• 한국해양공학회지
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• 제22권3호
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• pp.82-88
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• 2008

The diesel engine of the merchant ship has been aperated in severe environments more and more, because the temperature of the exhaust gas of a combustion chamber is getting higher and higher with increasing use of heavy oil of law quality, due to the significant increase in the price of oil in recent some years. As a result, the degree of wear and corrosion between exhaust valve and seat ring is more serious compared to other engine parts. Thus the repair welding of exhaust valve and seat ring is a unique method to prolong the life of the exhaust valve, from an economical point of view. In this study, the corrosion property of both weld metal and base metal was investigated using electrochemical methods such as measurement of corrosion potential, cathodic and anodic polarization curves, cyclic voltammogram, and polarization resistance in 5% H2SO4 solution. The test specimen was a part of an exhaust valve stem being welded as the base metal, using various welding methods. In all cases, the corrosion resistance as well as hardness of the weld metal zone was superior to the base metal. In particular, plasma welding showed relatively good properties for both corrosion resistance and hardness, compared to other welding methods. In the case of DC SMAW (Shielded metal arc welding), corrosion resistance of the weld metal zone was better than that of the base metal, although its hardness was almost same as the base metal.

• Corrosion Science and Technology
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• 제4권1호
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• pp.19-22
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• 2005

Two Au-Ag-Cu-Pd dental casting alloys (Au:12% and 20%) used. The test solutions used 0.9 % NaCl solution (isotonic sodium chloride solution), 0.9 % NaCl solution containing 1 % lactic acid, and 0.9 % NaCl solution containing 1 % lactic acid and 0.1 mol $dm^{-3}$ $Na_2S$. The surface of two samples in three sample solutions was not natural discoloration during one year. The alloy containing 12 % gold was easily alloyed and the composition was uniform comparing with the alloy containing 20 % gold. The rest potentials have not a little effect after three months. The kinds of metals could not definitely from the oxidation and reduction waves of metal on the cyclic voltammograms. The dissolutions of gold and palladium were 12 % Au sample in the 0.9 % NaCl solution containing 1 % lactic acid and 0.1 mol $dm^{-3}$ $Na_{2}S$. The pH of solution had an affect on dissolution of copper, and sulfur ion had an affect on dissolution of silver. The copper dissolved amount from 20 % gold sample was about 26 times comparing with that of 12 % gold sample in the 0.9 % solution containing 1 % lactic acid. Corrosion products were silver chloride and copper chloride in NaCl solution, and silver sulfide and copper sulfide in NaCl solution containing $Na_{2}S$.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2007년도 춘계학술대회A
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• pp.17-22
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• 2007

Low-cycle environmental fatigue tests of cast austenitic stainless steel CF8M at the condition of fatigue strain rate 0.04%/sec were conducted at the pressure and temperature, 15MPa, $315^{\circ}C$ of a operating pressurized water reactor. The used test rig was limited to install an extensometer at the gauge length of the cylindrical fatigue specimen inside the small autoclave. So the magnet type LVDT's were used to measure the fatigue displacement at the specimen shoulders inside the high temperature and high pressure water autoclave. However, the displacement and strain measured at the specimen shoulders is different from the one at the gauge length for the geometry and the cyclic strain hardening effect. FEM calculated the displacement and the strain of the gauge length from the data measured at the shoulders. Tensile test properties in elastic and plastic behavior of CF8M material were used in the FEM analysis. A series of low cycle fatigue tests simulating the cyclic strain hardening effect verified that the FEM calculation was well agreed with the simulated tests. The process and method developed in this study would be so useful to produce reliable environmental fatigue curves of CF8M stainless steel in pressurized water reactors.

• 한국기계가공학회지
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• 제2권4호
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• pp.53-60
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• 2003

Large sized marine structures are used under corrosion environment of seawater and applied by severe service loading such as an ocean current, a billow and a tempest. Marine structures are usually constructed by lots of thick wall steel pipes joining welded joints. The thickness of such as steel pipes is usually more than 40mm. The such as steels are called "Thermo-Mechanical Control Process steel (TMCP steel)" strengthened by a heat treatment in process of steel manufactures. The failure, especially crack initiation, of marine structures was starting at weld joints under service condition. Then they should be designed by basis of the fatigue strength under seawater corrosion environment of weld joints. To clarity the fatigue crack initiation behavior is important more than to clarify the crack propagation behavior on the strength design of marine structures, because it is very difficult to find out the crack initiation and propagation phenomena and then even if it will be able to find out, it is considered that the refit of the damaged parts of welded joints have a technical difficulty under the sea. Therefore, it is most important to clarify the corrosion fatigue crack initiation behavior under the seawater condition. But, there is one big difficulty to make a test for thick plate specimen, for example thicker than 40mm. Because, it is need large capacity loading apparatus to test such as thick plate specimen. In this research, the new configuration specimen for fatigue crack initiation tests was proposed. Using this new specimen, it is easy to carry out the fatigue clack initiation tests with relatively low cyclic loading and to observe a fatigue crack initiation behavior.

• 한국강구조학회 논문집
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• 제28권2호
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• pp.97-108
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• 2016

금속용사 또는 도장은 강구조물의 방식에 널리 사용되고 있다. 금속용사와 도장의 복합피복방식법은 혹독한 부식환경하에 놓인 강구물의 새로운 일반적 피복방식법으로 선택되고 있다. 본 연구에서는 아연, 아연-15%알루미늄 합금, 알루미늄, 알루미늄-5%마그네슘 합금의 4종류 금속용사 후 실링 처리한 시편, 4종류 금속용사 후 중방식 도장한 시편과 도장한 시편에 대해 175일간의 NORSOK M-501 부식촉진실험, 250일간의 해수 Wet/dry 반복 부식실험, 3년간의 해양환경 옥외노출실험을 실시하였다. 그 결과, 외관관찰에 근거하여 각 방식법의 내후성능을 비교, 검토하였다.

• 전기화학회지
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• 제6권4호
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• pp.242-249
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• 2003

아연 전극은 고농도의 KOH전해질 용액의 알카리 전지용 양극재료로 폭넓게 이용되고 있다. 그러나 급속한 전기화학적 반응과 높은 용해도에 의한 수지상의 생성에 의해 사이클 수명이 현저하게 짧아지는 것으로 알려져 있다. 본 연구에서는 용액온도 $25^{\circ}C$의 $40wt.\%$ KOH 전해질에 $Ca(OH)_2$, Citrate, Tartrate 및 Gluconate 등의 첨가제를 첨가하고 그리고 $Pb_3O_4\;5wt\%$를 아연 전극에 혼합하였을 때 아연 전극의 전기화학적 거동에 미치는 Pb,04와 첨가제의 효과를 동전위 분극 곡선, 순환전위전해분석법, 가속수명시험 및 SEM사진 분석을 통하여 고찰하였다. $Pb_3O_4$의 첨가는 아연 전극의 부식 속도를 확실히 감소시키는 효과가 있었으며 그리고 $Pb_3O_4$의 첨가에 의한 아연 전극의 부식 전위는 순수아연 전극에 비하여 다소 높았으나 개로 전압에는 거의 영향이 없었다. 그리고 4가지 종류의 첨가제는 내식성과 가속 수명시험시의 사이클 수명을 향상시키는 데 중요한 역할을 하고 있는 것으로 확인되었다. 더욱이 Tartrate 첨가는 4가지 종류의 첨가제 중에서 상대적으로 충방전 특성을 개선할 뿐 아니라 양호한 내식성 효과가 확인되었다.

• Structural Engineering and Mechanics
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• 제80권5호
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• pp.609-623
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• 2021

Buckling restrained bracing (BRB) was firstly introduced in Japan construction industry in year 1989. With time, BRB performance has been advanced to self-centering BRB (SC-BRB) which has exceptional energy dissipation, addressing the improvement in the structure performance in post-seismic affect. Although the BRB performance specifications are defined in design codes of several countries, specific design provisions are not generally provided since BRBs are usually considered a manufactured device. Furthermore, most of review papers focused on BRB rather than SC-BRB. Thus, this paper explores the background of both BRB and SC-BRB. The importance of self-centering components in BRB and literature related to it have been studied. This review study also highlights the significance of corrosion-resistance materials in the configuring BRB and SC-BRB since most of such members are made of carbon steel that is susceptible to corrosion.

• 한국해양공학회지
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• 제1권1호
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• pp.111-119
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• 1987

The corrosion fatigue crack propagation characteristics of SS41 steel in 3.5% NaCl solution have been evaluated for loading frequencies of 1Hz and 0.2Hz. A sine wave loading profile was used for fatigue testing. Each test was carried out at a constant stress ratio, R(0.1). The main results are summarized as follows; 1. Fatigue crack propagation rate was higher in 3.5% NaCl solution than in air, higher in the base metal than in the weld metal, and higher at f =0.2Hz than at f =1Hz. 2. The crack closure level of the base metal was not influenced by cyclic frequencies, but that of the weld metal was much influenced. 3. When the crack closure effect was eliminated in the evaluation of crack propagation characteristics by using $\Delta K_{eff}$, the envirommental influence was distinctly observed. At the base metal, crack propagation rate was enhanced by the hydrogen embrittlement, and the weld metal was reduced by the crac closure. 4. There was clearly observed hydrogen embrittlement and severely corroded aspect at fracture surface of lower frequency than that of higher frequency, and at that of base metal than that of the weld metal.

• Corrosion Science and Technology
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• 제13권1호
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• pp.20-27
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• 2014

The structures of reinforced concrete has been extensively increased with rapid development of industrial society. Futhermore, these reinforced concretes are easy to expose to severe corrosive environments such as sea water, contaminated water, acid rain and seashore etc.. Thus, corrosion problem of inner steel bar embedded in concrete is very important in terms of safety and economical point of view. In this study, multiple mortar test specimen(W/C:0.4) with six types having different cover thickness each other was prepared and was immerged in seawater solution for five years to evaluate the effect of cover thickness and immersion years to corrosion property of embedded steel bar. And the polarization characteristics of these embedded steel bars was investigated using electrochemical methods such as measuring corrosion potential, cathodic polarization curve, and cyclic voltammogram. At the beginning of immersion, the corrosion potentials exhibited increasingly nobler values with increasing cover thickness. However, after immersed for 5 years, the thicker cover of thickness, the corrosion potentials shifted in the negative direction, and the relationship between corrosion potential and cover thickness was not in good agreement with each other. Therefore, it is considered that the thinner cover of thickness, corrosive products deposited on the surface of the embedded steel bar plays the role as a resistance polarization which is resulted in decreasing the corrosion rate as well as shifting the corrosion potential in the positive direction. As a result, it seemed that the evaluation which corrosion possibility of the reinforced steel would be estimated by only measuring the corrosion potential may not be a completely desirable method. Therefore, it is suggested that we should take into account various parameters, including cover thickness, passed aged years as well as corrosion potential for more accurate assessment of corrosion possibility of reinforced steel which is exposed to partially or fully in marine environment for long years.

• 한국건설순환자원학회논문집
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• 제5권4호
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• pp.375-381
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• 2017

최근, 친환경 콘크리트에 대한 관심의 증가로, 플라이애시, 고로슬래그 미분말 및 실리카 퓸 등의 산업부산물을 혼입한 콘크리트의 사용이 증가되고 있다. 특히 이 같은 산업부산물은 콘크리트 내의 철근부식 저항성을 증가시키고 염화물이온 침투를 감소시키는 것으로 잘 알려져 있다. 이 실험연구의 목적은 시멘트량의 약 50%를 플라이애시로 치환한 하이볼륨 플라이애시 콘크리트(HVFAC)의 철근부식 저항성 및 임계 염화물량을 평가하는 것이다. 이를 위하여 철근 상부를 노출시킨 원주형 공시체의 철근부식 개시 시기를 추정하기 위하여 자연전위 측정에 의한 철근부식 모니터링을 수행하였다. 결론적으로, HVFAC의 철근부식 개시 시기는 플레인 콘크리트보다 1.2~1.3배 증가하여 철근부식 저항성이 우수한 것으로 나타났고, 플레인 콘크리트 및 HVFAC의 임계 염화물량은 각각 $0.80{\sim}1.20kg/m^3$, $0.89{\sim}1.60kg/m^3$으로 나타나, HVFAC가 플레인 콘크리트보다 1.1~1.3배 증가하는 것으로 나타났다.