Progress in Superconductivity and Cryogenics (한국초전도ㆍ저온공학회논문지)

The Korean Society of Superconductivity and Cryogenics (한국초전도저온학회)
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Synthesis of F-free Y & Cu precursor solution and optimization of annealing process

Sm 첨가 F-free Y & Cu 전구용액의 합성 및 열처리 공정의 최적화

  • 김영국 (한국기계연구원 신기능재료연구본부) ;
  • 유재무 (한국기계연구원 신기능재료연구본부) ;
  • 정국채 (한국기계연구원 신기능재료연구본부) ;
  • 고재웅 (한국기계연구원 신기능재료연구본부)
  • Published : 2007.03.31
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Abstract

The total Fluorine content in the precursor solution for MOD processing of YBCO coated conductors can be significantly reduced by synthesizing precursor solution with F-free Y & Cu precursor and Barium trifluoroacetate(TFA). It was shown that crack-free and uniform precursor films were formed after calcinations in humidified oxygen atmosphere. Less than 2 hours are required to finish the calcinations process and XRD measurement shows that $BaF_2,\;CuO,\;Y_2O_3$ are major constituent of calcined precursor films. Film thickness after calcinations was improved to be 2.8um by applying slot-die coating method. In particular, addition of Samarium shows critical current of $I_c=273A/cm-w(J_c=3.8MA/cm^2)$. It is shown that uniform and fast processing route to YBCO coated conductor with high Ic can be provided by employing F-free Y & Cu precursor solution in MOD process.

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References

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