• 제목/요약/키워드: Cubic equation of state

검색결과 25건 처리시간 0.031초

CPA 상태방정식에 의한 회합성 유체의 PVT 관계 (PVT Relations of Associating Fluids using the Cubic-Plus-Association EoS)

  • 김미경;심민영;김기창
    • 산업기술연구
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    • 제20권A호
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    • pp.195-202
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    • 2000
  • For modeling an equation of state suitable for describing associating fluids, we combined the cubic equation of state (Peng-Robinson) and an association term of SAFT. The resulting EoS (Cubic-Plus-Association) is not cubic with respect to volume and contains five pure compound parameters. Excellent correlations of both vapour pressures and saturated liquid volumes were obtained for n-alcohols and secondary alcohols. We considered a method for reducing the number of adjustable pure compound parameters from five to three, and the resulting 3-parameters EoS relation maintained the good correlation of vapour pressures and saturated liquid volumes.

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액체혼합물의 밀도 측정과 3차 상태방정식에 의한 과잉 몰부피의 예측 (Density Measurement of Liquid Mixture and Estimation of Excess Molar Volume by A Cubic Equation of State)

  • 김정민;배효광
    • Korean Chemical Engineering Research
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    • 제43권5호
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    • pp.637-640
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    • 2005
  • 극성과 비극성의 물질인 methyl tert-butyl ether(MTBE)와 2,2,4-trimethylpentane 혼합물과 methyl ethyl ketone(MEK)와 2,2,4-trimethylpentane 2성분의 액체혼합물 그리고 극성의 물질인 MTBE과 MEK 2성분 액체혼합물의 밀도를 densitometer를 사용하여 278.15 K, 288.15 K, 298.15 K에서 각각 측정하였다. 측정한 밀도로부터 얻은 2성분계 과잉몰부피의 측정값과 Huron-Vidal의 혼합법칙을 사용한 Peng-Robinson-Stryjek-Vera(PRSV)의 3차 상태방정식으로부터 계산한 계산값이 잘 일치하였으며 극성물질을 포함한 혼합물의 몰부피 계산에 3차의 PRSV 상태방정식이 이용될 수 있음을 확인하였다.

두 개의 온도 의존 매개변수가 있는 3차 상태방정식의 성능비교 (Performance Comparison of Cubic Equations of State With Two Temperature Dependent Parameters)

  • 권영욱;박경근
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 추계학술대회논문집B
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    • pp.205-210
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    • 2001
  • Cubic equations of state with two temperature dependent parameters are suggested and optimized using ASHRAE data for methane, propane, carbon dioxide, R-32 and R-134a. Appropriate simple functional forms are assumed for the temperature dependent parameters. The equations tested are Martin, Fuller, Harmens-Knapp, Schmidt-Wenzel. Among them modified Schmidt-Wenzel equation of state appears to be the choice for calculation of saturation properties such as vapor pressures, saturated liquid volumes, and saturated vapor volumes with an average absolute deviation of about one percent over the entire region excluding; the near cirtical.

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$H_2S$를 포함하는 LNG 혼합물에 대한 Cubic과 Noncubic 상태방정식의 예측 비교 (A comparison of predicted VLE of LNG mixtures containing $H_2S$ by use of Cubic and Noncubic EOS)

  • 최은주;이태종
    • 한국가스학회지
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    • 제4권4호
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    • pp.1-5
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    • 2000
  • [ $H_2S$ ]를 포함하는 액화천연가스(Liquified Natural Gas)의 기-액 조성을 noncubic 형태인 Modified-Benedict-Web-Robin EOS로 예측하였고, 그 결과를 대표적 cubic형태의 Peng-Robinson, Soave-Redlich-Kwong EOS로 예측한 기-액 조성과 비교 검토하였다.

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3차 상태방정식을 이용한 수소 충전 온도 거동 모사 (Simulation of Temperature Behavior in Hydrogen Tank During Refueling Using Cubic Equations of State)

  • 박병흥
    • 한국수소및신에너지학회논문집
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    • 제30권5호
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    • pp.385-394
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    • 2019
  • The analysis of temperature behavior of a hydrogen tank during refueling is of significance to clarify the safety of the compressed hydrogen storage in vehicles since the temperature at a tank rises with inflow of hydrogen. A mass balance and an energy balance were combined to obtain analytical model for temperature change during the hydrogen refueling. The equation was coupled to Peng-Robinson-Gasem (PRG) equation of state (EOS) for hydrogen. The PRG EOS was adopted after comparison with other four different cubic EOSs. A parameter of the model was determined to fit data from experiments of various inlet flow rates and temperatures. The temperature and pressure change with refueling time were obtained by the developed model. The calculation results revealed that the extent of precooling was more effective than the flow rate control.

섭동 이론을 이용한 정상류 Navier-Stokes 방정식의 주기함수 간극에 대한 삼승 법칙의 수정 (Modification of the Cubic law for a Sinusoidal Aperture using Perturbation Approximation of the Steady-state Navier-Stokes Equations)

  • 이승도
    • 터널과지하공간
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    • 제13권5호
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    • pp.389-396
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    • 2003
  • 본 연구는 정상류 Navier-Stokes 방정식에 섭동(perturbation) 이론을 적용하여 주기함수 간극에 대한 삼승법칙의 수정에 대해 논하였다. 이를 위해, 주기함수를 진폭과 파장에 대한 무차원 함수로 전환한 뒤 미소 계수에 대한 무차원 유동함수와 연속 방정식을 적용하였다. 이러한 과정을 통해 정상류 Navier-Stokes 방정식의 섭동 근사해를 구하였으며 이를 유한 차분법에 적용하였다. 단일 절리 모델에 대한유한 차분 수치해석을 통해, 수정된 삼승 법칙이 주기함수 간극의 유체 유동에 대한 정상류 Navier-Stokes 방정식의 섭동 근사해와 잘 일치하는 것으로 나타났다. 이를 통해 본 연구에서 제시된 삼승 법칙이 간극 분포에 따른 유체 유동의 평가에 있어 유용하게 적용될 수 있는 것으로 나타났다.

선회수와 리세스 길이가 초임계상태 케로신/액체산소 이중 와류 동축형 분사기의 화염구조에 미치는 영향 해석 (Effects of Swirl number and Recess length on Flame Structure of Supercritical Kerosene/LOx Double Swirl Coaxial Injector)

  • 박상운;김태훈;김용모
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2012년도 제45회 KOSCO SYMPOSIUM 초록집
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    • pp.33-35
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    • 2012
  • This study has been mainly motivated to numerically model the supercritical mixing and combustion processes encountered in the liquid propellant rocket engines. In the present approach, turbulence is represented by the extended k-e model. To account for the real fluid effects, the propellant mixture properties are calculated by using generalized cubic equation of state. In order to realistically represent the turbulence-chemistry interaction in the turbulent nonpremixed flames, the flamelet approach based on the real fluid flamelet library has been adopted. Based on numerical results, the detailed discussions are made for the effects of swirl number on flame structure of supercritical kerosene/LOx double swirl coaxial injector.

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선회수와 압력이 초임계상태 케로신 추진제 축소형 다중분사기의 화염구조에 미치는 영향 해석 (Effects of Swirl number and Pressure on Flame Structure of Supercritical Kerosene Propellant Subscale Injector)

  • 박상운;김태훈;김용모
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2013년도 제46회 KOSCO SYMPOSIUM 초록집
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    • pp.81-82
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    • 2013
  • This study has been mainly motivated to numerically model the supercritical mixing and combustion processes encountered in the liquid propellant rocket engines. In the present approach, turbulence is represented by the standard k-e model. To account for the real fluid effects, the propellant mixture properties are calculated by using generalized cubic equation of state. In order to realistically represent the turbulence-chemistry interaction in the turbulent nonpremixed flames, the flamelet approach based on the real fluid flamelet library has been adopted. Based on numerical results, the detailed discussions are made for the effects of swirl on flame structure of supercritical kerosene liquid propellant combustion.

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