• 제목/요약/키워드: Cu additive

검색결과 186건 처리시간 0.022초

THE ABSORPTION PROPERTIES OF Cu-Zn FERRITE/RUBBER COMPOSITE MICROWAVE ABSORBER WITH PZT ADDITIVE

  • Shin, Kwang-Ho;Geon, Sa-Gong
    • 한국자기학회지
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    • 제5권5호
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    • pp.556-560
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    • 1995
  • The absorption properties of Cu-Zn ferrite/rubber composite microwave absorbers with PZT(Lead Zirconate Titanate) additive were evaluated. The composite specimens have prepared by molding and curing the mixture of matrix rubber and Cu-Zn ferrite powders which are synthesized by the coprecipitation method using Fe Cl/sub 3/ .center dot. 6H/sub 2/O, CuCl/sub 2/ .center dot. 2H/sub 2/O and Zn Cl/sub 2/ as a starting raw materials. PZT is used as another filler particles to adjust the material constants of Cu-Zn ferrite/rubber composite specimens. We have found that the material constants of specimens could be controlled by various PZT mixing ratio. On the Cu-Zn ferrite/rubber composite specimens with PZT 10[wt%] additive, the reflection losses were larger than 30[dB] in the frequency range from 2.72 to 4.4[GHz]' by adjusing the thickness.

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Ag와 Au가 혼합된 $Bi_{1.84}\;Pb_{0.34}\;Sr_{1.91}\;Ca_{2.03}\;Cu_{3.06}\;O_{10+\delta}$ 산화물 고온초전도체의 초전도특성 (Composite Effect of Ag and Au in the $Bi_{1.84}\;Pb_{0.34}\;Sr_{1.91}\;Ca_{2.03}\;Cu_{3.06}\;O_{10+\delta}$(110K Phase) High-Tc Superconductor)

  • 이민수
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제52권6호
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    • pp.241-248
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    • 2003
  • $Bi_{1.84}Pb_{0.34}Sr_{1.91}Ca_{2.03}Cu_{3.06}O_{10+\delta}$ high $T_{c}$ superconductors containing Ag as an additive were fabricated by a solid-state reaction method. The superconducting properties, such as the structural characteristics, the critical temperatures, the grain size and the image of mapping on the surface were investigated. Samples with Ag and Au of 50 wt% each were sintered at various temperature(820~$850^{\circ}C$). The structural characteristics, the microstructure of surface and the critical temperature with respect to the each samples were analyzed by XRD and SEM, EDS and four-prove methode respectively. The critical temperature showed the result which the Ag additive samples are higher than Au additive samples. The microstructure of the surface showed the tendency which the Ag additive samples become more minuteness than Au additive samples.

Effects of Additives on the Properties of $YBa_2Cu_3O_x$

  • Soh, Dea-Wha;Cho, Yong-Joon;Fan, Zhanguo
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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    • pp.341-344
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    • 2004
  • The superconducting properties of $YBa_2Cu_3O_x$ with different content impurities of PbO and $BaPbO_3$ were studied. When the PbO was used as an additive in $YBa_2Cu_3O_x$, although the melting point could be reduced, the superconductivity became poor. From the XRD pattern of the sintered mixture of $YBa_2Cu_3O_x$ and PbO it was known that there is a reaction between $YBa_2Cu_3O_x$ and PbO, and the product is $BaPbO_3$. In the process of the reaction the superconducting phase of $YBa_2Cu_3O_x$ was decreased and $BaPbO_3$ would be the main phase in the sample. Therefore, $BaPbO_3$ was chosen as the impurity additive for the comparative study. The single phase of $BaPbO_3$ was synthesized by the simple way from both mixtures of $BaCO_3$ and PbO, $BaCO_3$ and $PbO_2$. Different contents of $BaPbO_3$ (10%, 20%, 30%) were added in the $YBa_2Cu_3O_x$. By the Phase analysis in the XRD patterns it was proved that there was no reaction between $YBa_2Cu_3O_x$ and $BaPbO_3$. When $BaPbO_3$ was used as impurity in $YBa_2Cu_3O_x$ the superconductivity was much better than PbO as an impurity additive in $YBa_2Cu_3O_x$.

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국부용융성장법으로 제조한 (Sm/Y)-Ba-Cu-0계 고온복합초전도체의 CeO2첨가에 따른 초전도특성 (Superconducting Properties of (Sm/Y)-Ba-Cu-0 High Tc Composite Superconductors with CeO2 Additive by Zone-Melt Textured Growth)

  • 김소정
    • 한국전기전자재료학회논문지
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    • 제15권3호
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    • pp.269-274
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    • 2002
  • (Sm/Y)-Ba-Cu-O system high Tc composite superconductors with/without $CeO_2$ additive were directionally grown by zone-melting process, haying large temperature gradient, In air atmosphere. Cylindrical green rods of $({Sm/y})_{1.8}Ba_{2.4}Cu_{3.4}O_x$ [(Sm/Y)1.8] composite oxides by cold isostatic pressing(CIP) method using rubber mold were fabricated. The microstructure and superconducting properties were investigated by XRD, SEM, TEM and SQUID magnetometer. The size of nonsuperconducting $({Sm/y})_2BaCuO_5$ inclusions of the melt-textured (Sm/Y)1.8 sample with CeO$_2$ additive were remarkably reduced and uniformly distributed within the superconducting (Sm/Y)1.8 matrix. Both samples, with/without $CeO_2$ additive, showed an onset Tc $\geq$ 90 K and sharp superconducting transition. The critical current density Jc value of the $CeO_2$ addictive were $1{\times}10^5A/\textrm{cm}^2$ in 77 K, 0 Tesla.

Enhanced Photovoltaic Performance of Perovskite Solar Cells by Copper Chloride (CuCl2) as an Additive in Single Solvent Perovskite Precursor

  • Kayesh, Md. Emrul;Matsuishi, Kiyoto;Chowdhury, Towhid H.;Kaneko, Ryuji;Noda, Takeshi;Islam, Ashraful
    • Electronic Materials Letters
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    • 제14권6호
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    • pp.712-717
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    • 2018
  • In this letter, we have introduced copper chloride ($CuCl_2$) as an additive in the $CH_3NH_3PbI_3$ precursor solution to improve the surface morphology and crystallinity of $CH_3NH_3PbI_3$ films in a single solvent system. Our optimized perovskite solar cells (PSCs) with 2.5 mol% $CuCl_2$ additive showed best power conversion efficiency (PCE) of 15.22%. The PCE of the PSCs fabricated by $CuCl_2$ (2.5 mol%) additive engineering was 56% higher than the PSC fabricated with pristine $CH_3NH_3PbI_3$.

Fe-계 산화물 매체의 수소 저장 및 방출을 위한 Cu 및 Ni 첨가제의 효과 (Effects of Cu and Ni Additives for Hydrogen Storage and Release of Fe-based Oxide Mediums)

  • 김홍순;차광서;이동희;유병관;강경수;박주식;김영호
    • 한국수소및신에너지학회논문집
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    • 제19권5호
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    • pp.394-402
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    • 2008
  • The Effects of Cu or Ni additives co-added with Ce/Zr mixed oxides to Fe-based oxide mediums were investigated for the purpose of the replacement of Rh, a precious metal additive, in terms of hydrogen storage(reduction by hydrogen) and release(water splitting). From the results of temperature programmed reduction(TPR), initial reduction rate of iron oxide in the mediums was greatly increased with the addition of Cu, similar to that of Rh. For isothermal redox reaction of 10 cycles, the total amounts of hydrogen evolved in water splitting steps for the mediums added with Cu or Ni were highly maintained at ca. 7 mmol/g-material, even though the oxidation rates were slightly lower than that for the medium added with Rh. This result suggests that the replacement of Rh to Cu or Ni is possible as a co-additive for Fe-based oxide mediums.

첨가제에 의한 PWM-PSN-PZT계 세라믹의 유전특성에 관한 연구 (A study on the dielectric characteristics of PWM-PSN-PZT ceramics with additive)

  • 신혜경;송현재;김유신;배선기
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2003년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.107-109
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    • 2003
  • This paper was to measure the structure, piezoelectric properties of $0.03Pb(Mg_{0.5}W_{0.5})O_3$ - $0.12Pb(Sb_{0.5}Nb_{0.5})O_3$ - $0.85Pb(Zr_{0.52}Ti_{0.48})O_3$ + $0.5[wt%]MnO_2$ ceramics dropped with additive CuO after manufacturing the specimens with a general method. It is shown that X-ray diffraction pattern variation of lines (211) have tendency to move minutely by addition of additive CuO. According to dropping with Cu, the dielectric constant at 20[$^{\circ}C$] reduced to CuO 3.0[wt%]. In case of sintering at 1050[$^{\circ}C$], dielectric constant was maximum value 623.59 at CuO 1.0[wt%]. Dielectric loss was maximum value 2.7[%] at Cu 2.0[wt%] in case of sintering at 1050[$^{\circ}C$].

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존멜팅법으로 제조한 (YNdSm)-Ba-Cu-O계 고온복합초전도체의 미세구조 및 전기적 특성 (Microstructure and Electrical Properties of (YNdSm)-Ba-Cu-O High Tc Composite Superconductors by Zone Melting Process)

  • 김소정;이상헌
    • 한국전기전자재료학회논문지
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    • 제29권2호
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    • pp.110-113
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    • 2016
  • (YNdSm)-Ba-Cu-O system high Tc composite superconductors were directionally grown by zone melting process, having large temperature gradient, in air atmosphere. Cylindrical green rods of $(YNdSm)_{1.8}Ba_{2.4}Cu_{3.4}O_x$ [(YNS)1.8]composite oxides by CIP (cold isostatic pressing) method using rubber mold were fabricated. The microstructure and superconducting properties were investigated by XRD, TEM and SQUID magnetometer. The size of nonsuperconducting $(YNdSm)_2BaCuO_5$ inclusions of the melt-textured (YNS)1.8 sample with $CeO_2$ additive were remarkably reduced and uniformly distributed within the superconducting (YNS)1.8 matrix. (YNS)1.8 samples, with / without $CeO_2$ additive, showed an onset $T_c{\geq}90K$ and sharp superconducting transition. The critical current density $J_c$ value of the (YNdSm)1.8 superconductor with $CeO_2$ additive were 840 A, $1.2{\times}104A/cm^2$ in 77 K, 0 Tesla by direct current transport method.