• Journal of the Korean Electrochemical Society
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• v.18 no.1
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• pp.24-30
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• 2015

To desalinate the aqueous solutions with high salt concentration using the capacitive deionization technology, two resin/membrane capacitive deionization(RMCDI) cells were fabricated by filling mixed ion exchange resins in two different flow channels (spacer and spiral type). The salt removal efficiency of the spacer- and spiral-RMCDI was 77.21 and 99.94%, respectively. Many ions were significantly removed in a spiral RMCDI cell because the feed solution could be more evenly contacted with the ion exchange resins filled on the spiral type flow channel. As the result of the changes of pH and accumulative charges, it was observed that Faradaic reaction was diminished for a spiral RMCDI cell filled by the mixture of cation and anion exchange resins. Therefore, the desalination of the aqueous solutions with high salt concentration by the capacitive deionization technology was proven. In addition, further studies on the optimization of the mixing ratio with ion exchange resins and the introduction of the regeneration process generally occurred in the continuous electrodeionization (CEDI) technology are required to improve the RMCDI technology.

• Membrane and Water Treatment
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• v.1 no.3
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• pp.215-230
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• 2010

Poly(vinylidene fluoride-co-hexafluoropropylene), PVDF-HFP, hollow fiber membranes were prepared by the dry/wet spinning technique using different polyethylene glycol (PEG) concentrations as non-solvent additive in the dope solution. Two different PEG concentrations (3 and 5 wt.%). The morphology and structural characteristics of the hollow fiber membranes were studied by means of optical microscopy, scanning electron microscopy, atomic force microscopy (AFM) and void volume fraction. The experimental permeate flux and the salt (NaCl) rejection factor were determined using direct contact membrane distillation (DCMD) process. An increase of the PEG content in the spinning solution resulted in a faster coagulation of the PVDF-HFP copolymer and a transition of the cross-section internal layer structure from a sponge-type structure to a finger-type structure. Pore size, nodule size and roughness parameters of both the internal and external hollow fiber surfaces were determined by AFM. It was observed that both the pore size and roughness of the internal surface of the hollow fibers enhanced with increasing the PEG concentration, whereas no change was observed at the outer surface. The void volume fraction increased with the increase of the PEG content in the spinning solution resulting in a higher DCMD flux and a smaller salt rejection factor.

• Applied Chemistry for Engineering
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• v.24 no.3
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• pp.247-252
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• 2013

Sulfonated poly(ether ether ketone) (SPEEK) with a certain degree of sulfonation were synthesized by reacting PEEK and sulfuric acid at different reaction time. Then ion-selective composite carbon electrodes (ISCCE) were fabricated by coating the prepared SPEEK on the surface of carbon electrodes. The specific capacitance and resistance of the ISCCE were analyzed by electrical impedance spectroscopy. The ion exchange capacities (IEC) of the SPEEKs were measured in the range of 1.60~2.57 meq/g depending on the sulfonation time. The SPEEK more than 2.5 meq/g of IEC was considered unsuitable for fabricating the ISCCE because it was dissolved in water. The specific capacitance of the prepared ISCCE increased with increasing the IEC of coated SPEEKs and the capacitance was improved up to about 20% compared to that of uncoated carbon electrode. In addition, the electrical resistance of coating layer decreased significantly with increasing the IEC of coated SPEEKs. It is expected that the desalination efficiency of conventional capacitive deionization process can be improved by using the prepared ISCCE coated with SPEEK.

• Journal of the Korean Institute of Intelligent Systems
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• v.24 no.3
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• pp.330-336
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• 2014

Many industrial processes such as continuous stirred tank reactors(CSTRs), desalination plant, distillation columns, pH neutralization processes and so on exhibit highly nonlinear characteristic and time-varying behavior during operation. The control of such processes has been challenging to control engineers. Hence, a variety of forms of PID controllers and their tuning rules for industrial processes have been developed to guarantee the best performance. In this paper, a scheme that designs the practical PID controller with an anti-windup strategy incorporating with an evolutionary algorithm(EA) is presented for the concentration control of a nonisothermal CSTR. EA is used to tune the parameters of the overall PID control process with anti-windup by minimizing the integral of absolute error(IAE). Simulation works for reference tracking and disturbance rejecting performances and robustness to parameter changes show the feasibility of using the proposed method.

• Membrane Journal
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• v.30 no.5
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• pp.293-306
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• 2020

Increasing harmful effects of climate change, such as its effect on water scarcity, has led to a focus on developing effective water purification methods to obtain pure water. Additionally, rising levels of water pollution is increasing levels of environmental degradation, calling for sources of water treatment to remove contaminants. To purify water, osmotic processes across a semipermeable membrane can take place, and recent studies are showing that incorporating nanoparticles, including carbon quantum dots (CQDs), graphene carbon dots (GQDs), and graphene oxide quantum dots (GOQDs) are making thin film composite (TFC) membranes more effective by increasing water flux while maintaining similar levels of salt rejection, increasing the hydrophilicity of the membrane surface, showing bactericidal properties, exhibiting antifouling properties to prevent accumulation of bacteria or other microorganisms from reducing the effectiveness of the membrane, and more. In the review, the synthesis process, applications, functionality, properties, and the role of several types of quantum dots are discussed in the composite membrane for water purification.

• Journal of The Korean Society of Agricultural Engineers
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• v.55 no.6
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• pp.69-75
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• 2013

Miscanthus has received wide attention as an option for biomass production in Korea, recently. New strain of giant miscanthus has been developed and was planted in two large trial sites (184 ha) in the lower reaches of the Geum River. To evaluate the susceptibility of the giant miscanthus as an bioenergy crop for the future, we investigated the influence of the giant miscanthus on the soil properties. The particle size, CEC, pH, EC, T-N, T-P, heavy metal total concentration, and heavy metal fractions of soil samples collected from abandoned field, 1 year old giant miscanthus field (1st Year GM), and 2 year old giant miscanthus field (2nd Year GM) at different depths of 0~15, 15~30, and 30~45 cm in April and August were analyzed. Results showed that the CEC and pH of the soil of the giant miscanthus field were lower than those of the soil of abandoned field. The EC of 2nd GM was lower than that of abandoned field, indicating that the giant miscanthus may facilitate soil desalination process. The organic and sulfide fraction and residual fraction of heavy metals in the giant miscanthus field was higher than in abandoned field, due to the low pH of the giant miscanthus field and the excretion of phytosiderophores by rhizome of the giant miscanthus. This study showed that the giant miscanthus can influence on the soil properties and further study for long term is needed to elucidate the interaction between the soil and the giant miscanthus.

• Korean Chemical Engineering Research
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• v.52 no.3
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• pp.328-334
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• 2014

This study examined the effect of concentration polarization on permeate flux in forward osmosis (FO) membrane process for saline and sucrose solution. The reduction in permeate flux during the FO membrane process is largely due to the formation of concentration polarization on membrane surfaces. The flux reduction due to internal concentration polarization formed on the porous support layer was larger than that due to the external concentration polarization on the active membrane surface. Water permeate flux through the FO membrane increased nonlinearly with the increase in osmotic pressure. The water permeability coefficient was $1.8081{\times}10^{-7}m/s{\cdot}atm$ for draw solution on active layer (DS-AL) mode and $1.0957{\times}10^{-7}m/s{\cdot}atm$ for draw solution on support layer (DS-SL) mode in NaCl solution system. The corresponding membrane resistance was $5.5306{\times}10^6$ and $9.1266{\times}10^6s{\cdot}atm/m$, respectively. With respect to the sucrose solution, the permeate flux for DS-AL mode was 1.33~1.90 times higher than that for DS-SL mode. The corresponding variation in the permeation flux (J) due to osmotic pressure (${\pi}$) would be expressed as $J=-0.0177+0.4506{\pi}-0.0032{\pi}^2$ for the forward and $J=0.0948+0.3292{\pi}-0.0037{\pi}^2$ for the latter.

• Korean Chemical Engineering Research
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• v.49 no.6
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• pp.810-815
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• 2011

Concentrated water discharged from seawater desalination process contains a high concentration of $Na^+$ ion. Electrolysis was applied to synthesize NaOH solution from the highly concentrated NaCl solution. The effect of various operating parameters of composited laboratory-scale chlor-alkali (CA) membrane cell was investigated. The operating parameters such as membrane types (CIMS and Nafion membranes), pretreatment of the membrane, flow rate (73 mL/min~200 mL/min), initial $Na^+$ ion concentration (1.5 M, 3M and 5 M) and current (1.5A and 2A) were evaluated. It was observed that synthesis efficiency of NaOH solution with CIMS membrane was higher than that with Nafion membrane, but the durability of CIMS membrane on $Cl_2$ gas was poor. The synthesis efficiency of NaOH solution increased with increasing initial $Na^+$ ion concentration and current, while the efficiency decreased with increasing flow rate using Nafion membrane.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.6
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• pp.721-728
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• 2016

97% of water on earth exists in the form of seawater. Therefore, the use of marine resources is one of the most important research issues at present. The use of seawater is expanding in various fields (seawater desalination, cooling water for nuclear power plants, deep seawater utilization, etc.). Seawater intake systems utilizing sand filters in order to take in clean seawater are being actively employed. For the intake pipe used in this system, assuring equal intake flows through the respective holes is very important to improve the efficiency of the intake and filtering process. In this study, we analyzed the efficiency of the dual structure perforated pipe used in the seawater intake system using 3D numerical simulations and the inflow rate according to the gap of the up holes. In the case of decreasing gaps in the up holes toward the pipe end, the variation of the total inflow rate was small in comparison with the other cases. However, the standard deviation of the inflow rate through the up holes was the lowest in this case. Also, stable flow occurred, which can improve the efficiency of the intake process. In the future, a sensitivity analysis of the various conditions should be performed based on the results of this study, in order to determine the factors influencing the efficiency, which can then be utilized to derive optimal designs suitable for specific environments.

• Journal of the Korean Society for Marine Environment & Energy
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• v.17 no.4
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• pp.333-337
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• 2014

The purpose of this study is to develop a process technology to produce high hardness concentrated seawater removing chloride ions but containing useful minerals such as magnesium and calcium in the seawater desalination process. In order to make high hardness concentrated seawater, evaporation system is mostly used recently. Because evaporation system requires a large amount of energy consumption, in this study, it was aimed to produce high hardness concentrated seawater using membrane filtration requiring less energy. Nano filtration membranes were used for the experiments, and different types of high hardness concentrated seawater was produced depending on the membranes' specification, the number of times being concentrated, and pressure. As a result, at between 15bar and 20 bar in pressure, in between the second and the third times of concentration, the experiment result showed the best economic efficiency. By the experiment, production of high hardness concentrated seawater seemed to have a good economic feasibility.