4th period, respectively. Higher average daily gain and feed conversion ratio were noted for treatments compared to control at both 1st and 2nd period (p<0.05). There were no treatment effects on rectal temperature (RT), cortisol, and behaviors during the entire experiment. However, both RT and cortisol in 0, 1st and 2nd period were higher than those of 3rd and 4th period (p<0.05). Carcass yield and grade remained unaffected by increasing TDN and CP levels. Behavioral changes in the hot season (1st period) included reduced lying (43%), increased standing (48%), decreased walking (62%), and decreased eating (38%) (p<0.05), with an increase in drinking by 54%. Rumination during standing was 53% higher, while rumination during lying was about 33% lower compared to the post-hot season (3rd period) (p<0.05). Conclusion: Dietary supplementation of protected fat in late-fattening Hanwoo steers under heat stress had a positive effect on preventing a reduction in performance.
This study was conducted to investigate bird community and to suggest a proper way how to manage protect bird community in Gap stream. The survey was carried out over four sections by the line transect method and point counts method from September 2001 to August 2002. Natural stream region as Gasuwon Bridge - Mannyeon Bridge are observed birds were 11 orders 29 families 67 species, Artificial stream region as Mannyeon Bridge - Daedeok Bridge are observed birds were 6 orders 10 families 30 species, Daedeok Bridge - Wonchon Bridge are 8 orders 12 families 28 species, Wonchon Bridge - Gap Stream Bridge are 8 orders 18 families 40 species. All the observed birds in artificial stream region are 8 orders 19 families 47 species. Number of species in natural stream region was higher than artificial stream region owe to a various habitat environment such as forest, cultivated land, streamside forest, sandy plain, gravelly field, reedy field etc. and can not add with the interface and the usage of the human. Number of species in artificial stream region was lower than natural stream region owe to a simple habitat environment and the water ecosystem is severed with embankment block and grass plot with the land ecosystem. The furtherance of various habitat environment which considers the ecosystem like the natural stream as the water ecosystem is joined together with the land ecosystem is desired to attract various wildbirds in Gap stream. The design is desired with the maintenance of the stream to consider the stream corridor which plays ecological important role as connect the fragment habitats.
Journal of The Korean Society of Grassland and Forage Science
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v.27
no.3
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pp.167-172
/
2007
Manure recycle is an emerging issue in agriculture in Korea these days. Farmers are keeping eye on legume mixture with grasses for nitrogen fixation and transfer to companion crops by legumes. We had a trial to investigate the effect of different legume mixtures on nitrogen fixation and transfer in spring soil. The treatment was arranged in a randomized complete block design with three replications. Three different mixtures were used(rye+hairy vetch, Italian ryegrass+crimson clover, oat+pea) and sowed in pots with paddy soil from western part of Korea(Seo Chon County). Pots with rye+vetch were transplanted from field of RDA(rural development administration) in Suwon on 2 February 2007 and other mixture treatments were sowed on early March with different sowing rate(7:3=Italian:crimson, 6:4=oat:pea). $(^{15}NH_4)_2SO_4$ solution at. $99.8\;atom%^{15}N$ was applied to the each pot at the rate of $2kg\;N\;ha^{-1}$. Application was done on 6 April at rye+vetch pots and remainder were applied on April 16. Forage were harvested from each pot at ground level in heading stage and separated into legume and grass. Total N content and $^{15}N$ value were determined using a continuous flow stable isotope ratio mass spectrometry. DM yield of rye+vetch, Italian+crimson and oat+pea were 6,607, 3,213 and 4,312 kg/ha, respectively. Proportion of N from fixation was 0.73(rye+vetch), 0.42(Italian+crimson) and 0.93(oat+pea). The percentages of N transfer from legume to grass were from 61% to 24% in different method by treatment and -35% to 21% in isotope dilution method.
Studies were carried out using growing to finishing pigs to investigate adequate floor space ($m^2/pig$) in Jeju environment. A randomized block design was used to compare the effect of pig performance on 3 stocking rates (low $0.56 m^2/pig$, medium 0.70 and high 0.90). Liveweight gain and feed intake were measured over a 4 week(Growth stage 1 and Growth stage 2) period or a 3 week(Growth stage 3) period. In growth stage 1 (43 to 65 kg body weight ; BW), daily weight gain was significantly higher in the medium stocking rate than in low or high (P<0.05). However, no significant difference in daily weight gain was found among treatments in growth stage 2(65 to 91 kg) or 3 (91 to 105 kg). Dressing percentage, back fat thickness and carcass grade were also not different (P>0.05). In conclusion, daily weight gain of pigs reared in medium density appeared to be higher than in the other groups during the early growing period which is $0.70m^2/pig$ and similar to that recommended by National Livestock Research Institute, RDA.
This study was conducted to evaluate the effects of bastnasite nitrate fertilizer (BNF) on the growth of creeping bentgrass. Fertilizer treatments were designed as follows; non-fertilizer (NF), control (CF; compound fertilizer), RE-l (CF+0.3 $g{\cdot}m^{-2}$BNF), RE-2 (CF+0.5 $g{\cdot}m^{-2}$BNF), RE-3 (CF+1.0 $g{\cdot}m^{-2}$BNF) and RE-4 (0.5 $g{\cdot}m^{-2}$BNF). Every treatment was arranged in a randomized complete block design with three replications. In creeping bentgrass, turf qualities such as turf color index and chlorophyll index, shoot number, clipping dry weight and nutrients of tissue were measured. It was hardly affected by BNF application in investigation of chemical properties of the soil. By applying BNF, turf color index and chlorophyll index in RE-2 were increased 3.9% and 9.2% more than NF. As applied BNF on creeping bentgrass, shoot number was increased 9% in RE-4 more than NF and 22% in RE~2 more than CF. It was increased in N uptake and clipping dry weight of creeping bentgrass by supplying BNF. These results indicated that the BNF application promoted a turf qualities and a growth of creeping bentgrass by advancing N uptake and shoot number.
In order to improve the spatial resolution of the gamma camera, the size of the hole in the collimator must be reduced, so the sensitivity is reduced. In order to improve the sensitivity, the size of the hole must be increased, and thus the spatial resolution is reduced. In other words, spatial resolution and sensitivity show opposite characteristics. In this study, a gamma camera was designed to improve both spatial resolution and sensitivity. In order to obtain higher sensitivity in gamma cameras with the same spatial resolution, the structure of the scintillator was designed differently from the existing system. A scintillation pixel was used, and a partition wall was placed between the scintillation pixels to prevent incident gamma rays from being transmitted to other scintillation pixels to interact. Geant4 Application for Tomographic Emission (GATE) simulation was performed to evaluate the performance of the designed gamma camera. When the same sensitivity as the block-type scintillator was obtained, the spatial resolution increased by 16.5%, and when the same spatial resolution was obtained, the sensitivity increased by 61.5%. It is considered that the use of the gamma camera designed in this study can improve the sensitivity compared to the existing system while securing excellent spatial resolution.
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