• Journal of the Korean Society for Precision Engineering
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• v.29 no.8
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• pp.887-895
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• 2012

Lamb waves have received a great attention in the structural health monitoring (SHM) societies because they can propagate over relatively large distances in wave guides such as thin plates and shells. The time-of-flights of Lamb waves can be used to detect damages in a wave guide. However, due to the inherent dispersive and multi-mode characteristics of Lamb waves, one must decompose the Lamb wave modes into the symmetric and anti-symmetric modes for SHM applications. Thus, this paper proposes a decomposition method for the two-mode Lamb waves based on two rules: the group velocity ratio rule and the mode amplitude ratio rule. The group velocity ratio rule means that the ratio of the group velocities of fundamental symmetric and anti-symmetric modes is constant, while the mode amplitude ratio rule means that the magnitude of the fundamental symmetric modes of all measured response signals should be always larger than those of the anti-symmetric mode once the input signal is applied so that the magnitude of fundamental symmetric mode of excited Lamb-wave is larger than that of anti-symmetric mode, and vice versa. The proposed method is verified through the experiments ducted for an aluminum plate specimen.

• Analytical Science and Technology
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• v.10 no.3
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• pp.179-186
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• 1997

This study was carried out to improve the analytical method for determination of germanium in plants by atomic absorption spectrometry with graphite furnace. For the decomposition of plant samples, the mixed acid of $HNO_3+HClO_4+H_2SO_4$(10 : 4 : 1, v/v) was used. Under this condition, time requirement for the decomposition was 4~5 days and recovery rate was more than 98%. Solution for filling up to constant volume after decomposition was 0.1M acetic acid-sodium acetate. Detection limit for determination of germanium was 0.02 ppm by atomic absorption spectrometry with graphite furnace and argon gas. These results were corresponded with the above-mentioned research projects for improving the determination method of germanium in plants.

• Journal of Energy Engineering
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• v.21 no.4
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• pp.373-377
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• 2012

Among the fossil fuels, the brown coal is a great deal of resources. However, it is hardly used due to the high moisture content and low calorific value. It has both the week points such as spontaneous combustion and high volatile content and the strong points such as the low-sulfur and low ash content. If we overcome these week points, the using amount of brown coal would be increased. Also, it is well known that biomass is one of the important primary renewable energy sources because of carbon neutral energy. Furthermore, the utilization of biomass has been more and more concerned with the depletion of fossil fuel sources as well as the global warming issues. Combustion and thermal decomposition of biomass is one of the more promising techniques among all alternatives proposed for the production of energy from biomass. In this study, combustion of brown coals and mushroom waste was done. Mass change of samples and emission of hydrocarbon components were measured. As the results, we obtained combustion rate constant. Also activation energy was calculated in char combustion step. Hydrocarbon components were more generated in low oxygen concentration than high. Emission amount of hydrocarbon components in mushroom waste was significantly increased comparing to brown coal.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.17 no.5
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• pp.486-491
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• 2004

Dimensionally stable anode(DSA) can be used for the hydro-metallurgy of non-ferrous metals like as Zn, and the electrolysis of sea water. MnO$_2$ electrode satisfies the requirements of DSA, and has a good cycle life and a low overpotential for oxygen evolution. MnO$_2$ electrodes based on Ti matrix were prepared by using thermal decomposition method and also MnO$_2$ was coated on Ti and Pb matrix with DMF and PVDF compositions. The MnO$_2$ electrodes prepared by thermal decomposition method had very weak adhesive strength onto Ti matrix and MnO$_2$ layer was removed out so that electrochemical properties for MnO$_2$ were not investigated. The viscosity of solvent used as a binder of MnO$_2$ Powder increased with the increasing PVDF contents. The thickness of the MnO$_2$ layer on Pb matrix in DSA, which was prepared with 5 times dipping at the solution mixed with PVDF : DMF = 1 : 9, was 150${\mu}{\textrm}{m}$. When the ratio of PVDF to MnO$_2$ was lower than 1 : 6, the Pb electrode didn't show any reaction irrespective of the concentrations of DMF. However, When the ratio of PVDF to MnO$_2$ was higher than 1: 6, the Pb electrode showed constant current reactions and homogeneous cyclic voltammetry even though at a high cycle. The reason for the high current and homogeneous cyclic voltammetry is the good catalytic reactions of MnO$_2$ powder in electrode.

• Journal of Broadcast Engineering
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• v.4 no.2
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• pp.144-154
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• 1999

The binomial sequences are family of orthogonal sequences that can be generated with remarkable simplicity-no multiplications are necessary. This paper introduces a class of non-recursive multidimensional filters for frequency-selective image processing without multiplication operations. The magnitude responses are narrow-band. approximately gaussian-shaped with center frequencies which can be positioned to yield low-pass. band-pass. or high-pass filtering. Algorithms for the efficient implementation of these filters in software or in hardware are described. Also. we show that the binomial QMFs are the maximally flat magnitude square Perfect Reconstruction paraunitary filters with good compression capability and these are shown to be wavelet filters as well. In wavelet transform the original image is decomposed at different scales using a pyramidal algorithm architecture. The decomposition is along the vertical and horizontal direction and maintains constant the number of pixels required to describe the images. An efficient perfect reconstruction binomial QMF-Wavelet signal decomposition structure is proposed. The technique provides a set of filter solutions with very good amplitude responses and band split. The proposed binomial QMF-filter structure is efficient, simple to implement on VLSl. and suitable for multi-resolution signal decomposition and coding applications.

• Bulletin of the Korean Chemical Society
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• v.24 no.3
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• pp.350-356
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• 2003

The mechanism of the decomposition of a bronchodilator, S-nitroso-N-acetyl-D,L-penicillamine (SNAP) by a bronchoconstrictor, aqueous sulfite, has been investigated in detail. The decomposition was studied using a conventional spectrophotometer at 336 nm over the ranges: 0.010 ≤ $[S^{IV}]_T$ ≤ 0.045 mol $dm^{-3}$, 3.96 ≤ pH ≤ 6.80 and 15.0 ≤ θ≤ 30.0 ℃, 0.60 ≤ I ≤ 1.00 mol $dm^{-3}$, and at ionic strength 1.00 mol $dm^{-3}$ (NaCl). The rate of reaction is dependent on the total sulfite concentration and pH in a complex manner, i.e., $k_{obs}\;=\;k_1K_2[S^{IV}]_T/ ([H^+]\;+\;K_2)$. At 25.0 ℃, the second order rate constant, $k_1$, was determined as $12.5\;{\pm}\;0.15\;mol^{-1}\;dm^3\;s^{-1}$. ${\Delta}H^{neq}\;=\;+32\;{\pm}\;3 kJ\;mol^{-1}\;and\;{\Delta}S^{\neq}\;=\;-138\;{\pm}\;13\;J\;mol^{-1}K^{-1}$. The N-nitrosohydroxylamine-N-sulfonate ion was detected as an intermediate before the formation of any of the by-products, namely, N-acetyl-D,L-penicillamine. The effect of concentration of aqueous copper(Ⅱ) ions on this reaction was also examined at pH 4.75, but there was no dependence on $[Cu^{2+}]$. In addition, the $pK_a$ of SNAP was determined as 3.51 ± 0.06 at 25.4 ℃ [I = 1.0 mol $dm^{-3}$ (NaCl)].

• Journal of Pharmaceutical Investigation
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• v.27 no.4
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• pp.253-263
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• 1997

To investigate the interaction of omeprazole (OMP) and meglumine (MEG), a complex was prepared by freeze-drying method in ammoniacal aqueous medium at room temperature and subjected to IR, DSC, and 1H NMR analysis. In addition, the stability of the complex was tested by accelerated stability analysis, and the dissolution rate of both powder and enteric coated was determined pellet by paddle method. The results are as follows; i) IR, DSC, and $^{1}H$ NMR studies indicate the formation of inclusion complex between OMP and MEG probably by electrostatic forces as $[OMP]\;[MEGH]^+$ form in a stoichiometric ratio (1:1) of OMP : MEG. ii) The dissolution rate of enteric coated OMP-MEG complex pellet in simulated enteric fluid was 90.6% in 10 minutes, which may satisfy the requirement for the regulation of dissolution. iii) OMP-MEG complex were decomposed according to pseudo 1st order kinetics: while the decomposition of OMP showed a rate constant $(k_{25^{\circ}C})$ of $5.13{\times}10^{-4}{\cdot}\;day^{-1}$, a half-life$(t_{1/2})$ of 1,350 days, a shelf-life$(T_{90%})$ 205 days and an activation energy of 23.53 kcal/mole. OMP-MEG complex inhibited a rate $(k_{25})$ of $2.92{\times}10^{-4}{\cdot}\;day^{-1}$, a half-life$(t_{1/2})$ of 2,373 days, a shelf-life $(T_{90%})$ of 306 days and an activation energy of 20.18 kcal/mole. iv) OMP was stabilized markedly by the formation of OMP-MEG complex between OMP and MEG, and the humidity increased the stability of OMP-MEG complex by decreasing the decomposition rate$(k_{50^{\circ}C})$ from $1.27{\times}10^{-2}{\cdot}\;day^{-1}$ at 31% R.H. to $2.54{\times}10^{-2}{\cdot}\;day^{-1}$ at 90% R.H.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.10
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• pp.1039-1046
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• 2008

The combining process of UV irradiation and H$_2$O$_2$ was used to investigate characteristics of cefaclor decomposition in the aquatic environment. The separate mixing tank was used to minimize the decreasing effective of contact area caused by sampling. Four baffles were installed inside the UV reactor for the complete mixing of the sample and outside of the reactor was wrapped with aluminum foil to protect the emission of photon energy. Production of OH radical was measured using pCBA(p-Chlorobenzoic acid) indirectly and rate constants were withdrawn pseudo-frist order reaction. Optimum condition for the maximum production of OH radical was found to be pH 3, hydrogen peroxide of 5 mmol/L and recirculation rate of 400 mL/min. Pseudo-frist order reaction rate constant was 0.1051 min$^{-1}$. In the optimum condition, cefaclor was completely decomposed within 40 min and rate constant was 0.093 min$^{-1}$. Decomposition by OH radical producted intermediate anions such as chloride, nitrate, sulfite and acetic acid and phenylglycine. After 6 hr most cefaclor was decomposed by UV/H$_2$O$_2$ process and converted to CO$_2$ and H$_2$O, resulting of operation in the decrease of TOC and acetic acid and the disappearance of phenylglycine.

• Korean Journal of Food Science and Technology
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• v.13 no.3
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• pp.188-193
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• 1981

Thermal degradation of pantothenic acid in potassium biphthalate buffer and in food samples such as rice, mushroom and beef was studied as functions of temperature and pH. Thermal degradation of pantothenic acid in buffer and food systems followed first order reaction at temperature between $60{\sim}104^{\circ}C$. Activation energy calculated from the Arrhenius equation ranged from 15,700 cal/mole 17,300 cal/mole for both systems. D values at $120^{\circ}C$ were approximately 18 hours for food samples and 15.4 hours at pH 5.65 for buffer sample. Z values of food samples were about $37^{\circ}C$, which were similar to those of buffer sample. The decomposition rate constant of pantothenic acid in buffer sample decreased when the pH increased from 4.0 to 6.46, but activation energy increased. In the range of $pH\;6.46{\sim}8.0$, decomposition rate constant increased but activation energy decreased as pH increased. The kinetic model of pantothenic acid decomposition in buffer system was proposed on the basis of empirical relationship.

• Journal of Radiation Industry
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• v.18 no.3
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• pp.235-240
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• 2024

Electron beam technology has recently attracted attention as one of the powerful air pollution control methods. In this study, methyl mercaptan decomposition by electron beam in a continuous gas flow system was studied. To this, the effect of gas flowrate, which is one of important operating variables in the continuous gas flow electron beam process, on methyl mercaptan treatment efficiency was studied. In particular, the treatment efficiency and the reaction kinetics of methyl mercaptan decomposition were compared when calculated based on the absorbed dose and when calculated based on the current intensity of electron beam. When based on the electron beam absorbed dose, the treatment efficiency and 1st-order reaction constant increased as the gas flowrate was increased, contrary to the trends in general chemical reactions. However, when based on the current intensity, the treatment efficiency and 1st-order reaction constant increased as the gas flowrate was decreased, which can be theoretically explained. This is due to the fact that the current intensity increased as the gas flowrate was increased, resulting in improved the electron beam treatment efficiency. In conclusion, it is necessary to consider not only the absorbed dose but also the current intensity of electron beam in order to explain the results of reaction efficiencies and kinetics in the continuous flow electron beam gas treatment process.