• Title/Summary/Keyword: CuO content

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Characterization of $Cu(In_xGa_{1-x})Se_2$ Solar Cells with Ga Content (Ga 함량에 따른 $Cu(In_xGa_{1-x})Se_2$ 태양전지의 특성분석)

  • Kim, Seok-Ki;Kwon, Se-Han;Lee, Doo-Yeol;Lee, Jeong-Churl;Kang, Ki-Whan;Yoon, Kyung-Hoon;Ahn, Byung-Tae;Song, Jin-Soo
    • Proceedings of the KIEE Conference
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    • 1998.07d
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    • pp.1264-1267
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    • 1998
  • $Cu(In_xGa_{1-x})Se_2$ thin films were prepared and characterized with various Ga contents. As the Ga content increased, the grain size of CIGS film became smaller. The 2 $\theta$ values in XRD patterns were shifted to larger values and the overlapped peaks were splitted. The energy bandgap increased from 1.04 to 1.67 eV and the resistivity decreased. The solar cell fabricated with ZnO/CdS/$Cu(In_{0.7}Ga_{0.3})Se_2/Mo$ structure yielded an efficeincy of 14.48% with an acitive area of 0.18 $cm^2$. The efficiency decreased with further increase of Ga content.

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Synthesis of F-free Y & Cu precursor solution and optimization of annealing process (Sm 첨가 F-free Y & Cu 전구용액의 합성 및 열처리 공정의 최적화)

  • Kim, Young-Kuk;Yoo, Jai-Moo;Chung, Kook-Chae;Ko, Jae-Woong
    • Progress in Superconductivity and Cryogenics
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    • v.9 no.1
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    • pp.1-4
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    • 2007
  • The total Fluorine content in the precursor solution for MOD processing of YBCO coated conductors can be significantly reduced by synthesizing precursor solution with F-free Y & Cu precursor and Barium trifluoroacetate(TFA). It was shown that crack-free and uniform precursor films were formed after calcinations in humidified oxygen atmosphere. Less than 2 hours are required to finish the calcinations process and XRD measurement shows that $BaF_2,\;CuO,\;Y_2O_3$ are major constituent of calcined precursor films. Film thickness after calcinations was improved to be 2.8um by applying slot-die coating method. In particular, addition of Samarium shows critical current of $I_c=273A/cm-w(J_c=3.8MA/cm^2)$. It is shown that uniform and fast processing route to YBCO coated conductor with high Ic can be provided by employing F-free Y & Cu precursor solution in MOD process.

A Study on the Influence of Ni and Si Content on the Characteristics of Cu-Ni-Si-P Alloy for Connector Materials (Connector용 Cu-Ni-Si-P합금의 특성에 미치는 Ni및 Si의 영향에 관한연구)

  • No, Han-Sin;Lee, Byeong-U;Lee, Gwang-Hak;Kim, Hong-Sik
    • Korean Journal of Materials Research
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    • v.4 no.8
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    • pp.877-887
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    • 1994
  • Cu-Ni-Si-P alloys have been studied in order to develop connector material which has a favorable combination of strength, electrical conductivity, elastic limit, thermal softening resistence and bend formability. Three kinds of trial alloys with various nickel and silicon content were melted and cast, hot rolled at about $900^{\circ}C$ and cold rolled. Mechanical properties and electrical conductivities of these alloys annealed at $450^{\circ}C$, $500^{\circ}C$ and $550^{\circ}C$ were investigated. An alloy with the composition of Cu-2.7%Ni-0.53%Si-O.O29%P, which shows a favorable combination of high strength and high electrical conductivity, has been developed. Various characteristics of the alloy 1 connector material were evaluated and compared with phospher bronze(C521OR-H) and brass(C26OOR-EH) connector material.

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Study of Humidity Sensing Properties Related to Metal Content of Aerosol Deposited Ceramic/Metal Composite Films (에어로졸 증착한 세라믹/금속 복합막의 금속 함량에 따른 습도 감지 특성 연구)

  • Kim, Ik-Soo;Koo, Sang-Mo;Park, Chulhwan;Shin, Weon Ho;Lee, Dong-Won;Oh, Jong-Min
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.34 no.5
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    • pp.314-320
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    • 2021
  • Controlling ambient humid condition through high performance humidity sensors has become important for various fields, including industrial process, food storage, and the preservation of historic remains. Although aerosol deposited humidity sensors using ceramic BaTiO3 (BT) material have been widely studied because of their longtime stability, there remain critical disadvantages, such as low sensitivity, low linearity, and slow response/recovery time in case of the sensors fabricated at room temperature. To achieve superior humidity sensing properties even at room temperature condition, BT-Cu composite films utilizing aerosol deposition (AD) process have been proposed based on the percolation theory. The BT-Cu composite films showed gradually improved sensing properties until the Cu concentration reached 15 wt% in the composite film. However, the excessive Cu (above 30 wt%) containing BT-Cu composite films showed a rapid decrease of the sensing properties. The results of observed surface morphology of the AD fabricated composite films, to figure out the metal filler effect, showed correlation between surface topography as well as size and the amount of open pores according to the metal filler content. Overall, it is very important not only dielectric constant of the humidity sensing films but also microstructures, because they affect either the variation range of capacitance by ambient humidity or adsorption/desorption of ambient humidity onto/from the humidity sensing films.

Power Loss and Electro-Magnetic Characteristics of Ni-Cu-Zn Ferrites (Ni-Cu-Zn페라이트의 손실과 자성 특성)

  • Otsuki E.;Kim Jeong-Su
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2004.12a
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    • pp.3-11
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    • 2004
  • The power loss analysis was carried out for Ni-Cu-Zn ferrite samples with different content of NiO and ZnO. The power loss, Pcv decreases monotonically wi increasing temperature and attains to a certain value at around $100\~120$ degrees Celsius. The frequency dependence of Pcv can be explained by $Pcv\~f^n$', and n is independent of the frequency, f up to 1MHz. The Pcv decreases with an increase in ZnO/NiO. The Pcv was separated to hysteresis loss, Ph and residual loss, (Pcv-Ph). The temperature characteristics and compositional dependence of Pcv can be attributed to the Ph, while (Pcv-Ph) is not affected by both temperature and ZnO/NiO. By analyzing temperature and composition dependence of Ph and initial permeability, ${\mu}^i$ following equations could be formularized. $${\mu}_i{\mu}o=I_x\;^2/(K_1+bs_ol_s)\;\;\;\;(1)$$ $Wh=13.5(I_s\;^2/{\mu}_i{\mu}_o)\;\;\;\;(2)$$ Were ${\mu}_o$ is permeability of vacuum, $I_s$ saturation magnetization, $K_1$ anisotropy constant, $S_o$ internal heterogeneous stress, $I_s$, magnetostriction constant, b unknown constant. Wh hysteresis loss per one cycle of excitation (Ph: Wh*f). Steinmetz constant of Ni-Cu-Zn ferrites, $m=1.64\~2.2$ is smaller than the one of Mn-Zn ferrites, which suggests the difference of loss mechanism between these materials.

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Structural analysis and thermal expansion property of Cu doped LSM for SOFCs (Cu가 도핑된 LSM의 구조분석과 열팽창특성 연구)

  • Noh, Tai-Min;Ryu, Ji-Seung;Kim, Jin-Seong;Jeong, Cheol-Weon;Lee, Hee-Soo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.4
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    • pp.175-180
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    • 2011
  • The doping effect of Cu in the Sr-doped lanthan manganites (LSM) has been investigated in terms of structural analysis and thermal expansion coefficient (TEC). The $La_{0.8}Sr_{0.2}Mn_{1-x}Cu_xO_3$ ($0{\leq}x{\leq}0.3$) were prepared by solid state reaction method and their crystal structure and TEC were measured. A decrease in the lattice parameters and the TEC were observed with increase eu content, whereas they were decreased for x = 0.3. For $0{\leq}x{\leq}0.2$, the decrease of the lattice parameter and the TEC with increase Cu content were attributed to the reduction of ionic radius of Cu ions due to the presence of $Cu^{3+}$ ions. For x = 0.3, however, the increase was originated from the formation of oxygen vacancies due 10 the presence of $Cu^{2+}$ and $Mn^{4+}$.

The effects of Si-content on the corrosion rate of Cu-al alloys (동일 알루미늄 합금의 탄식속도에 미치는 규소의 영향)

  • Ham, Dong-Ha;Kang, Tak;Kang, Choon-Sik
    • Journal of the Korean institute of surface engineering
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    • v.14 no.1
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    • pp.5-9
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    • 1981
  • The effects of silicon content on the corrosion rates of Cu-7wt% Al alloys have been investigated by the use of electrochemical methods. The corrosion current densities of the alloys are decreased with the addition of Si up to 2wt%, and the slightly increased at 2.5%Si. This increased corrosion rates are attributed to the precipitation of more anodic gamma-2 phase. The X-ray diffraction tests reveal the dealuminumification of these alloys and mixtures of CuCl and Al2O3 formed on the surface of the specimens, which are considered to passivate the alloys at noble potentials.

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Microstructure and Magnetic Property of Nanostructured NiZn Ferrite Powder

  • Nam, Joong-Hee
    • Journal of the Korean Ceramic Society
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    • v.39 no.12
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    • pp.1119-1123
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    • 2002
  • Nanostructured spinel NiZn ferrites were prepared by the sol-gel method from metal nitrate raw materials. Analyses by X-ray diffraction and scanning electron microscopy showed the average particle size of NiZn ferrite was under 50 nm. The single phase of NiZn ferrites was obtained by firing at 250${\circ}C$, resulting in nanoparticles exhibiting normal ferrimagnetic behavior. The nanostructured $Ni_{1-X}Zn_XFe_2O_4$ (x=0.0∼1.0) were found to have the cubic spinel structure of which the lattice constants ${\alpha}_2$ increases linearly from 8.339 to 8.427 ${\AA}$ with increasing Zn content x, following Vegard's law, approximately. The saturation magnetization $M_s$ was 48 emu/g for x=0.4 and decreased to 8.0 emu/g for higher Zn contents suggesting the typical ferrimagnetism in mixed spinel ferrites. Pure NiZn ferrite phase substituted by Cu was observed before using the additive but hematite phase was partially appeared at $Ni_{0.2}Zn_{0.2}Cu_{0.6}Fe_2O_4$. On the other hand, the hematite phase in this NiZn Cu ferrite was disappeared after using the additive of acethyl aceton with small amount. The saturation magnetization Ms of $Ni_{0.2}Zn_{0.8-y}Cu_yFe_2O_4$(y=0.2∼0.6) as measured was about 51 emu/g at 77K and 19 emu/g at room temperature, respectively.

Variation of Copper Content in Paddy Soil and Rice from Mangyeong River Area (만경강 유역의 논토양과 수도체중 Cu 함량의 변화)

  • Kim, Seong-Jo;Lee, Man-Sang;Ryu, Taek-Kyu;Kim, Un-Sung;Yoon, Ki-Woun;Baek, Seung-Hwa
    • Korean Journal of Environmental Agriculture
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    • v.13 no.1
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    • pp.10-17
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    • 1994
  • To investigate differences with the polluted sources on Cu contents in soils and paddy rices under water pollutions, soils with the distance, the surface(0-15㎝ depth) and subsurface(15-30㎝ depth) in 1982 and 1990, and rice plants at the soil sampling sites in 1990 were separately sample at Mangyeong River area under the influence of municipal and industrial waste water from Jeonju city. Soil samples were extracted with $4M-HNO_3$ and plant samples were digested with mixture of $HNO_3$ and $HClO_4$ for analyzing Cu, Cd, Zn, Pb by atomic absorption spectrophotometry. Cu contents in soils ranged from 5.20 to 71.70 mg $kg^{-1}$. Average Cu level in 1990 was higher than that in 1982. Variation of Cu content with the distances from the source of waste water in 1990 was more regularly decreased than that in 1982. A significant correlation was observed between Cu contents in leaf sheath of rice plant and Cu, Zn and Pb contents in soils. Cu contents in soil was correlated with Zn and Pb in soil at area affected by waste water, regardless of years and soil depths. Cu contents in brown rice ranged from 0.4 to 10 mg $kg^{-1}$, and it was the lowest in parts of rice plant, and Cu content in panicle axis was 2.3 times higher than that in brown rice.

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