• Title/Summary/Keyword: CuO content

Search Result 344, Processing Time 0.023 seconds

The influence of Ag-additions on the superconducting properties of Hg$Ba_{2}$Cu$O_{4+7}$ materials (고온 초전도 Hg$Ba_{2}$Cu$O_{4+7}$물질에 Ag의 첨가에 따른 초전도특성 연구)

  • 송규정;하홍수;하동우;오상수;권영길;류강식
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
    • /
    • 2001.02a
    • /
    • pp.21-24
    • /
    • 2001
  • A series of superconducting Hg$Ba_{2}$Cu$O_{4+7}$ materials, containing $Ag_{x}$ additions with molar fraction x = 0, 0.05, 0.1, 0.3, and 0.5, have been studied. This study has showed that Ag additions lead to changes in superconducting properties of Hg-1201 materials. In addition, according to the amount of $Ag_{x}$ additions with molar fraction x up to 0.5, both $T_{c}$ and $J_{c}$ of Hg-1201 materials generally decrease with Ag-content. These and other results are discussed in this paper.

  • PDF

Effect of Pr substitution on the normal-state and superconducting properties of GdBa$_2$(Cu$_{2.9}$Al$_{0.1}$)O$_z$

  • Park, Jung-Rok;Ha, Dong-Han;Lee, Ho-Keum
    • 한국초전도학회:학술대회논문집
    • /
    • v.10
    • /
    • pp.70-75
    • /
    • 2000
  • We report results of a comparative study of the normal-state and superconducting properties in the GdBa$_2$(Cu$_{2.9}$Al$_{0.1}$)O$_z$ system with substitutions by Pr for the Gd and Ba sites. It is observed that, fur both Pr-doped systems, the superconducting transition temperature(T$_c$) decreases almost linearly with the Pr-content, but Pr at Ba sites results in a faster T$_c$ drop than that of Pr at Gd sites. The thermoelectric power measurements indicate that there is a strong correlation between the T$_c$ and the room temperature value of thermoelectric power. The experimental results are discussed in connection with existing models.

  • PDF

Superconducting and Normal-state Properties of Y(Sr$_{2-x}$Ba$_x$)Cu$_{2.7}$Mo$_{0.3}$O$_z$

  • Her, Hark-Moo;Lee, Ho-Keum
    • 한국초전도학회:학술대회논문집
    • /
    • v.10
    • /
    • pp.76-79
    • /
    • 2000
  • The effect of Ba substitution for Sr on the lattice parameters and the temperature dependence of the thermoelectric power and electrical resistivity has been investigated for Y(Sr$_{2-x}$Ba$_x$)Cu$_{2.7}$Mo$_{0.3}$O$_z$ (x=0${\sim}$2.0). Both a and c lattice parameters increase as the Ba content, x increases. The correlation between Tc and the carrier concentration estimated from the thermoelectric power data indicates that the change of hole concentration is negligible for x ${\le}$ 1.0 in contrast to the large change for x > 1.

  • PDF

Effect of Sn Contents on the Microstructure and Acoustic Characteristics of Cu-Sn Alloys (Cu-Sn합금의 미세조직 및 음향특성에 미치는 Sn함량의 영향)

  • Hong, Young-Keun;Lee, Jeong-Keun;Kim, Myung-Ho
    • Journal of Korea Foundry Society
    • /
    • v.21 no.2
    • /
    • pp.135-140
    • /
    • 2001
  • Microstructure of the bell made with Cu-Sn alloys was examined by optical and scanning electron microscope and that analyzed quantitatively with image analyzer. Also acoustic characteristics of the bells were measured in detail by using FFT type power spectrum analyzer. ${\alpha}-single$ phases of large grains only were observed in Cu-5%Sn alloy. However mixed structure of primary ${\alpha}-phase$ and eutectoid of ${\alpha}+{\delta}%_o$ was existed in the Cu-Sn alloys with more than 9%Sn. Also the area fraction of eutectoid phases gradually increased with an increased Sn content. From the result of acoustic test, it was found that frequency and tonal intensity decreased with the increased Sn content from 5%Sn to 11%Sn, and those were rather increased with further increase of that. The lowest frequency and tonal intensity were showed in Cu-11%Sn, and porosity decreased considerably frequency and tonal intensity of the bells.

  • PDF

Effect of Silicon Content over Fe-Cu-Si/C Based Composite Anode for Lithium Ion Battery

  • Doh, Chil-Hoon;Shin, Hye-Min;Kim, Dong-Hun;Chung, Young-Dong;Moon, Seong-In;Jin, Bong-Soo;Kim, Hyun-Soo;Kim, Ki-Won;Oh, Dae-Hee;Veluchamy, Angathevar
    • Bulletin of the Korean Chemical Society
    • /
    • v.29 no.2
    • /
    • pp.309-312
    • /
    • 2008
  • Two different anode composite materials comprising of Fe, Cu and Si prepared using high energy ball milling (HEBM) were explored for their capacity and cycling behaviors. Prepared powder composites in the ratio Cu:Fe:Si = 1:1:2.5 and 1:1:3.5 were characterized through X-Ray diffraction (XRD) and scanning electron microscope (SEM). Nevertheless, the XRD shows absence of any new alloy/compound formation upon ball milling, the elements present in Cu(1)Fe(1)Si(2.5)/Graphite composite along with insito generated Li2O demonstrate a superior anodic behavior and delivers a reversible capacity of 340 mAh/g with a high coulombic efficiency (98%). The higher silicon content Cu(1)Fe(1)Si(3.5) along with graphite could not sustain capacity with cycling possibly due to ineffective buffer action of the anode constituents.

Effect of Swine Liquid Manure and Phosphorus Application on Chemical Properties and Microbial Population of Italian (제주화산회토지역에서 돈분액비와 인산시용이 이탈리안 라이그라스 재배 토양의 화학적 특성 및 미생물상에 미치는 영향)

  • 김문철;현해남;최대진;문봉춘;고용구;강태숙
    • Journal of The Korean Society of Grassland and Forage Science
    • /
    • v.21 no.4
    • /
    • pp.181-190
    • /
    • 2001
  • This study was conducted to investigate the effect of swine liquid manure(SLM) and phosphorus fertilizer from September, 1998 to July, 1999 on the soil fertility on Italian ryegrass field, Cheju volcanic ash soil. pH(lst investigated), Mg (2nd investigated) and Cu content (2nd investigated) on soil grown by Italian ryegrass were significantly increased by an increase of fertilizer P(P

  • PDF

Structure and Superconductivity of (Pb,V)Sr$_2$(Ca,Pr)Cu$_2$O$_z$ ((Pb,V)Sr$_2$(Ca,Pr)Cu$_2$O$_z$ 의 구조와 초전도 특성)

  • Kim, Tae-Young;Lee, Ho-Keun
    • 한국초전도학회:학술대회논문집
    • /
    • v.9
    • /
    • pp.256-259
    • /
    • 1999
  • The effects of Pr doping on structural and superconducting properties of (Pb$_{0.5}$V$_{0.5}$)Sr$_2$(Ca$_{1-x}$Pr$_x$)Cu$_2$O$_z$ have been studied. We have observed systematic variation of lattice parameters with increasing Pr content. A maximum Tc of about40 K has been observed in this system. The correlation between the crystal structure and superconductivity has been addressed.

  • PDF

Superconductivity of Ce$O_2$-added Y-Ba-Cu-0 Superconductors Prepared by Partial Melt Process (준용응법으로 제조한 Y-Ba-Cu-O 초전도체에서 Ce$O_2$첨가에 따른 초전도성)

  • Kim, Chan-Joong;Kim, Ki-Baik;Lee, Kyu-Won;Won, Dong-Yeon
    • Korean Journal of Materials Research
    • /
    • v.2 no.3
    • /
    • pp.202-206
    • /
    • 1992
  • The $CeO_2$-added Y-Ba-Cu-O oxides were prepared by the partial melt process involving the peritectic reaction, liquid + 2-1-1 phase ${\rightarrow}$ 1-2-3 phase, to investigate the effect of the dopant on microstructure and superconductivity. During the peritec reaction, all the added $CeO_2$ was converted to $BaCeO_3$ particles which were finely dispersed in large 1-2-3 grains. Superconducting transition temperature($T_{c}R=0$ point) of the partial-melted samples was as high as 90K regardless of $CeO_2$ content up to 5wt%, which is owing to the separation of the second phase from the 1-2-3 superconducting phase.

  • PDF

Design of Nanocluster Based Material with Catalytic Properties

  • Tadachika Nakayama;Kim, Chang-Yeoul;Tohru Sekino;Choa, Yong-Ho;Takafumi Kusunose;Yamato Hayashi;Koichi Niibara
    • Journal of Powder Materials
    • /
    • v.8 no.3
    • /
    • pp.197-200
    • /
    • 2001
  • Modified inert gas condensation method was used to produce the nanocluster composites of $CuO/CeO_2$. High-resolution TEM, SEM and catalytic measurements have been used to characterize the samples and study the synergistic effect between the CuO phase and $CeO_2$(ceria) support. By varying the He pressure, the heating temperature and configuration of the heating boats inside the modified gas condensation chamber, nanoclusters of varying sizes, shapes and composition can be produced. The composition and nanostructured morphology were shown to influence the catalytic properties of the system. A copper content around 10 at% with a morphology that favors high-energy surfaces of ceria is shown to be beneficial for a high catalytic activity.

  • PDF

Development of Ceramic Pigment using Brass Scrap (각종 황동 Scrap를 사용한 Ceramic 안료 개발)

  • Kim, Jun-Ho;Jeon, Ok-Hyun;Suh, Man-Chul;Lee, Byung-Ha
    • Journal of the Korea Safety Management & Science
    • /
    • v.9 no.6
    • /
    • pp.197-204
    • /
    • 2007
  • Ceramic pigments were developed by using 4 kinds of Brass scraps. Each Brass scraps were mixed with same weight-ratio of Husk ash, and fine-ground by Rotate ring mill(RRG-120, Armstech industrial. co. Ltd, Korea) after firing at $900^{\circ}C$, $1000^{\circ}C$ and $1100^{\circ}C$. As a result, analysis of particle size of synthetic pigments by particle size analyser, they are $3{\mu}m$ as average. The resulting pigments were characterized by using XRD, FT-IR, SEM Structure of the crystals are Zn2SiO4,, and ZnO, Cu2O, CuO, and cristobalite are existed and particles' shape are plate or needle. As a result of analysis of chemical composition by XRF, synthetic pigments have high SiO2 and CuO content and have SnO2, ZnO and NiO, too. 1wt%, 3wt% and 5wt% pigments were added in each lime glaze, lime-barium glaze and lime-magnesia glaze, and fired at oxidation and reducing atmosphere to figure hue in glazes out. As a result of analysis of color, chroma and brightness by UV, colors of glazes fired at oxidation atmosphere turned into green from sky blue, and colors of glazes fired at reducing atmosphere turned into pink and red.