• Title/Summary/Keyword: DECAY CONSTANT

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Kinetic Measurements of Irreversible Photobleaching of Bacteriorhodopsin in A High Temperature State

  • Yokoyama, Yasunori;Sonoyama, Masashi;Mitaku, Shigeki
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.296-298
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    • 2002
  • Irreversible photobleaching of bacteriorhodopsin (bR), namely denaturation induced by illumination of visible light, was investigated by absorption kinetic measurements. The denaturation kinetics revealed that light illumination significantly enhanced the structural decay of bR. The kinetic analyses showed that the molecular structure of bR denatures according to a single-exponential decay, whereas irreversible photobleaching has two decay components. The decay constant of the slow component of photobleaching is almost same as that in the dark. An Arrhenius plot of the denaturation kinetic constants for the fast and slow components showed similar activation energies of approximately 19 kcal/mol.

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Characteristics of Residual Free Chlorine Decay in Reclaimed Water (하수재이용수의 유리잔류염소 수체감소 특성 연구)

  • Kang, Sungwon;Lee, Jaiyoung;Lee, Hyundong;Park, Jaehyun;Kwak, Pilljae;Oh, Hyunje
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.4
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    • pp.276-282
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    • 2013
  • The reclaimed water has been highlighted as a representative alternative to solve the lacking water resources. This study examined the reduction of residual free chlorine by temperature (5, 15, $25^{\circ}C$) and initial injection concentration (1, 2, 4, 6 mg/L) in the reclaimed water and carried out propose on the calculating method of the optimal chlorine dosage. As the reclaimed water showed a very fast reaction with chlorine at the intial time comparing to that of drinking water, the existing general first-order decay model ($C_t=C_o(e^{-k_bt})$) was not suitable for use. Accordingly, the reduction of residual free chlorine could be estimated in a more accurate way as a result of applying the exponential first-order decay model ($C_t=a+b(e^{-k_bt})$). ($r^2$=0.872~0.988). As a result of calculating the bulk decay constant, it showed the highest result at 653 $day^{-1}$ under the condition of 1 mg/L, $25^{\circ}C$ for the initial injection whereas it showed the lowest result at 3.42 $day^{-1}$ under the condition of 6 mg/L, $5^{\circ}C$ for the initial injection. The bulk decay constant tends to increase as temperature increases, whereas the bulk decay constant tends to decrease as the initial injection concentration increases. More accurate calculation for optimal chlorine dosage could be done by using the experimental results for 30~5,040 min, after the entire response time is classified into 0~30 min and 30~5,040 min to calculate the optimal chlorine dosage. In addition, as a result of calculating the optimal chlorine dosage by temperature, the relationships of initial chlorine demand (y) by temperature (x) could be obtained such as y=1.409+0.450x to maintain 0.2 mg/L of residual free chlorine at the time after 4 hours from the chlorine injection.

Improvement of the Exponential Experiment System for the Automatical and Accurate Measurement of the Exponential Decay constant (지수감쇠계수의 자동 및 정밀 측정을 위한 지수실험장치 개선)

  • 신희성;장지운;이윤희;황용화;김호동
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.292-303
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    • 2004
  • The previous exponential experiment system has been improved for the automatical and accurate axial movement of the neutron source and detector with attaching the automatical control system which consists of a Programmable Logical Controller(PLC) and a stepping motor set. The automatic control program which controls MCA and PLC consistently has been also developed on the basis of GENIE 2000 Library. The exponential experiments have been carried out for Kori 1 unit spent fuel assemblies, Cl4, Jl4 and G23, and Kori 2 unit spent fuel assembly, J44, using the improved systematical measurement system. As the results, the average exponential decay constants for 4 assemblies are determined to be 0.1302, 0.1267, 0.1247, and 0.1210, respectively, with the application of Poisson regression.

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A Model for Litter Decomposition of the Forest Ecosystem in South Korea (남한의 산림생태계에 있어서의 낙엽의 분해모델)

  • Park, Bong Kyu;In Sook Lee
    • The Korean Journal of Ecology
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    • v.4 no.1_2
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    • pp.38-51
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    • 1981
  • The present investigation was estimated the effect of temperature, precipitatiion, and time on the decomposition of litters with litter bags of Pinus densiffora and Quercus mongolica at Gure where elevation in 50m, and at Nogodan where elevation in 1300m on Mt. Jiri. As the above results, decomposition model was proposed to relation of the environmental conditions. And was investigated the production and decomposition of litters from the stands of various forest communities in Kwangneung, Mt. Jiri and Mt. Halla. The results are as follows; The models for the decay of organic carbon (C) was as follows: $C=Coe^{-Kt}$ (limiting factor;time) $C=Coe^{-K'te}$ (limiting factor;tempedrature) $C=Coe^{-KnP}$ (limiting factor:precipitation) As observed in litter bag method, the decomposition rate of litter in Pinus densiflora was slower than that of Quercus mongolica. The higher elevation, the slower decomposition rate. The decomposition of litters at Gure where elevation in 50m was equally influenced by temperature and precipitation. But at Nogodan where elevation in 1300m was much inflenced by precipitation. The decay constant of litters was larger in hardwood forest than in coniferous forest. In the same species, the more elevatiion, the less decomposition constant. The time required for the decay of 50%, 95^, 99% of the accumulated litters in the forest floor were faster in hardwood forest than in coniferous forest. In the same species, the higher elevatiion, the longer time required.

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A Study on the Surface Properties of Poly(ethylene terephthalate) films by Discharge Treatment (방전처리에 따른 Poly(ethylene terephthalate) 필름의 표면특성에 관한 연구)

  • Lim, K.B.;Lee, B.S.;Lee, S.H.;Hwang, M.W.;Park, G.B.;Park, G.K.;Kim, Y.I.;Lim, H.C.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.1587-1589
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    • 2000
  • In this paper the weight loss, surface potential decay, surface resistivity and dielectric constant are measured to investigate the surface properties, insulation characteristic changes of PET film according to the discharge treatment. As a result of the test, up to the 10[min] the surface potential decay and surface resistivity have increased. Also, from the result of dielectric constant has decreased. On the other hand, the insulation characteristic of PET film have decreased after 10[min] in the discharge treatment.

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The Balance of the Storage and Decay of DNA by Producers and Decomposers in the Ecosystem of a Zoysia japonica Grassland (잔디초지 생태계에 있어서 생산자와 소비자에 의한 DNA의 축적과 분해의 평형)

  • 장남기;김정석;이병설;강경미
    • Asian Journal of Turfgrass Science
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    • v.10 no.4
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    • pp.275-283
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    • 1996
  • An investigation was performed to reveal the relation between the storage and decomposition of the titter DNA of a Zoysia japonica grassland on Mt. Kwanak. The loss constant k of litters was 0.167. The times required for the decomposition of half, 95% and 99% of accumulated DNA on the grassland floor were 3.8, 16.6 and 27.6, respectively. The amount of DNA which is turned to living organism in the ecosystem is higher than that of crude protein. In the case of crude protein, the decay constant k was 0.181. The times needed for the decomposition of half, 95% and 99% of accumulated crude protein on the Z. japonica grassland floor were 3.8, 16.6 and 27.6 years, respectively. Key words: Zoysia japonica, Mt. Kwanak, Litter DNA, Crude protein, Decomposition, Accumulation.

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Surface Analysis of Silicone Polymer used as Insulating Material by XPS and Surface Voltage Decay (XPS 및 Surface voltage decay를 이용한 실리콘 절연재료의 표면분석)

  • Youn, B.H.;Lee, K.T.;Park, C.R.;Kim, N.R.;Seo, Y.J.;Huh, C.S.;Cho, H.G.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.236-239
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    • 2002
  • Surface states of silicone polymer treated by plasma were investigated by the analysis by x-ray photoelectron spectroscopy (XPS) and surface voltage decay. Plasma treatment causes the silica-like oxidative layer, which is confirmed with XPS, and lowers surface resistivity with increasing the plasma treatment time. Using the decay time constant of surface voltage, the calculated surface resistivity was compared with the value directly measured by a voltage-current method. A good agreement between two methods was obtained. In addition, we estimated the thermal activation energy for surface conduction, Based on our results, we could understand the relationship between surface chemical states and surface electrical properties.

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Algorithm for Calculating Uncertainty in the Computational Simulation for Radiochronometry of Nuclear Materials (핵물질 연대추정을 위한 전산모사 불확도 계산 알고리즘)

  • Jae-Chan Park;Tae-Hoon Jeon;Jin-Young Chung;Jung-Ho Song
    • Journal of the Korean Society of Radiology
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    • v.17 no.7
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    • pp.1075-1089
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    • 2023
  • Nuclear forensics is an essential part of nuclear material control and nuclear non-proliferation verification. Radiochronometry for nuclear forensics is used to estimate the timing of refinement and production of nuclear materials based on decay chain characteristics and the Bateman equation. The results of radiochronometry have uncertainties because the decay constant and number of nuclides are statistics derived from analyses or repeated experiments and involve uncertainties. The aim of this study was to develop an uncertainty calculation algorithm by performing computational simulation to overcome the limitations of the existing uncertainty calculation method for radiochronometry based on the Bateman equation. The results of the proposed uncertainty calculation algorithm were comparable to those of the existing method. The algorithm allowed for more than two generations of uncertainty calculations and mitigated the underestimation of the decay constant during the uncertainty calculation.

Application of QUAL2E Model to Water Quality Prediction of the Nam river (남강의 수질예측을 위한 QUAL2E 모델 적용)

  • Choi, Hyoung-Sub;Park, Tae-Ju;Heo, Jong-Soo
    • Korean Journal of Environmental Agriculture
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    • v.14 no.1
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    • pp.7-14
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    • 1995
  • This research was conducted to apply the QUAL2E model to be adopted to the Nam river under current water quality conditions. The survey area of total 60 Km was divided into five reaches. Each reach was then subdivided into the uniform computational elements of 1.5 Km. Based on the stream characteristics, nine sampling stations consisting of six at main streams and three at tributaries were selected. The field data were obtained from the selected stations twice during October of 1991 and May of 1992, which represented the cold weather and low flow, also the warm weather and low flow conditions, respectively. As the results of sensitivity analysis of the model, the important parameters were the rates of BOD decay, Org-N oxidation, $NH_3-N$ oxidation, Org-P decay. The calibrated and verified results by QUAL2E model were correlation coefficient of $0.45{\sim}0.94$. The results displayed a good agreement between the variables of the field measurements and the model simulations, indicating a potential use of the QUAL2E model for the water quality assessment in the Nam River.

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Studies on microbial population affecting the decomposition of fir litter. (전나무낙엽의 분해에 따른 Microbial population의 변화에 관한 연구)

  • Jang, Nam Gi;Im, Yeong Deuk
    • Korean Journal of Microbiology
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    • v.6 no.3
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    • pp.92-92
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    • 1968
  • 1) The aim of present investigation is to elucidate the relation of the balance of the production and decomposition of the fir litter. in Kwangnung plantation stands. 2) The decay constant, K, of litters was 0. 185 for the fir stand at Kwangnung. 3) The mode for the accumulation of organic carbon ($C_a$) is $c_a$= $610(1-e^{-0.185t})$), and for the decay of organic carbon (C) C = $610(1-e^{-0.185t})$. 4) The time required for the decay of half of the accumulated organic carbon in the fir stand is 3. 74 years and for 99% of elimination 27.02 years. 5) The litters of Abies holophylla killed by heat and washed with alcohol-benzol, with hot water, or with both alcohol-benzol and hot water were incubated after inoculated with suspension of firwood soil. Plate counts were made of fungi and bacteria from time to time. 6) Removal of the alcohol-benzol soluble substance stimulates at the beginning of the decay the growth of fungi and also of bacteria. 7) Removal of the water soluble fraction is detrimental to the growth of fungi in particular. 8) The distribution of soil microbial population is higher in both F and H horizon of the fir plantation soil in Kwangnung. However, the number of soil microorganisms decreases with the depth in forest soil.