• Title/Summary/Keyword: Curing effect

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Strength Improvement of Polymer-Modified Mortars Using Epoxy Resin (에폭시수지 혼입 폴리머 시멘트 모르타르의 강도증진방안)

  • Kim, Wan-Ki;Jo, Young-Kug
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.465-468
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    • 2006
  • This paper investigates the effect of curing conditions on the strength improvement of polymer-modified mortars using epoxy resin with various curing methods. The polymer-modified mortars using epoxy resin are prepared with various polymer-cement ratios, and subjected to standard, hot water, heat cure and autoclave cures. The epoxy-modified mortars are tested for flexural and compressive strengths at desired curing methods. From the test results, the flexural and compressive strengths of the epoxy-modified mortars are hardly improved by the autoclave and hot water cures compared to the ideal cure of $20^{\circ}C$. Among the four types of curing methods, the strengths of the heat cured epoxy-modified mortars is largely improved. Especially, it is obtained in the mortars sealed with PVDC film.

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A study of polymerization shrinkage of composite resins cured by various light intensities

  • Lim, Mi-Young;Hong, Chan-Ui
    • Proceedings of the KACD Conference
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    • 2003.11a
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    • pp.613-613
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    • 2003
  • The purpose of this study was to compare the effect of exponential curing method with conventional curing and two step soft start curing method on polymerization shrinkage of composite resins. Three brands of composite resins (Synergy Duo Shade, Z-250, Supreme) and three brands of light curing units (Spectrum 800, Elipar Highlight, Elipar Trillight) were used. In this study, the diameter of specimen was 5.5mm and height 1.6mm and the specimen was cured for 40 seconds. The shrinkage was measured by custom made linometer. The amount of linear polymerization shrinkage recorded in the computer every 0.5 second for 90 seconds. Each group was measured 10 times.(omitted)

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Effects of carbonation on hydration characteristics of ordinary Portland cement at pre-curing condition

  • Kim, Gwang Mok
    • Journal of Urban Science
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    • v.11 no.1
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    • pp.21-28
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    • 2022
  • Raman spectroscopy is effective to investigate functional groups via molecular vibration. The technique offers the structural information of compounds including subtle changes in the chemical composition of local atomic coordination without critical damage. Thus, the effect of carbonation on the hydration characteristics of Portland cement under pre-curing conditions for carbonation was investigated via Raman spectroscopy in the present study. Gaseous CO2 was injected within 60 seconds, and the reaction time was varied from 0 minute to 90 minutes. The test results indicated that the Ca/Si ratio of C-S-H reduced immediately after mixing and then the C-S-H with a relatively high Ca/Si ratio coexisted as the reaction time increased. The calcium carbonates formed in the present study included calcite and amorphous calcium carbonates. The test results via Raman spectroscopy provide valuable information about the carbonation characteristics of OPC under pre-curing conditions for carbonation.

Thermal Curing Behavior and Tensile Properties of Resole Phenol-Formaldehyde Resin/Clay/Cellulose Nanocomposite

  • Park, Byung-Dae;Kadla, John F.
    • Journal of the Korean Wood Science and Technology
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    • v.40 no.2
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    • pp.110-122
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    • 2012
  • This study investigated the effects of layered clay on the thermal curing behavior and tensile properties of resole phenol-formaldehyde (PF) resin/clay/cellulose nanocomposites. The thermal curing behavior of the nanocomposite was characterized using conventional differential scanning calorimetry (DSC) and temperature modulated (TMDSC). The addition of clay was found to accelerate resin curing, as measured by peak temperature ($T_p$) and heat of reaction (${\Delta}H$) of the nanocomposite’ curing reaction increasing clay addition decreased $T_p$ with a minimum at 3~5% clay. However, the reversing heat flow and heat capacity showed that the clay addition up to 3% delayed the vitrification process of the resole PF resin in the nanocomposite, indicating an inhibition effect of the clay on curing in the later stages of the reaction. Three different methods were employed to determineactivation energies for the curing reaction of the nanocomposite. Both the Ozawa and Kissinger methods showed the lowest activation energy (E) at 3% clay content. Using the isoconversional method, the activation energy ($E_{\alpha}$) as a function of the degree of conversion was measured and showed that as the degree of cure increased, the $E_{\alpha}$ showed a gradual decrease, and gave the lowest value at 3% nanoclay. The addition of clay improved the tensile strengths of the nanocomposites, although a slight decrease in the elongation at break was observed as the clay content increased. These results demonstrated that the addition of clay to resole PF resins accelerate the curing behavior of the nanocomposites with an optimum level of 3% clay based on the balance between the cure kinetics and tensile properties.

Curing and segregation of pSL100 and recombination of its segregants (Plasmid pSL100의 curing, segregation 및 segregants 들의 재조합에 관한 연구)

  • 백형석;김국찬;이세영
    • Korean Journal of Microbiology
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    • v.20 no.1
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    • pp.11-20
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    • 1982
  • A study was undertaken to examine the effect of curing agents on the stability, curing and segregation of R plasmid pSL100. And also the stability, transfer frequency, and recombination of its segregants obtained from curing agent treatment were studied. Ethidium bromide, acridine orange, and mitomycin-C were used as curing agent. The results obtained were as follows ; 1. The curing agent ethidium bromide, acridine orange, and mitomycin-C were not effective for curing the multiple antibiotic resistant determinant of pSL100 in Salmonella typhimurium and Escherichia coli. However, they induced plasmid segregation with high frequency in S.typhimuruim LT-2strains. TcApSmCm, TcSmCmKm, TcApCm, TcAp, TcKm, Tc segregants were obtained. 2. The resistant markers of the segregents were transferred to S.typhimurium LT-2 strains with high frequencies whereas they were transferred to E.coli K-12 only with low frequencies. 3. The transconjugants obtained from conjugation between two different S.typhimurium segregants were similar to the phenotype of the original R factor pSL100 and the resistant markers were transferred to the S.typhimurium LT-2 or E.coli strain with equal frequencies, indicating that they are recombinants. 4. The transconjugants obtained from conjugation between pSL100 segrgants and pKM101, or pBR322 possessed the resistant markers of the two parental plasmids and they were transferred to both S.typhimurium and E.coli K-12 strains with the same frequencies and maintained stably, suggesting that they are also recombinants. 5. The recombinant pSL100 could be also obtained in rec A-strains of E.coli, suggesting that the gene function of rec A is required for the recombination of pSL100 segregants in E.coli.

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Study on the Curing Properties of Photo-curable Acrylate Resins (광경화성 아크릴 수지의 경화특성에 관한 연구)

  • Kim, Sung-Hyun;Chang, Hyun-Suk;Park, Sun-Hee;Song, Ki-Gook
    • Polymer(Korea)
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    • v.34 no.5
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    • pp.469-473
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    • 2010
  • The curing mechanism and characteristics of UV curable acrylate resins were studied using Photo-DSC, FTIR, and Raman spectroscopy. Effects of chemical structures of acrylate, numbers of functional group, and UV intensity on curing kinetics were investigated with Photo-DSC. FTIR and Raman spectroscopy has been used to understand curing mechanisms and reaction conversion. In order to investigate the effect of oxygen on the photo-curing reaction, the curing process was compared between the acrylate and thiol-ene resins. The reaction conversion was found to be less than 80% for acrylate resins. The photo-curing reaction of the acrylate resin could not proceed to the end because of oxygen which acts as a reaction inhibitor while the thiol-ene resin was hardly affected from oxygen during the curing process.

A Convergence Study on Comparison of the Difference in the Blue-Light Transmittance by Goggles and Dental Curing Light Unit Tips (청색광이 광중합기용 팁과 보안경에 따라 투과되는 투과율 차이 비교의 융합적 연구)

  • Lee, Sook-Jeong
    • Journal of the Korea Convergence Society
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    • v.10 no.12
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    • pp.177-181
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    • 2019
  • The purpose of this study was to investigate the degree of blocking of blue light of the tips and goggles of the curing light during the dental treatment using the blue light of the light curing. The light curing tips and goggles were placed on a UV-Vis spectrometer and the results of light transmission were analyzed. Comparative analysis. As a result, all four types of light curing tips used in the analysis showed excellent blue light blocking effect. In the case of safety goggles, red-type goggles showed blue light transmittance similar to those of light curing than yellow-type goggles. As a result, it is recommended that the attachment of the light curing with high degree of blue light blocking and the wearing of safety glasses are necessary to protect the eyes. This behavior is thought to reduce persistent irritation and fatigue in the eyes.

Effects of Treatment of Silane Coupling Agent in MPS Concentration on the Shear Bond Strength between Self Curing Resins and Heat Curing Resin (Silane coupling agent인 MPS 농도별처리에 따른 열중합 레진과 자가중합 레진 간의 전단결합강도)

  • Choi, Esther;Kwon, Eun-Ja
    • The Journal of the Korea Contents Association
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    • v.15 no.2
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    • pp.344-351
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    • 2015
  • The purpose of this study was to evaluate the effect of the surface treatment of widely used in dental of silane coupling agent concentration on the shear bond strength of denture base resin and self curing resins. Denture base resin surface was treated with silane coupling agent concentration, after self curing resins were injected shear bond strength was measured. The results of silane coupling agent(MPS) concentration on the shear bond strength of Vertex self curing resin showed that the value of 5%, 7% groups were higher than that of other group(P<0.05). Silane coupling agent concentration on the shear bond strength of Kooliner resin showed that the value of 5% was highest(P<0.05). Therefore, we could conclude 5% MPS to strengthen effectively the shear bonding property of denture base resin and self curing resins of this study.

Effect of Moisture Conditions and Curing Conditions of Recycled Coarse Aggregate on Concrete Compressive Strength (재생 굵은 골재의 함수조건과 양생조건이 콘크리트 압축 강도에 미치는 영향)

  • Shin, Mingun;Boo, Sangpil;Park, Sangyeol;Moon, Kyoungtae
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.44 no.3
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    • pp.283-290
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    • 2024
  • Currently, the quality standards for recycled aggregates in Korea are very high, at almost the same level as natural aggregates, so recycled aggregates cannot be widely used for concrete. In particular, it is necessary to evaluate how the moisture conditions and curing conditions of recycled aggregates with high absorption rates and wearing rates affect the compressive strength of concrete. Therefore, in this study, we wanted to investigate the effects on compressive strength through experiments using the moisture conditions and curing conditions of recycled coarse aggregate as variables, and compare the compressive strength characteristics of natural coarse aggregate concrete. As a result of this experimental study, the effect of compressive strength on concrete using recycled coarse aggregates according to curing conditions was similar to that of natural aggregate concrete, and the compressive strength showed a low strength of about 13 to 17 %. The effect of the moisture conditions of recycled coarse aggregates was that in the case of wet curing, concrete using wet aggregate showed slightly higher compressive strength than concrete using dry aggregate, but in the case of air curing, on the contrary, dry recycled aggregate concrete was relatively higher than wet aggregate concrete.

Determination of Proper Application Rate of Curing Compound for Cement Concrete Pavement (콘크리트 포장 양생제의 적정살포량 결정 연구)

  • Kim, Jang-Rak;Suh, Young-Chan;Ahn, Sung-Soon
    • International Journal of Highway Engineering
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    • v.7 no.2 s.24
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    • pp.45-55
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    • 2005
  • It is known that the Q/C(Quality Control) in the early age of portland cement concrete(PCC) pavement gives a huge effect on long term pavement performance. Thus, many studies regarding the construction of PCC pavement have focused on how to assure construction quality at the early age stage. Curing is one of the most important factor in Q/C of PCC pavement. Membrane curing that protects the evaporation of moisture by placing an impermeable layer on the slab surface is the most common practice for curing the PCC pavement. In order to improve the membrane curing practice, the rate of curing compound should be optimized. However, the optimum rate of curing compound considering Korean weather and environmental conditions has not been specified in the pavement construction specifications. In this study, a proper application rate was recommended in terms of minimizing evaporation with several full-scale tests where various rates of curing compound have been applied. Four test sites on the expressway were enlisted during the summer of 2002 and 2003. Application rates tested were in the range of $0. The rate of evaporation, the temperature pattern of the slab and the pulse velocity of concrete surface have been monitored at each test construction. The result from this study showed that the rate of current construction was approximately $160ml/m^2$ and that approximately $400ml/m^2$ of curing application was recommended as the proper rate for minimizing the moisture evaporation.

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