• 한국건축시공학회지
• /
• 제8권5호
• /
• pp.119-125
• /
• 2008

In this paper, the estimation of super retarding concrete incorporating mineral admixtures at the same time including fly ash(FA), blast furnace slag(BS) are studied based on maturity method. The setting time was retarded, as super retarding agent contents increase and curing temperature decreases. In addition, apparent activation energy by Arrhenius function was ranged from $24\sim35$ KJ/mol with slightly difference along with mixture proportion. This value is smaller than existing value $30\sim50$ KJ/mol. Based on strength development estimation. it exhibited comparable relativity between prediction value and measurement value. Therefore, this study provided effective strength development prediction value with super retarding agent contents and mineral admixture combination. Strength development prediction equation provided herein is possibly valid for estimating accurate strength development of the super retarding concrete at the job site.

• 한국지반환경공학회 논문집
• /
• 제13권6호
• /
• pp.19-26
• /
• 2012

본 연구에서는 산업부산물 중 고로슬래그를 기본 재료로 바이패스 더스트(Bypass dust), 플라이애쉬와 인산석고를 자극제로 활용하고 원료들 간의 화학적 상호작용을 이용하여 개발된 지반 고화제의 개량효과를 판단하기 위하여 화강풍화토 및 준설된 해성점토에 다양한 혼합비로 혼합하여 기본 물성실험과 일축압축실험을 실시하였다. 화강풍화토와 혼합하여 실험한 결과, 인산석고를 자극제로 활용한 B-2고화제가 바이패스 더스트를 자극제로 활용한 B-1고화제에 비해 우수한 강도를 발현하였다. 화강풍화토에 5~7%의 무게비로 혼합된 B-1 및 B-2고화제는 일반 포트랜트 시멘트(OPC)에 비해 44%~60%의 강도를 발현시키나 원료가 산업부산물이므로 특별히 높은 강도를 요구하지 않는 지반구조물에 사용된다면 시멘트뿐 아니라 현재 국내에서 판매되는 고화제에 비해 경제적인 것으로 판단된다. 또한 해성준설토에 5~14%로 혼합하여 실험한 결과, 양생일 및 혼합비 증가에 따라 혼합토의 강도는 증가하며 B-1 고화제의 경우 양생일에 대해 선형적으로 증가하여 14% 혼합비에서 28일 양생일의 일축압축강도가 OPC혼합토에 비해 40%의 강도를 보이나 B-2는 양생일에 대해 비선형적으로 증가하여 OPC 혼합토 대비 133%로 매우 큰 강도를 발현하였다. 한편 B-1혼합토와 B-2혼합토의 변형계수는 $E_{50}=(20{\sim}47)_{qu,28}$ 범위인 것으로 나타나 OPC 혼합 준설토의 하한계 값에 가까운 것으로 나타났다.

• 펄프종이기술
• /
• 제38권1호통권113호
• /
• pp.1-8
• /
• 2006

To overcome troubles in strength and process of linerboard caused by raw materials, a neutral sizing which is usual in fine paper making can be considered. A new sizing agent is necessary to show good performance in a system with high conductivity and COD. In this study, fast cure type AKD was examined as a new sizing agent and compared with conventional AKD. The effects of fixing agent addition and drying condition were also investigated. Fast cure type AKD which has a higher cationicity showed better sizing degree than conventional AKD in spite of low addition level and no curing treatment. And when fixing agent of sufficient amount was added, sizing degree was improved for both AKDs. High cationicity is a crucial factor for neutral sizing of linerboard for obtaining fast and stable sizing degree. Drying with temperature over $100^{\circ}$ was desirable for developing sizing degree.

• 한국지반신소재학회논문집
• /
• 제16권2호
• /
• pp.131-138
• /
• 2017

본 연구에서는 지반함몰을 유발하는 지반 내 공동 긴급복구 재료에 대한 팽창 및 일축압축강도 실험을 수행하였으며, 실험결과를 바탕으로 주제-경화제 구성비와 주제 내 발포제-촉진제 배합비에 따른 팽창 및 강도특성을 분석하였다. 먼저, 경화시간-팽창률 관계를 분석한 결과, 주제에 포함된 발포제와 촉진제 배합조건에 상관없이, 경화제의 비율이 높으면, 경화시간을 단축하면서 팽창률을 감소시키는 것으로 평가되었다. 이는 주제-경화제 구성비가 팽창률에 큰 영향을 미치는 것을 의미한다. 팽창재료의 강도특성을 분석한 결과, 발포제와 촉진제 배합비가 팽창재료 강도에 큰 영향을 미치는 것으로 확인되었다. 따라서 긴급복구가 요구되는 경우, 공동의 크기 및 형태 등에 따라 팽창재료의 소요 주입시간, 팽창률 및 요구강도를 고려한 주제-경화제 구성비, 주제 내 발포제-촉진제 배합비의 적용이 필요함을 확인하였다.

• 한국응용과학기술학회지
• /
• 제23권3호
• /
• pp.264-271
• /
• 2006

PU type flame-retardant coatings (TBAO/L-75, TBAOL ; TBAO/N-100, TBAON) were prepared by blending bromine-containing modified polyester (TBAO) which was synthesized in our earlier work. with two kinds of isocyanate curing agents, Desmodur L-75 and Desmodur N-100. Physical properties of the prepared flame-retardant coatings were tested. TBAOL shows better hardness than TBAON, while TBAON shows better viscosity, accelerated weathering resistance, yellowness index and lightness index difference than TBAOL. There were no remarkable differences in fineness of grind, $60^{\circ}$ specular gloss, cross-hatch adhesion, and abrasion resistance of TBAOL and TBAON. There was no discernable difference in flame-retardancy between the two flame-retardant coatings, TBAOL and TBAON. When the content of tribromo acetic acid, which is flame-retarding component, was 30wt% the LOI value was in a range of $29{\sim}30%$, which indicates that the two coatings are good flame-retardant coatings.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2008년도 춘계학술대회 논문집 센서 박막재료연구회 및 광주 전남지부
• /
• pp.75-79
• /
• 2008

In this paper, we measured the activation energy of the Bisphenol A type Epoxy resin (DGEBA)-Jeffamine system according to an irradiation. We put the mixed solutions to the silicon mold after mixing both DGEBA(216g) and Jeffamine(93.9g), curing agent of amine system. The mixed solutions were cured in the atmosphere during 24hours after finishing the first curing during 4hours in the vacuum oven under $80^{\circ}C$. The mixed solutions were cured in the atmosphere during 24hours after finishing the second curing during 12hours in the vacuum oven under $60^{\circ}C$ again. Prepared samples were irradiated to the dose rate of 8kGy/hr with 500kGy, 700kGy, 1000kGy, 1500kGy, 2000kGy, 2500kGy. Experimental results indicated activation energy of the samples reduced as the irradiation dose increased because of the peroxides of the Epoxy created by the oxidation and the radiation.

• 한국의류학회지
• /
• 제10권2호
• /
• pp.59-67
• /
• 1986

To control the amounts of formaldehyde released from the cotton fabric finished with N-methylol compounds, glycerol was used as a formaldehyde-scavenging agent. It was observed the effects of catalysts and curing conditions when aftertreated with glycerol on melamine resin finished fabric. The effects of Different processes of glycerol treatment, and different resins, urea resin and melamine resin, were compared. The conclusions obtained from the results are as follows: 1) It was shown hatt the aftertreatment with glycerol (treated without catalyst) was more effective than treated with catalysts in controlling free formaldehyde. 2) The optimum curing temperature and curing time for the glycerol aftertreatment without adversely affecting the other properties of fabric was about $160^{\circ}C$, 3 min. 3) According to the increase of glycerol concentration in both aftertreatment and simultaneous treatment the amounts of free formaldehyde was reduced. The rate of decrease was manifest within the limits of $6\%$ in the case of simultaneous treatment with glycerol ana resins, and $3\%$ in the case of glycerol aftertreatment on resin finished fabrics. 4) Dry wrinkle recovery angle was decreased the increase of glycerol concentration. Melamine resin had a little adverse effect than urea resin, particulary glycerol aftertreatment. 5) The breaking strength was increased with the increase of glycerol concentration.

• 한국추진공학회:학술대회논문집
• /
• 한국추진공학회 2006년도 제26회 춘계학술대회논문집
• /
• pp.229-232
• /
• 2006

Tetrahydrofuran(THF)과 Ethylene oxide(EO) 또는 EO를 단량체로 하여 양이온 개환중합을 이용한 새로운 합성방법으로 random 또는 tri-block HTPE(Hydroxyl-terminated polyether)를 합성할 수 있었다. 합성된 random과 tri-block HTPE를 IPDI/N-100혼합 디이소시아네이트 경화제와 촉매로 TPB(triphenylbismuth)를 사용하여 폴리우레탄을 제조하였으며, 혼합 이소시아네이트 화합물의 비율에 따른 폴리우레탄의 기계적 특성을 연구하였다. 그리고 폴리 우레탄 추진제 바인더 제조를 위한 prepolymer인 합성된 HTPE의 최적 경화 조건을 찾기 위해 HTPE의 후처리 과정, 우레탄 합성시 사용되는 촉매의 양 등의 영향에 대해 알아보았다.

• Macromolecular Research
• /
• 제10권5호
• /
• pp.259-265
• /
• 2002

The cure kinetics of blends of epoxy (DGEBA, diglycidyl ether of bisphenol A)/anhydride resin with polyamide copolymer, poly(dimmer acid-co-alkyl polyamine), were studied using differential scanning calorimetry (DSC) under isothermal condition. On increasing the amount of polyamide copolymer in the blends, the reaction rate was increased and the final cure conversion was decreased. Lower values of final cure conversions in the epoxy/(polyamide copolymer) blends indicate that polyamide hinders the cure reaction between the epoxy and the curing agent. The value of the reaction order, m, for the initial autocatalytic reaction was not affected by blending polyamide copolymer with epoxy resin, and the value was approximately 1.3, whereas the reaction order, n, for the general n-th order of reaction was increased by increasing the amount of polyamide copolymer in the blends, and the value increased from 1.6 to 4.0. A diffusion-controlled reaction was observed as the cure conversion increased and the rate equation was successfully analyzed by incorporating the diffusion control term for the epoxy/anhydride/(polyamide copolymer) blends. Complete miscibility was observed in the uncured blends of epoxy/(polyamide copolymer) up to 120 $^{\circ}C$, but phase separations occurred in the early stages of the curing process at higher temperatures than 120 "C. During the curing process, the cure reaction involving the functional group in polyamide copolymer was detected on a DSC thermogram.gram.

• 한국의류산업학회지
• /
• 제3권3호
• /
• pp.283-289
• /
• 2001

Shrink resist finishing of wool fabric was carried out with Monoethanol aminesulphite (MONAMIN BTN) shrink resist agent after chlorination with Dichloro isocyanuric acid (DCCA). The purpose of this study is to investigate the effect of treating conditions, such as concentrations of DCCA and MONAMIN BTN, pH of treating bath, dyeing times, curing times and temperatures, on dyeing property of wool fabrics. K/S values and fastness properties of dyed wool fabrics were measured. The K/S values of dyed fabrics were increased gradually with increasing concentration, and decreased with increasing curing time. The optimum dyeing time and curing temperature were 60 min and $140^{\circ}C$, respectively. Also it seems likely that the shrink resist finishing carried out at 3% (o.w.f.) of MONAMIN BTN and pH 7 of resin treating bath is effective in increasing K/S values. Light fastness of fabric dyed was very poor and the fastness of fabric dyed was not influenced by the treatment conditions.