• Title/Summary/Keyword: Cyclic Structure

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The Electrical Conductivity and Electrochemical Characteristics of Amphiphilic Milecules Multilayer Film confined with Hetero Type (양친매성 다중층막의 전기적 도전성 및 전기적 특성)

  • 최인희;박수길;임기조;이주성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.05a
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    • pp.269-272
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    • 1996
  • The electrochemical behavior of Ru complex and PD complex monolayer, deposited on conductive substrate by the Langmuir-Blodgett(LB) technique as monolayer and multilayer, has been studied by cyclic voltammetry. Monolayer films show stable reversible state. Atomic resolution imaging of LB highly-conductive, environmently stable organic films has been obtained by atomic force microscopy (AFM) showing their closely packed structure,

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An analytical Study on the Elasto-Plastic Behaviour of Steel Structure Member & Frame under Cyclic Load (반복 하중을 받는 강 구조 부재 및 골조의 탄소성 성상에 관한 해석적 연구)

  • 김화중;권영환;박정민
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 1992.10a
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    • pp.52-57
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    • 1992
  • The purpose of this study is that to develop computer program, which is about to analy size nonlinear behaviour of elastic framed structures include to geometric & material nonlineality, and to formulate between stress-strain relationship. In order to examplity the efficiency of this program, a few analytical results have been obtained on : (1) nonlinear behaviour of beam which is subject to vertical force (2) nonlinear behaviour of portal frame which is subject to vertical & horizontal force.

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Synthesis of Trimetallic Au@Pb@Pt Core-shell Nanoparticles and their Electrocatalytic Activity toward Formic Acid and Methanol

  • Patra, Srikanta;Yang, Hae-Sik
    • Bulletin of the Korean Chemical Society
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    • v.30 no.7
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    • pp.1485-1488
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    • 2009
  • A facile, seed-mediated preparation method of trimetallic Au@Pb@Pt core-shell nanoparticles is developed. Au nanoparticles are the template seeds onto which sequentially reduced Pb and Pt are deposited. The trimetallic core-shell structure is confirmed by UV-Vis spectroscopy, TEM and EDS analysis, and cyclic voltammetry. The trimetallic Au@Pb@Pt core-shell nanoparticles show high electrocatalytic activity for formic acid and methanol electrooxidation.

GENERALIZED T-SPACES AND DUALITY

  • YOON, YEON SOO
    • Honam Mathematical Journal
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    • v.27 no.1
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    • pp.101-113
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    • 2005
  • We define and study a concept of $T_A$-space which is closely related to the generalized Gottlieb group. We know that X is a $T_A$-space if and only if there is a map $r:L(A,\;X){\rightarrow}L_0(A,\;X)$ called a $T_A$-structure such that $ri{\sim}1_{L_0(A,\;X)}$. The concepts of $T_{{\Sigma}B}$-spaces are preserved by retraction and product. We also introduce and study a dual concept of $T_A$-space.

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Development of EDLC using aqueous polymeric gel electrolytel (수용성 고분자 젤 전해질을 이용한 전기이중층 커패시터 의 개발)

  • 오길훈;김한주;최원경;박수길
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.581-584
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    • 2001
  • For the first time, a totally solid state electric double layer capacitor has been fabricated using an alkaline polymer electrolyte and an activated carbon powder as electrode material. The polymer electrolyte serves both as separator as well as electrode binder. The capacitor has a three-layer structure; electrode-electrolyte-electrode. A cyclic voltammetry and constant current discharge have been used for the determination of the electro chemical performance of capacitors.

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A Method for Finite Element Vibration Analysis of Rotating Blade Disks (회전하는 익차의 유한요소 진동해석 기법)

  • 김창부;안영철;이동환
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 1997.10a
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    • pp.88-95
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    • 1997
  • In this paper, we present an efficient method for finite element vibration analysis of constantly rotating blade disks which are deformed to some considerable extent by centrifugal force, Coriolis force and operating load, and vibrate due to several types of exciting forces. A blade disk which is a structure with cyclic symmetry is divided into substructures with the same geometry. Only one substructure is modeled and can be analysed rapidly and exactly using discrete Fourier transform by means of a computer with small memory.

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Ozonolyses of Cycloalkenes: Trapping of Carbonyl Oxide by Trifluoroacetophenone

  • 이주연;이치원;허태성
    • Bulletin of the Korean Chemical Society
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    • v.19 no.11
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    • pp.1244-1248
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    • 1998
  • Ozonolysis reactions of cyclic olefins 1a-c and norbomene In in the presence of trifluoroactophenone 6 provided the corresponding cross-ozonides 7a-c and 7n. Further reactions of ozonides 7a-c and 7n with the independently prepared carbonyl oxide 11 gave diozonides of structure l0a-c and 10n. The ozonolysis of 1methylcyclopentene 12a and 1-methylcyclohexene 12b in the presence of trifluoroactophenone 6 provided exclusively ozonide 15 and 16 derived from capture of carbonyl oxide 13. All of the new ozonides have been isolated as pure substances and characterized by their 1H NMR and 13C NMR spectra.

Inelastic displacement ratios for evaluation of stiffness degrading structures with soil structure interaction built on soft soil sites

  • Aydemir, Muberra Eser
    • Structural Engineering and Mechanics
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    • v.45 no.6
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    • pp.741-758
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    • 2013
  • In this study, inelastic displacement ratios are investigated for existing systems with known lateral strength considering soil structure interaction. For this purpose, SDOF systems for period range of 0.1-3.0 s with different hysteretic behaviors are considered for a number of 18 earthquake motions recorded on soft soil. The effect of stiffness degradation on inelastic displacement ratios is investigated. The Modified Clough model is used to represent structures that exhibit significant stiffness degradation when subjected to reverse cyclic loading and the elastoplastic model is used to represent non-degrading structures. Soil structure interaction analyses are conducted by means of equivalent fixed base model effective period, effective damping and effective ductility values differing from fixed-base case. For inelastic time history analyses, Newmark method for step by step time integration was adapted in an in-house computer program. A new equation is proposed for inelastic displacement ratio of system with SSI with elastoplastic or degrading behavior as a function of structural period ($\tilde{T}$), strength reduction factor (R) and period lengthening ratio ($\tilde{T}$/T). The proposed equation for $\tilde{C}_R$ which takes the soil-structure interaction into account should be useful in estimating the inelastic deformation of existing structures with known lateral strength.

Study on mechanical behaviors of column foot joint in traditional timber structure

  • Wang, Juan;He, Jun-Xiao;Yang, Qing-Shan;Yang, Na
    • Structural Engineering and Mechanics
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    • v.66 no.1
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    • pp.1-14
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    • 2018
  • Column is usually floating on the stone base directly with or without positioning tenon in traditional Chinese timber structure. Vertical load originated by the heavy upper structure would induce large friction force and compression force between interfaces of column foot and stone base. This study focused on the mechanical behaviors of column foot joint with consideration of the influence of vertical load. Mechanism of column rocking and stress state of column foot has been explored by theoretical analysis. A nonlinear finite element model of column foot joint has been built and verified using the full-scale test. The verified model is then used to investigate the mechanical behaviors of the joint subjected to cyclic loading with different static vertical loads. Column rocking mechanism and stress distributions of column foot were studied in detail, showing good agreement with the theoretical analysis. Mechanical behaviors of column foot joint and the effects of the vertical load on the seismic behavior of column foot were studied. Result showed that compression stress, restoring moment and stiffness increased with the increase of vertical load. An appropriate vertical load originated by the heavy upper structure would produce certain restoring moment and reset the rocking columns, ensuring the stability of the whole frame.

Effectiveness of seismic isolation in a reinforced concrete structure with soft story

  • Hakan Ozturk;Esengul Cavdar;Gokhan Ozdemir
    • Structural Engineering and Mechanics
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    • v.87 no.5
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    • pp.405-418
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    • 2023
  • This study focused on the effectiveness of seismic isolation technique in case of a reinforced concrete structure with soft story defined as the stiffness irregularity between adjacent stories. In this context, a seismically isolated 3-story reinforced concrete structure was analyzed by gradually increasing the first story height (3.0, 4.5, and 6.0 m). The seismic isolation system of the structure is assumed to be composed of lead rubber bearings (LRB). In the analyses, isolators were modeled by both deteriorating (temperature-dependent analyses) and non-deteriorating (bounding analyses) hysteretic representations. The deterioration in strength of isolator is due to temperature rise in the lead core during cyclic motion. The ground motion pairs used in bi-directional nonlinear dynamic analyses were selected and scaled according to codified procedures. In the analyses, different isolation periods (Tiso) and characteristic strength to weight ratios (Q/W) were considered in order to determine the sensitivity of structural response to the isolator properties. Response quantities under consideration are floor accelerations, and interstory drift ratios. Analyses results are compared for both hysteretic representations of LRBs. Results are also used to assess the significance of the ratio between the horizontal stiffnesses of soft story and isolation system. It is revealed that seismic isolation is a viable method to reduce structural damage in structures with soft story.